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研究生: 陳穎平
Ying-Ping Chen
論文名稱: 質子交換膜燃料電池系統之模型與分析
Modeling and analysis of proton exechange membrane fuel cell system
指導教授: 陳亮光
Liang-Kuang Chen
口試委員: 王英才
Ying-Tsai Wang
陳柏全
B.O. Chen
學位類別: 碩士
Master
系所名稱: 工程學院 - 機械工程系
Department of Mechanical Engineering
論文出版年: 2005
畢業學年度: 93
語文別: 中文
論文頁數: 66
中文關鍵詞: 燃料電池動態模型質子交換膜
外文關鍵詞: fuel cell, dynamic model, proton exchange membrane
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  • 質子交換膜燃料電池效率高,無污染。為目前國內積極研發之電源供應裝
    置。為使質子交換膜燃料電池可正常運作,須配合其他元件架構一燃料電池系統
    以確保氣體之正常供應。本文使用HPOWER-PS250 為燃料電池本體來架構完整電
    池系統。為達成燃料電池之系統整合,需要一完整之模型正確的描述燃料電池之
    性能與特性。本研究根據文獻中之燃料電池靜態模型、氣體壓力動態模型及等效
    電路模型,再整合此HPOWER 燃料電池特有之各部元件,發展成一完整之動態模
    型來描述該質子交換膜燃料電池系統之性能表現。最後再利用一系列之實驗來驗
    證所發展之系統模型,結果顯示此模型可正確描述系統性能。而其動態響應將對
    系統性能造成重大影響。


    Proton exchange membrane fuel cell (PEMFC) is high-efficient and
    pollution-free. Currently it is an actively researched alternative power supply
    device nationwide. For the PEMFC to operate normally, the stack must be
    equipped with supporting components that maintain the required fuel supply
    and operating conditions, thus forming an integrated fuel cell system. In this
    study, an HPOWER-PS250 fuel cell system is the basis of the structure and is
    to be analyzed and integrated. For the purpose of system integration, a model
    that can accurately describe the characteristics and behavior of this fuel cell
    system is needed. Therefore, in this study an integrated fuel cell system model
    is developed. The model is established based on the unique components of
    this fuel cell stack, and subsystem models that have been reported in the
    literature, including the static fuel cell model, the fluid dynamics model of the manifold and the flow channel, and the equivalent circuit model for the stack output. Finally, a series of experiments are conducted to verify the developed fuel cell system model. The results show that this model can accurately describe the characteristics and behavior of this fuel cell system. It is found that the dynamic response have significant effect to on the performance of the fuel cell system.

    中文摘要.……………………….………………………………….. Ⅰ 英文摘要.………………………………………….……………….. Ⅱ 誌謝………………………………………………………………… Ⅲ 目錄……………..………………………………………………….. Ⅳ 圖表索引………..………………………………………………….. Ⅵ 第一章 緒 論…………….………..……………………………… 1 1.1 前言……………………..…………………………………. 1 1.2 燃料電池簡介……………………………………………… 2 1.3 研究動機…………….………...……..……………………. 5 1.4 文獻探討…………………………………..………………. 6 1.4.1 質子交換膜燃料電池基本架構…………………...… 9 1.4.2 質子膜燃料電池之電化學模型………………...…… 12 1.5 論文大綱…………………………………..………………. 19 第二章 理論基礎…………………………………….…………… 20 2.1 PEMFC 內部電路等效模型………..……………………….. 20 2.2 氣體動力學…………..…………………………………….. 22 2.3 結合電容效應及氣體動力學之燃料電池系統動態模型… 24 2.4 電腦模擬結果……………………………………………… 25 第三章 實驗結果與分析…………………………………………. 30 3.1 燃料電池系統架構與建立………….……….…………….. 30 3.1.1 250W 質子膜燃料電池組(HPower-PS250) ….……… 32 3.1.2 燃料電池空氣流道系統….………………………...… 33 3.1.3 燃料電池氫氣流道系統….……………...…………… 36 3.1.4 直流電子負載….…………………….…………..…… 38 3.1.5 燃料電池系統介面電路及操作程式….……………... 39 3.2 燃料電池(HPOWER-PS250)之性能測試…………………… 40 3.3 燃料電池(HPOWER-PS250)之電容效應測試……………… 45 3.4 空氣壓力對燃料電池(HPOWER-PS250)輸出之影響……… 50 3.5 同時改變電流與空氣壓力,燃料電池之電壓輸出情形.... 55 第四章 結論…………………………….………………………… 59 4.1 總結………………………………………………………… 59 4.1 結論………………………………………………………… 59 4.2 未來工作與展望….…………..……………………………. 60 參考文獻…………………………………………………………… 61 附錄………………………………………………………………… 63 作者簡介…………………………………………………………… 65 授權書……………………………………………………………… 66

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