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研究生: 許韶津
Shao-chin Hsu
論文名稱: 以鈦酸鋰改善二硫化鉬作為陽極材料應用於鋰離子電池之研究
Using lithium titanate to improve molybdenum disulfide on anode material for lithium-ion batteries
指導教授: 何郡軒
Jinn-Hsuan Ho
戴龑
Yian Tai
口試委員: 何郡軒
Jinn-Hsuan Ho
江佳穎
Chia-Ying Chiang
鄧熙聖
His-Sheng Teng
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2020
畢業學年度: 109
語文別: 中文
論文頁數: 94
中文關鍵詞: 二硫化鉬鈦酸鋰鋰離子電池
外文關鍵詞: molybdenum disulfide, lithium titanate, lithium-ion batteries
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  儲能陽極材料中,二硫化鉬因具有層狀結構利於鋰離子嵌入,但嵌入鋰離子至一定程度後,會分解原本二硫化鉬的結構產生金屬鉬與硫化鋰,硫化鋰進而產生的多硫化物會導致穿梭效應,造成循環使用壽命不佳。本研究設計改善二硫化鉬作為陽極電極應用於鋰離子電池時具有循環使用壽命不佳的問題。
  本研究採用鈦酸鋰作為抑制物質以抑制硫化鋰作為活物所發生的穿梭效應為目標,利用鈦酸鋰與多硫化物做化學鍵結,以及擁有比表面積大的優點,使反應所產生的硫化鋰或單質硫能夠有更高選擇性吸附於鈦酸鋰表面,進而在充放電表現上大幅改善二硫化鉬電容量急速降低的問題,繼而增加整體材料的循環使用壽命,並藉由添加的鈦酸鋰之電子傳導性佳使得電極擁有較低電阻值,固可提升電池效能。


In the energy storage anode material, molybdenum disulfide has a layered structure that facilitates lithiation, but after lithiation to a certain extent, it will decompose the original structure of molybdenum disulfide to produce metal molybdenum and lithium sulfide, and the polysulfide generated by lithium sulfide. It can cause a shuttle effect, resulting in poor cycle life. This research design improves the problem of poor cycle life when molybdenum disulfide is used as an anode electrode in lithium-ion batteries.
In this thesis, lithium titanate was used as the inhibitory substance to suppress the shuttle effect of lithium sulfide as an active material. It uses lithium titanate and polysulfide for chemical bonding and has a large specific surface area, caused lithium sulfide and sulfur can be adsorbed on the surface of lithium titanate with higher selectivity. Which it greatly improves the problem of the rapid decrease in the capacity of molybdenum disulfide in charge and discharge performance, and then increases the cycle life of the material. Lithium titanate has good electronic conductivity, so the electrode has a low resistance value, which can improve battery performance.

中文摘要 I Abstract II 致謝 III 目錄 IV 圖目錄 VII 表目錄 XI 第一章 緒論 1 1-1前言 1 第二章 原理與文獻回顧 3 2-1鋰離子二次電池 3 2-1-1發展 3 2-1-2電池機制 5 2-2鋰離子電池組成 5 2-2-1隔離膜 6 2-2-2電解液 7 2-2-3陰極(正極)材料 8 2-2-4陽極(負極)材料 10 2-3金屬硫化物 12 2-3-1過渡金屬硫化物 12 2-3-2二硫化鉬 13 2-4鋰硫電池 17 2-5極性材料抑制多硫化物 20 2-5-1極性金屬氧化物 21 2-5-2極性有機物 21 2-5-3鈦酸鋰 22 2-6研究動機與目的 25 第三章 實驗設備與方法 26 3-1儀器設備 26 3-2實驗藥品與器材 27 3-3實驗步驟 28 3-3-1實驗架構流程圖/分析儀器 28 3-3-2電池製備流程圖 29 3-3-3電極製備 29 3-3-4鈕扣型電池組裝 30 3-3-5臨場實驗之鈕扣型電池組裝 31 3-4材料鑑定與分析 32 3-5電化學分析 40 第四章 實驗結果與討論 43 4-1活物粉體與電極分析 43 4-1-1活物粉體與電極晶相分析 43 4-1-2活物粉體與電極表面分析 45 4-2混用鈦酸鋰之電化學特性分析 47 4-2-1充放電曲線分析 48 4-2-2電化學反應平台分析 52 4-2-3交流電阻抗現象分析 54 4-3離場分析 55 4-3-1鍵結與表面型態分析 56 4-3-2多硫化物損失量之吸收分析 60 4-4臨場分析 61 4-4-1臨場X光繞射實驗 62 4-4-2臨場X光吸收實驗 65 第五章 結論與未來展望 73 文獻參考 74

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