含有對苯乙炔和降冰片烯二酸酐單元的嵌段共聚物高分子合成與鑑定

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研究生：	古明龍 Ming-Long - Gu
論文名稱：	含有對苯乙炔和降冰片烯二酸酐單元的嵌段共聚物高分子合成與鑑定 Synthesis and characterization of block copolymers containing phenylenevinylene and norbornene dicarboximide units
指導教授：	游進陽 Chin-Yang Yu
口試委員:	邱智瑋 Chih-Wei Chiu 堀江正樹 Masaki Horie
學位類別：	碩士 Master
系所名稱：	工程學院 - 材料科學與工程系 Department of Materials Science and Engineering
論文出版年：	2017
畢業學年度：	105
語文別：	英文
論文頁數：	112
中文關鍵詞：	開環歧化聚合、降冰片烯衍生物、環對苯雙烯衍生物、嵌段共聚物、自組裝
外文關鍵詞：	Ring opening metathesis polymerization, norbornene derivatives, paracyclophanediene derivatives, block copolymer, self assembly
相關次數：	點閱：316 下載：0
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上一筆

此論文的目標是合成和鑑定以開環岐化聚合所得到具有不同體積比率的嵌段共聚物。為了控制分子量的分布，三代格拉布催化劑作為本論文中的所選用的催化劑。

The aim of this thesis was to synthesis and characterization the polymers containing phenylene vinylene and norbornene dicarboximide units with different volume fraction via ring-opening metathesis polymerization. In order to control the molecular weights and narrow polydispersities of polymers, the fast-initiation ruthenium catalyst such as Grubbs’ 3rd was selected in this thesis.
The block copolymers were examined by 1H nuclear magnetic resonance spectroscopy to investigate the block ratio of the phenylenevinylene and norbornene dicarboximide units. The molecular weights, optical, thermal and electrochemical properties of polymers were also investigated by gel permeation chromatography, differential scanning calorimeter, thermogravimetric analysis, UV-vis absorption, photoluminescence spectroscopy and cyclic voltammetry. The polymers containing phenylenevinylene units can be carried out an isomerization from cis/trans to trans-rich microstructure under an irradiation of UV-lamp (λ=365nm) for 36 hours. The 1H NMR spectra and optical properties of trans-rich polymers were also investigated and compared with the cis/trans ones. The morphology study of cis/trans and trans-rich polymer films was examined by atomic force microscopy (AFM) to observe the self-assembly behavior of the polymers.

Table of content
Abstract	1
Chapter 1. Introduction and Aims	4
Introduction	5
1	Conducting polymers	5
2	Synthetic routes for poly(arylenevinylene)s	8
3	Block copolymers	14
4	Self-assembly behavior of polymers	17
5	Ring opening metathesis polymerization	20
6	Aim of the project	25
7	References	26
Chapter 2. Results and Discussion	28
1	Synthesis and characterization of monomers	29
1.1	Synthesis of exo-5-Norbornene-2,3-dicarboximide (3)	29
1.2	Synthesis of tetraoctyloxy substituted paracyclophanediene (10a)	35
2	Synthesis and characterization of polymers	38
2.1	Synthesis of poly(N-octyl-exo-norbornene-5,6-dicarboximide)  homopolymer P1	38
2.2	Synthesis of poly(2,5-dioctyloxy-p-phenylenevinylene)s  homopolymer P2	40
2.3	Synthesis of poly(N-octyl-exo-norbornene-5,6-dicarboximide) -b-(2,5-dioctyloxy-p-phenylenevinylene) block copolymer P3-P5	42
3	Properties of polymers	46
3.1	Molecular weight of polymers	46
3.2	Optical properties of polymers	48
3.3	Isomerization of the polymers by UV light irradiation	52
3.4	Thermal properties of polymers	56
3.5	Electrochemical properties of polymers	59
3.6	Morphology study of polymer films	61
4	References	71
Chapter 3. Conclusion	73
Chapter 4. Experimental	75
1	General procedures	76
2	Synthesis of the monomers (3) and (10a)	78
3	Synthesis of polymers P1-P5	86
Appendix	89
1H, 13C, COSY and HSQC NMR spectra	89
Mass spectroscopy	108
                                

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全文公開日期 2022/01/18 (校內網路)
全文公開日期本全文未授權公開 (校外網路)
全文公開日期本全文未授權公開 (國家圖書館：臺灣博碩士論文系統)

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