研究生: |
王建富 Chien-fu Wang |
---|---|
論文名稱: |
聚乙二醇烷基醚之改質及其界面性質 Modifications of polyoxyethylenated alkyl ether and their surface activities |
指導教授: |
陳耿明
Keng-ming Chen |
口試委員: |
郭中豐
Chung-Feng Kuo 許應舉 Ying-Gev Hsu 蘇清淵 Ching-Iuan Su 林河木 Ho-Mu Lin 王英靖 Ying-jing Wang 劉興鑑 Xing-jian Liu |
學位類別: |
博士 Doctor |
系所名稱: |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
論文出版年: | 2010 |
畢業學年度: | 98 |
語文別: | 中文 |
論文頁數: | 120 |
中文關鍵詞: | 生物分解性改質 、界面活性 、多陰離子改質 、相互作用 、粒徑 、複合體結構 |
外文關鍵詞: | biodegradable modified, surface activity, multi-anionic modified, interaction, particle size, complex formation |
相關次數: | 點閱:380 下載:7 |
分享至: |
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摘 要
本論文係探討ㄧ系列改質界面活性劑之合成及界面性質,以非離子聚乙二醇十八烷基醚界面活性劑為主體,內容包括二種新型機能性界面活性劑之改質。
第一部分為將非離子聚乙二醇十八烷基醚導入糊精改質成生物分解性,並探討其在染色工業上之應用,此項改質除增加界面活性劑之活性(可提高織物洗淨力及精練漂白處理後之織物白度)外,又具有生物可分解性,在環境問題上可降低污染。
所合成的產物以元素分析、紅外線光譜分析及核磁共振光譜確認其構造,所測試之界面性質包括表面張力、接觸角、起泡性等。在精練漂白上,合成產物可使棉布白度增加且吸水性增加,表示其有良好之精練性。
合成產物之生物分解性改質界面活性劑因構造中同時具有多種疏水基及親水基,呈現界面活性劑之特殊構造及良好的界面性質,較傳統界面活性劑更具附加價值。
第二部分為非離子之聚乙二醇十八烷基醚構造中導入陰離子,形成多種親水基改質之陰非離子界面活性劑,除基本性質如表面張力、起泡性、濕潤性等機能外,並測定應用性質之染料與界面活性劑之相互作用、染色性,了解染色機構,以作為染色助劑之用途。
由直接染料染棉之染著情形及與染料-助劑間之相互作用,結果顯示皆因染料構造不同,染料-助劑複合體凝集或解凝集之作用,造成染色有促染或緩染之效果。
ABSTRACT
In this study, a series of modified surfactants were prepared and the surface activities were investigated. It relied mainly on surface activity of nonionic polyoxyethylenated stearyl ether. The content includes two kinds of new function modified surfactants.
Part 1 contains the preparation of biodegradable modified surfactants by reacting dextrin-derived with polyoxyethylenated stearyl ether. The surface active properties for fabrics were improved for application in dyeing industry. Besides the increasing surface activity of surfactants, can to improve the whiteness of cotton fabric, cleaning power and biodegradable to reduce environmental pollution.
The structure of these surfactants has been confirmed by EA, FTIR and 1H-NMR while the surface activities were evaluated by surface tension, contact angel and foaming properties. These surfactants exhibit excellent functional properties of surface activities. In application on cotton bleaching procedures, these surfactants increase the wetting power of the fibers of grey fabrics and also increase the whiteness of bleached cotton.
Biodegradable modified surfactants possess hydrophilic groups and hydrophobic groups, exhibiting specific structure and surface activities better than traditional surfactants.
Part 2 contains the preparation of multi-anionic modified surfactants were prepared by reacting anionic with nonionic polyoxyethylenated stearyl ether. For multi-anionic and nonionic hydrophilic surfactant, possess the function properties including surface tension, foam properties and wetting, can use dye auxiliary to determine interaction of dye and surfactant, dyeability and dyeing mechanism.
The dyeing properties on cotton-direct dye systems were studied via the spectrophotometric method. The aggregation of direct dyes in dye-surfactant systems was found to influence the rate of cotton dyeing. The disaggregations of direct dyes in the presence of surfactants increase the dye uptake of cotton. On the other hand, the formations of dye-surfactant complex retard the speed of dye uptake at leveling fabric dyeing.
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