研究生: |
林揚鵬 Yang-Peng Lin |
---|---|
論文名稱: |
添加石墨烯及奈米碳管之AZ91鎂基複合材料微觀結構觀察及機械性質探討 Microstructure and mechanical properties of graphene nanoplatelets and multi-walled carbon nanotube on AZ91 magnesium matrix composites |
指導教授: |
黃崧任
Song-Jeng Wang |
口試委員: |
陳復國
Fun-Kuo Chen 丘群 Chun Chiu 曾有志 Yu-Chin Tzeng |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 機械工程系 Department of Mechanical Engineering |
論文出版年: | 2023 |
畢業學年度: | 111 |
語文別: | 中文 |
論文頁數: | 97 |
中文關鍵詞: | 鎂基複合材料 、石墨烯 、奈米碳管 、熱處理 |
外文關鍵詞: | Magnesium matrix composites, GNPs, CNTs, Heat treatment |
相關次數: | 點閱:383 下載:0 |
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本研究採用AZ91鎂鋁合金作為鎂基複合材料之基質材料,以石墨烯(Graphene nanoplatelets, GNPs)、奈米碳管(Carbon nanotubes, CNTs)作為強化相,利用重力鑄造法及機械攪拌法進行鎂基複合材料之製備,強化相添加量為0.1wt%、0.2wt%、0.3wt%,完成製備切割成實驗試片後一部分施作T4固溶熱處理後直接進行水淬,另一部分進行T4固溶熱處理及T6人工時效熱處理,探討添加不同重量百分比強化相及不同熱處理對於AZ91/GNPs+CNTs鎂基複合材料之微觀結構、機械性質。從實驗結果中可以發現添加奈米級之碳強化相可以得到晶粒細化之效果,降伏強度、極限強度、延展性及硬度皆有所提升,透過T4熱處理後將第二相Mg17Al12溶入基材中有助於提升材料延展性,提升極限強度。施作T6熱處理之後使第二相析出後,因析出物硬脆特性使材料硬度、降伏強度有所上升。
This research uses AZ91 magnesium alloy as the metal matrix and graphene nanoplate and carbon nanotube as the reinforcement. In addition, the amount of 0.1, 0.2 and 0.3 weight percent of the reinforcement particles were added respectively into matrix and produced by gravity casting. After T4 solution treatment and T6 aging heat treatment, the specimens were tested for the mechanical properties and microstructure. Discussions of the effects of different ratios reinforcement and heat treatment have been included in this experiment. From the experiment result, when adding GNPs and CNTs the grain size was decreased effectively. Yield strength, ultimate tensile strength and hardness were improved due to the grain refinement. After T4 solution treatment, ultimate tensile strength and ductility were improved. After T6 aging heat treatment, β-phase was precipitated, hardness and yield strength were strength.
[1] 林穎智 (2018),鎂基複合材料機械性質及其熱傳導性之研究,國立臺灣科技大學機械工程學系碩士論文
[2] 蘇士銘 (2019),不同溫度及道次等通道轉角擠製(ECAP)對AZ61/Al2O3鎂基複合材料機械性質及腐蝕之影響,國立臺灣科技大學機械工程學系碩士論文
[3] S. Kandemir , “Development of graphene nanoplatelet-reinforced AZ91 magnesium alloy by solidification processing”, Journal of Materials Engineering and Performance, vol. 27, pp. 3014-3023, 2018.
[4] M. Rashad , F. Pan , A. Tang , M. Asif , M. Aamir , “Synergetic effect of graphene nanoplatelets (GNPs) and multi-walled carbon nanotube (MW-CNTs) on mechanical properties of pure magnesium ”, Journal of Alloys and Compounds, vol. 603, pp. 111-118, 2014.
[5] M. Torabi Parizi , G.R. Ebrahimi , H.R. Ezatpour , M. Paidar, “The structure effect of carbonaceous reinforcement on the microstructural characterization and mechanical behavior of AZ80 magnesium alloy”, Journal of Alloys and Compounds, vol. 809, article 151682 , 2019.
[6] 黃建忠 (2013),強化項粒徑對AZ61/SiCp鎂基複合材料鑄錠及擠型材之機械性質影響的研究,國立臺灣科技大學機械工程學系碩士論文。
[7] 吳懿璋(2014),強化相粒徑與含量對AZ61/SiCP 鎂合金複合材料於擠製加工及後續退火製程在機械性質影響之研究,國立臺灣科技大學機械工程學系碩士論文
[8] L. Zheng, H. Nie, W. Liang, H. Wang, Y. Wang, “Effect of pre-homogenizing treatment on microstructure and mechanical properties of hot-rolled AZ91 magnesium alloys”, Journal of Magnesium and Alloys, Vol. 4, Issue 2, pp. 115-122, 2016.
[9] X. J. Wang, X. S. Hu, W. Q. Liu, J. F. Du, K. Wu, Y. D. Huang, M. Y. Zheng, "Ageing behavior of as-cast SiCp/AZ91 Mg matrix composites",Materials Science and Engineering,Vol.682,pp.491-500,2017.
[10] 李奕賢 (2019),不同比例SiCp添加與不同熱處理方式對鎂基複合材料機械性質及疲勞之影響,國立臺灣科技大學機械工程學系碩士論文
[11] Y. Z. Lu , Q.D. Wang, W. J. Ding, X. Q. Zeng, Y. P. Zhu ,“Fracture behavior of AZ91 magnesium alloy ” , Materials Letters, vol. 44, pp.265–268, 2000.
[12] Q.H. Yuan , G.H. Zhou, L. Liao, Y. Liu, L. Luo, “Interfacial structure in AZ91 alloy composites reinforced by graphene nanosheets” ,Carbon, vol. 127, pp. 177-186, 2018.
[13] 周暾煜 (2016),等徑轉角擠壓 (ECAP) 製程及添加物對AZ鎂合金儲氫性能之影響,國立台灣科技大學機械工程學系碩士論文
[14] 李智堯 (2018),不同轉角及道次之等徑轉角擠製對AZ31/WS_2 INT鎂基複合材料微觀結構及機械性質影響之研究,國立臺灣科技大學機械工程學系碩士論文。
[15] H. Zare, M. Jahedi, M. Reza Toroghinejad, M. Meratian, M. Knezevic ,“Microstructure and mechanical properties of carbon nanotubes reinforced aluminum matrix composites synthesized via equal-channel angular pressing” ,Materials Science & Engineering A, vol. 670, pp. 205–216, 2016.
[16] 蔡承勳 (2013),不同製程對 AZ61/Al2O3P 鎂基複合材料機械性質及疲勞之影響,國立臺灣科技大學機械工程學系碩士論文。
[17] Y. Suna, C. Yanga, B. Zhanga, J. Fanc, H. Li , T. Zhaoa, J. Li, “The aging behavior, microstructure and mechanical properties of AlN/AZ91 composite”, Journal of Magnesium and Alloys, Available online 3 March 2022
[18] X. Zhou, D. Su, C. Wu, L. Liu , “Tensile mechanical properties and strengthening mechanism of hybrid carbon nanotube and silicon carbide nanoparticle-reinforced magnesium alloy composites”, Journal of Nanomaterials, vol. 2012, pp. 7, 2012.
[19] 陳仲威 (2010),添加AlNp鎂基複材製備及機械性質之研究國立中正大學機械工程學系碩士論文。
[20] S.Diwan MidYeen, “Microstructure Evolution and Strengthening Mechanical (Tensile ,Compression, Impact & Fatigue) Properties on Hybrid Nano-SiCp and Micro Elements (Bi & Sb) of AZ91 Magnesium Composite” ,National Taiwan University of Science and Technology
[21] 張紘瑋 (2019),添加不同比例MoS2及WS2製備AZ91鎂基複合材料之微觀結構以及機械性質研究,國立臺灣科技大學機械工程學系碩士論文。