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研究生： 陳品嫻
Pin-sian Chen
論文名稱： 具噻吩并吡之染料敏化太陽能電池染料合成與研究
Synthesis and Study of Thieno[3,4-b]pyrazine Based Dyes for Dye Sensitized Solar Cells
指導教授： 何郡軒
Jinn-Hsuan Ho
口試委員: 張家耀
Jia-Yaw Chang
戴 龑
Yian Tai
學位類別： 碩士
Master
系所名稱： 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年： 2014
畢業學年度： 102
語文別： 中文
論文頁數： 165
中文關鍵詞： 染料敏化太陽能電池
外文關鍵詞： thieno[3 4-b]pyrazine, Dye-Sentized Solar Cells
相關次數： 點閱：214  下載：4 
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  •  上一筆

    • 本論文合成出一系列具有噻吩并[3,4-b]吡的有機敏化染料，以加入中間拉電子基噻吩并[3,4-b]吡 於D-A-π-A系統取代傳統的D-π-A系統，目的是增加分子內電子從推電子基到拉電子基及錨基上，調控更好的電子能階，使得分子最大吸收波長能夠到紅外光區(620 -740 nm)而六種有機染料是利用Suzuki coupling、Stilling coupling和Knoevenagel reaction方法合成，以三苯胺作為推電子基、噻吩并[3,4-b]吡為中間拉電子基、不同π共軛橋基與Cyanoacrylic acid為拉電子基，並以核磁共振光譜譜（NMR）以及質譜儀（MASS）鑑定結構。利用紫外/可見光光譜儀與循環電位儀去探討六種染料的光電性質。

    In this research, a series of organic sensitizers based on thieno[3,4-b]pyraizne has been synthesized for dye-sensitized solar cells (DSSCs). We have used thieno[3,4-b]pyrazine as the additional acceptor in the D-A-π-A system, instead of a D-π-A system. This D-A-π-A system, results in the increase of the maximum absorption band to red light region (620 – 740 nm) due to increasing electron density from donor to acceptor and has better regulation of the electronic energy levels. Six organic dyes synthesized with Suzuki coupling, Stilling coupling and Knoevenagel reaction contain triphenylamine as donor, heteroaryl group as π bridge, thieno[3,4-b]pyraizne and cyanoacrylic acid as acceptors. Use nuclear magnetic resonance spectroscopy (NMR) and mass spectrometry (MASS) to identify the structures and use UV / visible spectroscopy and cyclic potential instrument to discuss the photophyscial and electrochemical properties.

    第一章 緒論 1 1-1 前言 1 1-2 太陽能電池簡介 1 1-3 染料敏化太陽能電池的發展 3 1-4 染料敏化太陽能電池結構及工作原理 3 1-5 影響染料敏化太陽能電池的效率 5 1-6 染料光敏化劑 5 1-6-1 釕金屬錯合物染料 7 1-6-2 非有機金屬染料 9 1-6-3 Triphenylamine染料 11 1-7 染料敏化劑的設計 13 1-8 研究動機與目的 18 第二章 結果與討論 20 2-1 化合物之合成與討論 20 2-2 化合物於溶液中之光物理研究 24 2-3 莫耳吸收係數 30 2-4 光學性質討 34 2-5 電化學性質探討 36 2-6 化合物的理論計算結果探討 43 2-7 化合物的理論與實驗結果討論 48 2-8 元件效率 49 第三章 結論 51 3-1 結論 51 3-2 未來展望 52 第四章 實驗部份 53 4-1 實驗儀器 53 4-2 實驗藥品與溶劑 54 4-3 吸收度量測方法 56 4-4 莫耳吸收係數量測方法 57 4-5 實驗步驟 58 第五章 參考文獻 80

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