研究生: |
洪壽邦 Shou-Bang Hong |
---|---|
論文名稱: |
水相合成鎵摻雜之CuInSe2量子點及其量子點敏化太陽能電池應用 Aqueous synthesis of Ga-doped CuInSe2 quantum dots and its application in quantum dots sensitized solar cell |
指導教授: |
張家耀
Jia-Yaw Chang |
口試委員: |
何郡軒
李昇隆 |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2017 |
畢業學年度: | 105 |
語文別: | 中文 |
論文頁數: | 82 |
中文關鍵詞: | 銅銦硒三元量子點 、量子點敏化太陽能電池 、水相合成 、摻雜 |
外文關鍵詞: | CISe QDs, QDSSCs, Aqueous synthesis, Doping |
相關次數: | 點閱:306 下載:1 |
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本研究利用微波輔助合成法,將低毒性金屬前驅物與雙功能分子於水相系統中反應以合成三元半導體CuInSe2量子點,並將其應用於量子點敏化太陽能電池以製備出高效率的電池元件。此種合成技術相較於傳統有機製程,具有快速且簡易的合成、環境友善性佳等優勢,使其具有發展的潛力。
研究內容分成兩部分,第一部分為藉由調控前驅物銅銦莫耳數比,改善量子點的吸光範圍及填補其本身的內部缺陷,在銅銦比例1:3時有最佳光電轉換效率8.24%。此外,由元件的電化學阻抗分析與光強度調製光電流/光電壓分析儀分析,探討電子內部的傳遞動力學及界面阻抗之影響;第二部分為藉由鎵元素摻雜於不同銅銦比例之量子點,以提升光電轉換效率,其中在銅銦比例1:3時,效率可由原本的8.24%進一步的提升至8.68%,根據我們的了解,這是目前在水相製程中最佳的效率。
In this study, we demonstrated the synthesis of CuInSe2 (CISe) quantum dots (QDs) by microwave-assisted method in aqueous phase for quantum dots sensitized solar cells (QDSSCs). The CISe QDs were synthesized by the rapid reaction of low-toxic metal precursors and short-chain bi-functional molecules in the absence of organic solvents. Compared to traditional hot-injection and heating-up methods by using of organic solvents, aqueous synthesis has advantages of rapid, simple, and environmentally friendly.
This research was divided into two parts. The first part was by adjusting the copper to indium (Cu/In) ratio of CISe QDs to improve the absorption range and modify the internal defects, which effectively enhanced the photoelectric conversion efficiency (PCE) up to 8.24%. The electrochemical impedance spectroscopy (EIS) analysis and intensity modulated photocurrent / photovoltage spectroscopy (IMPS/IMVS) showed the internal electron transfer and impedance of the interface. The second part was by doping gallium (Ga) into different Cu/In ratio of CISe QDs and further boosted the photoelectric conversion efficiency up to 8.68%. Based on our knowledge, this is the best efficiency of QDSSCs in direct aqueous synthesis.
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