研究生: |
黃瑋倫 Wei-Lun Huang |
---|---|
論文名稱: |
製備硫化銅鋅錫多層次微奈米球結構光觸媒分解水製氫之研究 Preparation of Cu2ZnSnS4 Hierarchical Microspherical Photocatalysts for H2 Generation by Water Splitting |
指導教授: |
陳良益
Liang-Yih Chen |
口試委員: |
陳景翔
Ching-Hsiang Chen 許世杰 Shih-Chieh Hsu |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2014 |
畢業學年度: | 102 |
語文別: | 中文 |
論文頁數: | 100 |
中文關鍵詞: | 光觸媒 、製氫 、硫化銅鋅錫 |
外文關鍵詞: | photocatalysts, hydrogen generation, Cu2ZnSnS4 |
相關次數: | 點閱:175 下載:0 |
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本研究主要利用硫化銅鋅錫做為光觸媒產氫的材料,經過簡單的低溫溶劑熱法合成出硫化銅鋅錫花狀多層次微米球。硫化銅鋅錫花狀多層次微米球具有好的分散性與高比表面積。當光觸媒與電解液接觸時可以提供更多的活性點。針對製程條件,在本研究中考慮了反應前驅物、反應溶劑及反應時間對合成硫化銅鋅錫花狀多層次微米球的影響。同時,利用電子顯微鏡、X-光繞射儀、光電子光譜儀、紫外光-可見光吸收光譜儀、能量色散光譜儀、拉曼、BET等分析技術,針對所合成的硫化銅鋅錫花狀多層次微米球進行形態、晶體結構、元素組成、光學性質、比表面積、進行分析。同時,將合成的硫化銅鋅錫花狀多層次微米球利用光化學沉積法將白金被覆於表面,以提供更多的活性點。將負載白金的硫化銅鋅錫花狀多層次微米球添加至犧牲試劑內,利用300瓦氙燈照射,進行光觸媒產氫之可行性評估。
In this stady, copper zinc tin sulfide (Cu2ZnSnS4, CZTS) flowerlike microspherical photocatalysts were synthesized by solvothermal method for hydrogen generation by water splitting process. The CZTS flowerlike microspherical photocatalysts own good dispersion and high specific surface areas for providing many activity sites in aqueous solution. Herein, the precursor species, reaction solvents and reaction time were used as parameters for studying the influenec on the synthesis process of CZTS flowerlike microspherical photocatalysts. In addition, electron microscopy, X-ray diffractometer, X-ray photoelectron spectroscopy, UV-visible absorption spectroscopy, energy dispersive spectrosopy, Raman spectroscopy and BET were used to characterize the morphology, crystallinity, composition, optical properties and specific surface areas of CZTS flowerlike microspherical photocatalysts. At the same time, a photosynthesis method was employed to deposit Pt co-catalysts on the surfaces of CZTS flowerlike microspherical photocatalysts to provide more many activity sites. In this thesis, the synthesized CZTS flowerlike microspherical photocatalysts were added into the the aqueous solution with sacrificial reagents to evaluate the possibility for hydrogen generation by using CZTS flowerlike microspherical photocatalysts under the irradiation of 300 W Xeron lamp.
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