簡易檢索 / 詳目顯示

研究生: 蔡昆哲
Kun-Jer Tsai
論文名稱: 低碳鋼與304不銹鋼異質銲件於氯化鈉/硫酸鈉混合鹽之熱腐蝕
Hot Corrosion Behavior of Dissimilar Welding between Low Carbon Steel and 304 Stainless Steel with NaCl/Na2SO4 Mixed Deposit
指導教授: 王朝正
Chaur-Jeng Wang
口試委員: 丘群
Chiun Chiu
開物
Wu Kai
學位類別: 碩士
Master
系所名稱: 工程學院 - 機械工程系
Department of Mechanical Engineering
論文出版年: 2014
畢業學年度: 102
語文別: 中文
論文頁數: 110
中文關鍵詞: 異質銲接氯化鈉硫酸鈉熱腐蝕加凡尼腐蝕
外文關鍵詞: dissimilar weldments, NaCl, Na2SO4, hot corrosion, Galvanic corrosion
相關次數: 點閱:290下載:7
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 本研究使用氬銲以309L為銲料將低碳鋼及304不銹鋼進行異質銲接,銲接部位沉積2 mg/cm2 不同比例NaCl-Na2SO4混合鹽後,置於750 °C靜滯空氣爐中探討熱腐蝕之影響。鋼料銲接後在低碳鋼 HAZ與304 HAZ皆發生晶粒成長,且304之HAZ有發生敏化現象,低碳鋼與銲道之界面則有碳化物產生。
    熱腐蝕實驗結果顯示,304與309L銲道均呈現典型內侵蝕,低碳鋼則為均勻腐蝕之型態,各區侵蝕深度皆隨持溫時間增加而增加;銲道因309L具高鉻含量使其金屬損失量最小。304之HAZ因敏化而具有大的金屬損失及總侵蝕深度;在有足量熔融鹽下,因加凡尼效應而導致在低碳鋼/309L界面之低碳鋼側發生嚴重侵蝕。


    The purpose of this work was to study the hot-corrosion behavior of dissimilar weldments by gas tungsten arc welding applied to join 304 stainless steel and low carbon steel with consumable-309L stainless steel wires at 750 °C in static air with 2 mg/cm2 mixture of various NaCl-Na2SO4 deposits. It was found that both the weldments revealed the coarse grain structure in low carbon steel HAZ and 304 HAZ and the sensitization around 304 HAZ. Moreover, the carbon migrated from the low carbon steel base metal to the higher chromium weld metal side and formed chromium carbide adjacent to the low carbon steel HAZ/WM interface.
    The results of hot corrosion showed that both 304 and 309L appeared subscale attack but low carbon steel was uniform corrosion. The depth of attack increased with increasing exposure duration of time. The weld metal had the smallest metal loss because of its high chromium content. Due to sensitized reaction the 304 HAZ had the most metal loss and the total depth of attack. The galvanic effect to the low carbon steel resulted in a serious corrosion with sufficient molten salt at low carbon steel HAZ/WM interface.

    第一章 前言 1 第二章 文獻回顧 2 2.1 銲接 2 2.1.1 氬銲 2 2.1.2 銲接熱影響效應 4 2.2 異質金屬之銲接 6 2.2.1 碳鋼與沃斯田鐵系不銹鋼之異質銲接 8 2.2.1.1 碳鋼 8 2.2.1.2 沃斯田鐵系不銹鋼 9 2.2.1.3 碳擴散問題 10 2.2.1.4 硬度之變化 13 2.2.1.5 熱影響區之晶粒變化 13 2.3 熱腐蝕及熱力學 14 2.3.1 熱力學資料 14 2.3.2 NaCl之熱腐蝕 19 2.3.3 Na2SO4之熱腐蝕 21 2.3.3.1 硫化模式 21 2.3.3.2 熔鹽模式 22 2.3.4 NaCl-Na2SO4混合鹽之熱腐蝕 23 2.3.5 沉積鹽之熱腐蝕 25 2.4 加凡尼效應 30 第三章 實驗方法 32 3.1 實驗流程圖 32 3.2 試片準備 33 3.3 鋼料銲接試片 35 3.3.1 顯微組織 35 3.3.2 銲接試片受熱之影響 40 3.4 高溫腐蝕實驗 44 3.4.1 沉積鹽熱腐蝕 44 3.4.1.1 氯化鈉-硫酸鈉混合鹽噴覆作業 44 3.4.1.2 熱腐蝕試驗 44 3.4.2 浸泡熔鹽熱腐蝕 44 3.5 腐蝕實驗後分析設備與方法 47 3.5.1 分析設備 47 3.5.2 分析方法 49 第四章 實驗結果 51 4.1 沉積鹽熱腐蝕 51 4.1.1 100% NaCl熱腐蝕 53 4.1.2 Na2SO4熱腐蝕 62 4.1.3 NaCl-Na2SO4熱腐蝕 70 4.2 熔鹽腐蝕 92 第五章 討論 97 5.1 100% NaCl熱腐蝕 97 5.2 100% Na2SO4熱腐蝕 98 5.3 NaCl-Na2SO4混合鹽之熱腐蝕 99 5.4 熔鹽之熱腐蝕 100 第六章 結論 101 參考文獻 102

    1. J. D. Farren, J. N. Dupont and F. F. Noeker, “Fabrication of a Carbon Steel-to-Stainless Steel Transition Joint Using Direct Laser Deposition-A Feasibility Study,” Weld. J. Vol. 86, p. 55, 2007.
    2. G. Y. Lai, in “High-Temperature Corrosion of Engineering Alloys,” ASM, p. 154, 1990.
    3. 蘇永華,"鐵基合金於氯化鈉/硫酸鈉混合鹽之熱腐蝕",國立台灣科技大學機械所碩士論文,民國88年。
    4. 何天佐,"鎳鉻合金於氯化鈉之高溫腐蝕反應機制",國立台灣科技大學機械所碩士論文,民國90年。
    5. 姜志華、蔡金峯,"銲接冶金概論",徐氏基金會,民國76年。
    6. 陳永甡,"焊接學",文京圖書有限公司,民國73年。
    7. 王振欽,"銲接學",登文書局,民國74年。
    8. CNS 12831 Z7211,銲接詞彙-第2部:共通部分,中華民國國家標準,民國90年。
    9. I. Hajiannia, M. Shamanian, and M. Kasiri, “Microstructure and Mechanical Properties of AISI 347 Stainless Steel/A335 Low Alloy Steel Dissimilar Joint Produced by Gas Tungsten Arc Welding,” Materials and Design, Vol. 50, pp. 566-573, 2013.
    10. 浜田晉作著,趙平譯,"不同金屬之熔接技術",台隆書店,1982
    11. J. M Nicholls, “Corrosion Properties of Duplex Stainless Steels : General Corrosion, Pitting and Crevice Corrosion,” 4th International Conference Duplex 94 Stainless Steels, Glasgow, Scotland, paper K, 13-16 Nov. 1994.
    12. Y. N. Chang and F. I. Wei, “High Temperature Chlorine Corrosion of Metals and Alloys,” J. Mater. Science, Vol. 26, pp. 3693-3698, 1991.
    13. O. Kubaschewski, E. L. Evans, and C. B. Alcock in “Metallurgical Thermochemistry,” 4th edition, Pergamon, New York, pp. 421-429, 1967.
    14. E. T. Turkdogan, in “Physical Chemistry of High Temperature Technology,” Harcourt Brace Jovanovich, New York, 1980.
    15. M. K. Hossain and S. R. J. Saunders, “A Microstructural Study of the Influence of NaCl Vapor on the Oxidation of a Ni-Cr-Al Alloy at 850 °C,” Oxidation of Metals, Vol. 12, pp. 1-21, 1978.
    16. F .J. Kohl, G. J. Santoro, C. A. Stearns, G. C. Fryburg, and D. E. Rosner, Journal of the Electrochemical Society. Vol. 126, p. 1057, 1979.
    17. J. Stringer, “Hot Corrosion of High –Temperature Alloys,” Ann. Rev. Mate. Science, Vol. 7, pp. 477-509, 1977.
    18. E. L. Simons, G. V. Browning, and H. A. Liebhafskey, “Sodium Sulfate in Gas Turbines,” Corrosion Science, Vol. 11, pp. 17-26, 1955.
    19. M. A. DeCrescente and N. S. Bornstein, “Formation and Reactivity Thermodynamics of Sodium Sulfate with Gas Turbine Alloys,” Corrosion Science, Vol. 24, No. 5, pp. 127-133, 1968.
    20. R. H. Boll and H. C. Patel, J. Eng. For Power (ASME), Vol. 83, p. 451, 1961.
    21. D. M. Johnson, D. P. Whittle, and J. Stringer, “Mechanisms of Na2SO4-Induced Accelerated Oxidation,” Corrosion Science, Vol. 15, pp. 736-739, 1975.
    22. M. A. Clevinger, K. M. Kessell, C. G. Messina, and H. M. Ondik (Eds.), Phase Diagrams for Ceramists, The American Ceramic Society, Inc., OH, Fig. 7109, 1989.
    23. 涂宗漢,"低碳鋼於氯化鈉之熱腐蝕機制及熱浸鋁之防制改善",國立台灣科技大學機械所碩士論文,民國84年。
    24. 林建勝,"鐵鎳鉻系合金於氯化鈉沉積鹽之熱腐蝕",國立台灣科技大學機械所碩士論文,民國85年。
    25. 吳烈宗,"鐵鎳鉻合金及鉻鉬鋼披覆氯化鈉之熱腐蝕",國立台灣科技大學機械所碩士論文,民國88年。
    26. 柯賢文,"腐蝕及其防制",全華圖書股份有限公司, 2011.
    27. 柯賢文、王朝正,"腐蝕及其防制",全華圖書股份有限公司, 2014.
    28. K. S. Guan, F. Xu, Z. W. Wang, and H. Xu, “Failure Analysis of Hot Corrosion of Weldments in Ethylene Cracking Tubes,” Engineering Failure Analysis, Vol. 12, pp. 1-12, 2005.
    29. U. Seybolt, “Oxidation of Ni-20Cr Alloy and Stainless Steel in the Presence of Chlorides,” Oxidation of Metals, 2, 2, pp. 119-143, 1970.
    30. 王朝正、王裕賢、張永忠,"氯化鈉熱腐蝕之回顧", 防蝕工程, Vol. 12, No. 1, pp. 1-17, 1998.
    31. B. P. Mohanty and D. A. Shores, “Role of Chlorides in Hot Corrosion of a Cast Fe-Cr-Ni Alloy. Part I: Experimental Studies,” Corrosion Science, 46, pp. 2893-2907, 2004.
    32. 李清祺,"鐵鎳鉻合金於氯化鈉之高溫腐蝕反應機制",國立台灣科技大學機械所碩士論文,民國87年。
    33. N. Hiramatsu, Y. Uematsu, T. Tanaka, and M. Kinugasa, “Effects of Alloying Elements on NaCl-Induced Hot Corrosion of Stainless Steels,” Materials Science and Engineering, A120, pp, 319-328, 1989.
    34. T. Nartia, W. W. Smeltzer, and K. Nishida, Oxid. Met., 17(5/6) pp. 299-314, 1982.
    35. T. Nartia and W. W. Smeltzer, Oxid. Met., 21(1/2) pp. 39-55, 1984.
    36. T. Narita and K. Nishida, Proc. JIMIS-3. J. Inst. Met. Suppl., pp 457-464, 1983.
    37. K. N. Strafford, W. Y. Chan, and J. F. Norton, Proc. 8th Int. Congr. On Metallic Corrosion, Mainz, DECHEMA, Frankfurt, Vol. 2, pp. 1576-1584, 1981.
    38. Y. Shinata, F. Takahashi, and K. Hashiura, “NaCl-induced Hot Corrosion of Stainless Steel,” Mater. Sci. Eng., 87, p. 399, 1987.

    QR CODE