研究生: |
古明龍 Ming-Long - Gu |
---|---|
論文名稱: |
含有對苯乙炔和降冰片烯二酸酐單元的嵌段共聚物高分子合成與鑑定 Synthesis and characterization of block copolymers containing phenylenevinylene and norbornene dicarboximide units |
指導教授: |
游進陽
Chin-Yang Yu |
口試委員: |
邱智瑋
Chih-Wei Chiu 堀江正樹 Masaki Horie |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
論文出版年: | 2017 |
畢業學年度: | 105 |
語文別: | 英文 |
論文頁數: | 112 |
中文關鍵詞: | 開環歧化聚合 、降冰片烯衍生物 、環對苯雙烯衍生物 、嵌段共聚物 、自組裝 |
外文關鍵詞: | Ring opening metathesis polymerization, norbornene derivatives, paracyclophanediene derivatives, block copolymer, self assembly |
相關次數: | 點閱:342 下載:0 |
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此論文的目標是合成和鑑定以開環岐化聚合所得到具有不同體積比率的嵌段共聚物。為了控制分子量的分布,三代格拉布催化劑作為本論文中的所選用的催化劑。
The aim of this thesis was to synthesis and characterization the polymers containing phenylene vinylene and norbornene dicarboximide units with different volume fraction via ring-opening metathesis polymerization. In order to control the molecular weights and narrow polydispersities of polymers, the fast-initiation ruthenium catalyst such as Grubbs’ 3rd was selected in this thesis.
The block copolymers were examined by 1H nuclear magnetic resonance spectroscopy to investigate the block ratio of the phenylenevinylene and norbornene dicarboximide units. The molecular weights, optical, thermal and electrochemical properties of polymers were also investigated by gel permeation chromatography, differential scanning calorimeter, thermogravimetric analysis, UV-vis absorption, photoluminescence spectroscopy and cyclic voltammetry. The polymers containing phenylenevinylene units can be carried out an isomerization from cis/trans to trans-rich microstructure under an irradiation of UV-lamp (λ=365nm) for 36 hours. The 1H NMR spectra and optical properties of trans-rich polymers were also investigated and compared with the cis/trans ones. The morphology study of cis/trans and trans-rich polymer films was examined by atomic force microscopy (AFM) to observe the self-assembly behavior of the polymers.
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