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研究生: 韓新花
Yohana - Dwi Setyawati
論文名稱: 降低白米澱粉中直鏈澱粉含量以生產糯米粉
Producing Glutinous Rice Flour by Reducing Amylose Content of White Rice Starch
指導教授: 朱義旭
Yi-Hsu Ju
口試委員: 王孟菊
Meng-Jiy Wang
Suryadi Ismadji
Suryadi Ismadji
Felycia Edi Soetaredjo
Felycia Edi Soetaredjo
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2015
畢業學年度: 103
語文別: 英文
論文頁數: 67
中文關鍵詞: 直鏈澱粉支鏈澱粉碎白米糯米黏米超音波
外文關鍵詞: amylose, amylopectin, broken white rice, glutinous rice, sticky rice, ultrasonication
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糯米或稱作黏米經煮過後呈現黏性。糯米在食品工業上有極佳應用價值,例如嬰兒食物。雖然在食品加工工業上有高價值,但糯米汁產量低;在某些國家,例如泰國,糯米價格遠高於白米。本研究發展出一種方法可將碎白米澱粉中直鏈澱粉之含量降至2%以下,是以產品之性質可能與糯米粉相近。本研究將現有利用直鏈澱粉與甘油形成錯合物之浸出法改良,引進超音波及鹼(氫氧化鈉)結果可將處理溫度從98°C降到70°C、處理時間從2小時降到1小時。將甘油濃度、鹼使用量及超音波對直鏈澱粉移除效果作探討,結果發現甘油濃度、鹼使用量及超音波對直鏈澱粉移除效果有顯著影響。在最佳情況下,直鏈澱粉之含量可從 27.27%降低至 1.43%,產率為80%。.


Glutinous rice flour or sticky rice flour is a type of rice which is sticky when cooked. This kind of rice flour is excellent for many applications in food products, such as thickening for white sauce and puddings. Despite its high value in food processing industry, the productivity seems to be low and in some countries, such as Thailand, the price is significantly higher than that of white rice. In this work, a method was developed to reduce the amylose content of broken white rice starch to lower than 2%, therefore it may have similar characteristic to glutinous-type rice flour. The existing aqueous leaching method by complex formation of amylose with glycerol was modified by introducing ultrasonication and alkaline (NaOH) so that the treatment temperature can be reduced from 98°C to 70°C and treatment time from 2 h to 1 h. The effects of glycerol concentration, alkali, and ultrasonication were studied and the results showed that ultrasonication, glycerol concentration, and alkali have significant effects on the decrease of amylose content after treatment. Under optimum conditions, the amylose content of broken white rice starch can be reduced from 27.27% to 1.43% with a yield of 80%.

Chapter 1Introduction 1.1Background of the study 1.2Objectives of the study Chapter 2Literature Survey 2.1White rice 2.1.1Broken white rice 2.2Glutinous rice 2.3Rice starch 2.3.1Amylose 2.3.2Amylopectin 2.3.3Solubility of starch component in water 2.1Ultrasonication and Its Application 2.2Starch Fractionation 2.2.1Selective precipitation 2.2.2Aqueous leaching 2.3Gel Permeation Chromatography (GPC) Chapter 3Materials and Methods 3.1Materials 3.2Chemicals and Standards 3.3Solutions 3.4Apparatus and Equipments 3.5Methods 3.5.1Preparation of material 3.5.2Extraction of amylose 3.5.3Analysis 3.5.3.1Amylose content by GPC 3.5.3.2Total sugar and starch content 3.5.3.3Crude fiber, protein, ash, and lipid content 3.5.3.4Moisture content 3.5.3.5Thermal decomposition 3.5.3.6Gelatinization and retrogradation properties of rice flour starch 3.5.3.7Swelling power and solubility of rice flour starch 3.5.3.8Scanning electron microscopy (SEM) 3.5.3.9X-ray diffraction (XRD) Chapter 4Results and Discussion 4.1Effect of glycerol concentration 4.2Effect of NaOH 4.3Effect of ultrasonication 4.4Effect of treatment time 4.5Scanning electron microscopy (SEM) study 4.6Thermal decomposition of rice flour 4.7Gelatinization and retrogradation properties of rice flour 4.8Swelling power and solubility of rice flour starch 4.9X-ray diffraction (XRD) Chapter 5Conclusion REFERENCES APPENDIX

USA Rice Federation. 2010. Rice Technical Information Kit. The complete guide for using U.S rice as an ingredient. Arlington, USA: 1-18.
Abdullah, S., Mudalip, S. K. A., Shaarani, S. M. and Pi, N. A. C. 2010. Ultrasonic extraction of oil from Monopterus albus: effects of different ultrasonic power, solvent volume and sonication time. J Appl Sci, 10, 2713-2716.
Adeniyi, O. D. and Bawa, A. A. 2006. Mackerel (Scomber scrombrus) oil extraction and evaluation as raw materials for industrial utilization. Leonardo J Sci, 8, 33-42.
Buleon, A., Colonna, P., Planchot, V. and Ball, S. 1998. Mini review: starch granules: structure and biosynthesis. Int J Biol Macromol, 23, 85-112.
Cai, J., Yang, Y., Man, J., Huang, J., Wang, Z., Zhang, C., Gu, M., Liu, Q. and Wei, C. 2014. Structural and functional properties of alkali-treated high-amylose rice starch. Food Chem, 145, 245-253.
Castillo, C. P. S., Dewey, P. J. S., Lara, J. J., Henderson, D. L., Solano, M. d. L. and James, W. P. T. 2000. The starch and sugar content of some Mexican cereals, cereal products, pulses, snack foods, fruits and vegetables. J Food Compos Anal, 13, 157-170.
Chan, H.-T., Bhat, R. and Karim, A. A. 2010. Effects of sodium dodecyl sulphate and sonication treatment on physicochemical properties of starch. Food Chem, 120, 703-709.
Dalen, G. V. 2004. Determination of the size distribution and percentage of broken kernels of rice using flatbed scanning and image analysis. Food Res Int, 37, 51-58.
Ding, W., Wang, Y., Zhang, W., Shi, Y. and Wang, D. 2015. Effect of ozone treatment on physicochemical properties of waxy rice flour and waxy rice starch. Int J Food Sci Tech, 50, 744-749.
Falleh, H., Ksouri, R., Lucchessi, M. E., Abdelly, C. and Magne, C. 2012. Ultrasound-assisted extraction: effect of extraction time and solvent power on the levels of polyphenols and antioxidant activity of Mesembryanthemum edule L. Aizoaceae shoots. Trop J Pharm Res, 2, 243-249.
FAOSTAT. 2013. Top production - rice, paddy. http://faostat.fao.org/site/339/default.aspx.
Green, M. M., Blankenhorn, G. and Hart, H. 1975. Which starch fraction is water-soluble, amylose or amylopectin? J Chem Educ, 52, 729-730.
Imberty, A., Buleon, A., Tran, V., Perez, S. and Nantez. 1991. Recent advances in knowledge of starch structure. Starch-Starke, 43, 375-384.
IRRI. 2006. Rice milling. Agricultural Unit: 1-11.
Isono, Y., Kumagai, T. and Watanabe, T. 1994. Ultrasonic degradation of waxy rice starch. Biosci Biotech Bioch, 58, 1799-1802.
Jambrak, A. R., Herceg, Z., Šubaric, D., Babic, J., Brncic, M., Brncic, S. R., Bosiljkov, T., Cvek, D., Tripalo, B. and Gelo, J. 2010. Ultrasound effect on physical properties of corn starch. Carbohydr Polym, 79, 91-100.
Juliano, B. O. 1984. Rice starch: production, properties, and uses. Starch. Academic Press, Inc, New York. 507-528.
Karim, A. A., Nadiha, M. Z., Chen, F. K., Phuah, Y. P., Chui, Y. M. and Fazilah, A. 2008. Pasting and retrogradation properties of alkali-treated sago (Metroxylon sagu) starch. Food Hydrocolloid, 22, 1044-1053.
Kerr, R. W. and Severson, G. M. 1943. On the multiple amylose concept on starch. III. The isolation of an amylose in crystalline form. J Am Chem Soc, 65, 193-198.
Khush, G. S. 2005. What it will take to feed 5.0 billion rice consumers in 2030. Plant Mol Biol, 59, 1-6.
Lansky, S., Kooi, M. and Schoch, T. J. 1949. Properties of the fractions and linear subfractions from various starches. J Am Chem Soc, 71, 4066-4075.
Martinez, M. O., Whitney, K. and Simsek, S. 2013. Analysis of starch in food systems by high-performance size exclusion chromatography. J Food Sci, 78, 192-198.
Montgomery, E. M. and Senti, F. R. 1958. Separation of amylose from amylopectin of starch by an extraction-sedimentation procedure. J Polym Sci, 28, 1-9.
Nadiha, M. Z. N., Fazilah, A., Bhat, R. and Karim, A. A. 2010. Comparative susceptibilities of sago, potato and corn starches to alkali treatment. Food Chem, 121, 1053-1059.
Okotore, R. O. 1998. Basic separation techniques in biochemistry. Poplai for New Age International, New Delhi, India.
Pigman, W. W. and Wolfrom, M. L. 1945. Advances in carbohydrate chemistry. Academic Press Inc, New York.
Potter, A. L. and Hassid, W. Z. 1948. Molecular weights of amyloses and amylopectins from starches of various plant origins. J Am Chem Soc, 70, 3774-3777.
Prasad, K., Anil, A., Singh, Y. and Sinha, A. S. K. 2013. Concentration dependent rheological behaviour of promising basmati and non basmati rice flour. Int Food Res J, 20, 2005-2008.
Reid, B. O. F., Tatsuta, K. and Thiem, J. 2008. Glycoscience: chemistry and chemical biology. Springer, Berlin.
Schoch, T. J. 1942. Fractionation of starch by selective precipitation with butanol. J Am Chem Soc, 64, 2957-2961.
Shaptadvipa, B. and Sarma, R. N. 2009. Study on apparent amylose content in context of polymorphism information content along with indices of genetic relationship derived through SSR markers in Birain, Bora and Chokuwa groups of traditional glutinous rice (Oryza sativa L.) of Assam. Asian J Biochem, 4, (2), 45-54.
Shih, F. F., Champagne, E. T., Daigle, K. and Zarins, Z. 1999. Use of enzymes in the processing of protein products from rice bran and rice flour. Nahrung, 43, 14-18.
Singh, N., Singh, J., Kaur, L., Sodhi, N. S. and Gill, B. S. 2003. Review: morphological, thermal and rheological properties of starches from different botanical sources. Food Chem, 81, 219-231.
Sodhi, N. S. and Singh, N. 2003. Morphological, thermal and rheological properties of starches separated from rice cultivars grown in India. Food Chem, 80, 99-108.
Sotelo, A., Sousa, V., Montalvo, I., Hernandez, M. and Hernandez-Aragon, L. 1990. Chemical composition of different fractions of 12 Mexican varieties of rice obtained during milling. Cereal Chem, 67, 209-212.
Techawipharat, J., Suphantharika, M. and BeMiller, J. N. 2008. Effects of cellulose derivatives and carrageenans on the pasting, paste, and gel properties of rice starches. Carbohydr Polym, 73, 417-426.
Tester, R. F. and Morrison, W. R. 1990. Swelling and gelatinization of cereal starches. II. waxy rice starches. Cereal Chem, 67, 558-563.
Titapiwatanakun, B. 2012. Technical Assistance Consultant’s Report. Kasetsart University, Thailand.
Vandeputte, G. E. and Delcour, J. A. 2004. From sucrose to starch granule to starch physical behaviour: a focus on rice starch. Carbohydr Polym, 58, 245-266.
Varavinit, S., Shobsngob, S., Varanyanond, W., Chinachoti, P. and Naivikul, O. 2003. Effect of amylose content on gelatinization, retrogradation and pasting properties of flours from different cultivars of Thai Rice. Starch-Starke, 55, 410-415.
Wani, A. A., Singh, P., Shah, M. A., Schweiggert-Weisz, U., Gul, K. and Wani, I. A. 2012. Rice starch diversity: effects on structural, morphological, thermal, and physicochemical properties—A review. Compr Rev Food Sci F, 11, 417-436.
Wulff, G. and Kubik, S. 1992. Helical amylose complexes with organic complexands, 1 microcalorimetric and circular dichroitic investigations. Makromol Chem, 193, 1071-1080.
Yu, S., zhang, Y., Ge, Y., Zhang, Y., Sun, T., Jiao, Y. and Zheng, X.-Q. 2013. Effects of ultrasound processing on the thermal and retrogradation properties of nonwaxy rice starch. J Food Process Eng, 36, 793-802.
Yuliana, M., Huynh, L. H., Ho, Q. P., Truong, C. T. and Ju, Y. H. 2012. Defatted cashew nut shell starch as renewable polymeric material: Isolation and characterization. Carbohydr Polym, 87, 2576-2581.
Zhu, L. J., Liu, Q. Q., Wilson, J. D., Gu, M. H. and Shi, Y. C. 2011. Digestibility and physicochemical properties of rice (Oryza sativa L.) flours and starches differing in amylose content. Carbohydr Polym, 86, 1751-1759.
Zhu, T., Jackson, D. S., Wehling, R. L. and Geera, B. 2008. Comparison of amylose determination methods and the development of a dual wavelength iodine binding technique. Cereal Chem, 85, 51-58.
Zhu, Y., Chen, H., Fan, J., Wang, Y., Li, Y., Chen, J., Fan, J., Yang, S., Hu, L., Leung, H., Mew, T. W., Teng, P. S., Wang, Z. and Mundt, C. C. 2000. Genetic diversity and disease control in rice. Nature, 406, 718-7

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