錳系氧化物觸媒材料用於鋅空氣電池陰極之研究｜國立臺灣科技大學博碩士論文系統

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研究生：	陳冠廷 Guan-Ting Chen
論文名稱：	錳系氧化物觸媒材料用於鋅空氣電池陰極之研究 Study of Manganese-based Oxide Catalysts as the Cathode for Zinc-Air Battery
指導教授：	郭俞麟 Yu-Lin Kuo
口試委員:	周宏隆 Hung-Lung Chou 王丞浩 Chen-Hao Wang 吳錦貞 Ching-Chen Wu
學位類別：	碩士 Master
系所名稱：	工程學院 - 機械工程系 Department of Mechanical Engineering
論文出版年：	2018
畢業學年度：	107
語文別：	中文
論文頁數：	136
中文關鍵詞：	鋅空氣電池、錳系氧化物觸媒、陰極
外文關鍵詞：	Zinc-Air Battery, Manganese-based Oxide Catalysts, Cathode
相關次數：	點閱：230 下載：0
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本研究主要探討錳系氧化物觸媒應用於鋅空氣電池陰極端之氧氣還原反應(ORR)活性，實驗分為三部分討論，第一部分材料選用純相系列之錳系觸媒，第二部分是將乾電池放電過後之正極錳材以不同溫度進行燒結而得一系列回收乾電池之錳系觸媒，試圖將材料還原至最初狀態，第三部分則使用不同燒結溫度而得一系列錳礦之錳系觸媒，將以上各種錳系觸媒作為空氣電極並進行電化學活性分析。

The research primarily discuss the oxygen reduction reaction of manganese-based oxide catalysts as the cathode for zinc-air battery.The choise of catalysts was divided into three parts, in the first part, choosing a series of pure phase materials; the second part, sintering the discharged dry battery powder for different temperature to obtain a series of dry battery materials, and attempting reducting this material to the original condition; the third part, sintering the manganese ore to acquire a series of manganese ore materials. Using these catalysts as the cathode and executing the electrochemically active analysis.

誌謝 ................................................................... I
摘要 .................................................................. II
ABSTRACT ............................................................. III
目錄 .................................................................. IV
圖目錄 .............................................................. VIII
表目錄 .............................................................. XIII
第一章 序論 ............................................................ 1
1 前言 .............................................................. 1
2 儲能技術............................................................ 2
3 空氣電池............................................................ 3
4 研究動機 ........................................................... 4
第二章 文獻回顧 ........................................................ 5
1 電池簡介 ........................................................... 5
1.1 化學電池原理 ..................................................... 8
1.2 一次電池 ......................................................... 9
1.3 二次電池 ........................................................ 10
1.4 燃料電池 ........................................................ 12
2 金屬空氣電池 ...................................................... 13
2.1 金屬空氣電池發展史................................................ 13
2.2 金屬空氣電池之特性................................................ 13
2.3 金屬空氣電池之機制................................................ 15
3 鋅空氣電池 ........................................................ 16
3.1 陽極之氧化反應 .................................................. 17
3.2 陰極之還原反應 .................................................. 18
3.3 鋅陽極之添加劑 .................................................. 19
3.4 電解液 ......................................................... 20
4 空氣電極之組成 .................................................... 20
4.1 氣體擴散層 ...................................................... 22
4.2 集電網 ......................................................... 23
4.3 催化層 ......................................................... 23
4.4 黏結劑 ......................................................... 23
4.5 碳材 ........................................................... 23
4.6 空氣陰極之觸煤 .................................................. 24
5 鈣鈦礦 ........................................................... 27
6 二氧化錳 ......................................................... 29
第三章 實驗程序 ....................................................... 33
1 實驗流程 ......................................................... 33
2 實驗藥品 ......................................................... 34
3 實驗設備 ......................................................... 35
4 實驗方法 ......................................................... 36
4.1 以固態法製備α 相二氧化錳觸煤粉末.................................. 36
4.2 製備商用觸媒粉末 ................................................ 37
4.3 製備乾電池回收系列觸媒粉末 ....................................... 38
4.4 製備錳礦系列觸媒粉末 ............................................ 39
4.5 空氣陰極之製備 .................................................. 40
4.6 檢測儀器 ....................................................... 41
4.7 空氣陰極之氧氣還原活性測試 ....................................... 42
4.8 鋅空氣電池之全電池充放電測試 ..................................... 43
4.9 空氣陰極之電化學阻抗頻譜分析 ..................................... 44
第四章 結果與討論 ..................................................... 45
1 錳系氧化物之陰極觸媒材料製備與鑑定分析 .............................. 46
1.1 以純相系列材料製備錳系氧化物之陰極觸媒 ............................ 46
1.2 以回收乾電池之正極含錳系列材料製備錳系氧化物之陰極觸媒 ............. 56
1.3 以錳礦系列材料製備錳系氧化物之陰極觸媒 ............................ 61
2 空氣陰極之電化學活性分析 ........................................... 66
2.1 純相系列與錳礦系列材料之線性掃描伏安法(LSV)測試.................... 66
2.2 回收乾電池系列材料之線性掃描伏安法(LSV)測試........................ 67
3 組裝全電池充放電循環壽命分析 ....................................... 71
3.1 純相系列材料之充放電循環壽命測試 ................................. 71
3.2 回收乾電池系列材料之充放電循環壽命測試 ............................ 78
3.3 錳礦系列材料之充放電循環壽命測試 ................................. 84
4 全電池電化學阻抗頻譜(EIS)分析....................................... 88
5 組裝鋅空氣電池之全電池放電測試 ..................................... 104
第五章 結論與未來展望 ................................................. 109
1 實驗結論 ......................................................... 109
2 未來展望 ..........................................................110
參考文獻 ............................................................. 111
                                

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