研究生: |
許適恆 Shi-Heng Shu |
---|---|
論文名稱: |
以自組裝3-Aminopropyltriethoxysilane (3-APTS)單分子薄膜成長於矽基板並以其為接合反應平台之研究 Study the fabrication of self-assembled 3-Aminopropyltriethoxysilane (3-APTS) monolayer on silicon substrates and using it as a platform for grafting reactions |
指導教授: |
戴龑
Yian Tai |
口試委員: |
洪偉修
W. H. Hung 陳良益 Liang-Yih Chen |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2009 |
畢業學年度: | 97 |
語文別: | 中文 |
論文頁數: | 122 |
中文關鍵詞: | 自組裝單分子薄膜 、接合反應 、奈米銀粒子 |
外文關鍵詞: | 3-APTS |
相關次數: | 點閱:275 下載:10 |
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本論文利用自組裝單分子薄膜(self-assembled monolayer, SAM)技術於矽基板上成長3-Aminopropyltriethoxysilane (3-APTS)薄膜,研究基板表面與溶劑的潤濕性、SAM分子對溶劑溶解度,以及成膜過程中溶液濃度對3-APTS分子成長之影響,發現選擇極性溶劑配合疏水基板,能有效控制3-APTS分子成長於基板的層數。另外,配合前述條件並針對混合溶劑系統進行研究,可得出成長3-APTS之最佳條件。此外,本論文也針對有機分子保護之奈米銀粒子合成進行研究。選擇雙羧酸之芳香族分子做為保護機團,藉由紫外光-可見光光譜儀與傅立葉紅外光光譜儀鑑定,發現羧酸根是以架橋形式接在奈米銀粒子表面。最後以3-APTS作為一接合反應之平台,將4-Fluorobenzoic acid (4-FBA) 與奈米銀粒子分別稼接於SAM薄膜尾端,經分析儀器檢測,得知可利用DCCD為反應劑,以化學方式將有機分子或無機金屬奈米粒子順利接合於3-APTS薄膜表面。
This research focuses on fabrication of self-assembled monolayer (SAM) of 3-Aminopropyltriethoxysilane (3APTS) on silicon substrates, and using it as a platform for the grafting reaction. A controllable method of fabricating monolayers was demonstrated which considering the surface wettability of substrates, the solubility of SAM molecule in solvent and the concentration of SAM solution during the fabrication process. Well-ordered SAM can be formed by using mixed solvents with optimized conditions. In addition, we study the synthesis of 1.4-dimethane- carboxylic acid benzene (DMCAB)-protected silver nanoparticles. UV-VIS and FTIR results suggested that the carboxylate bonding of DMCAB anchored on nanoparticle surface with a bridging bidentate type. Finally, we successfully use 3APTS SAM as a platform to graft 4-Fluorobenzoic acid (4-FBA) and silver nanoparticles on it respectively through chemical reaction.
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