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研究生: 李竑慶
HUNG-CHING LEE
論文名稱: 奈米氧化物對具多孔性陽極氧化 鋁膜之玻璃基板的光學特性影響
Effect of Nanometer Oxide on the Optical Properties of Glass Substrate with Porous Anodic Aluminum Oxide Film
指導教授: 陳士勛
Shih-Hsun Chen
口試委員: 陳柏均
Po-Chun Chen
丘群
Chun Chiu
學位類別: 碩士
Master
系所名稱: 工程學院 - 機械工程系
Department of Mechanical Engineering
論文出版年: 2019
畢業學年度: 107
語文別: 中文
論文頁數: 66
中文關鍵詞: 陽極氧化鋁氧化鋅磁控射頻濺鍍機可見光光譜儀穿透度
外文關鍵詞: Anodic aluminum oxide, ZnO, Magnetron RF Sputtering, UV-visible spectroscopy, Transmittance
相關次數: 點閱:291下載:10
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  • 本研究在玻璃基板上建立半透明微奈米陣列結構,改善玻璃的光學特性,並於奈米結構上方濺鍍金屬鋅,再經過氧化處理成為氧化鋅薄膜,探討光波經過光學薄膜層所產生吸收或穿透的光學改變量。製程主要是利用磁控射頻濺鍍機在透光玻璃基板上沉積鋁薄膜;並透過電化學加工,建立具有奈米孔洞陣列結構的氧化鋁薄膜(AAO),達到結構奈米化,同時借助其透明之特性,有利於光學穿透度分析與探討。透過改變陽極處理製程的電解液及電壓值,得到草酸電解液在40 V電壓以及磷酸在125 V電壓時,能做出符合尺寸奈米化的完整結構,並直接影響光學特性。以可見光譜測量儀分析可見光範圍內的光波變化量;又因奈米化結構使得氧化鋅薄膜能夠更均勻沉積在微結構的表面,達到穿透度改善的效益;並觀察到氧化鋅薄膜在紫外光波段有選擇性吸收的效果,透過驗證發現,光波在386.3nm有一個吸收峰值,使光波產生吸收效應。每步驟所需要的尺寸驗證,皆使用場發射掃描式電子顯微鏡 (Field Emission Scanning Electron Microscope, FE-SEM),其能同步呈現形貌與微結構尺寸量測,並以X光繞射儀(XRD)確認氧化鋅材料的成分結構。


    In this study, a microstructure was set on the glass to change the transmittance of light. Zinc were deposited on the glass substrate by magnetic reactive sputtering with anodic aluminum oxide (AAO) template, after that the ZnO nanoparticles were prepared by thermal oxidation. The procedure of the experiment was mainly used magnetron RF Sputter to deposit Al film on the glass with transmittance and also processed the Al into nano porous structure by using electrochemical process Moreover, the analysis of the optical penetration is attribute to the nano porous structure and transparency of AAO.During the manufacturing process, the electrolyte with anodic treatment and the voltage was changed in order to analyze the variation of light by using Ultraviolet/Visible spectroscopy. In addition, due to the benefit of nano porous structure, ZnO film could deposit on the surface much more homogeneously, improving the transparency Therefore, the study observed that ZnO film had the character of selective absorption in ultraviolet band. For example, it was proved that the ZnO film was opaque in the range of 386.3 nm of the light.
    Lastly, the each step of measurement test including used the Field Emission Scanning Electron Microscope (FE-SEM), which could not only show the shape, but also measure the microstructure, as well as make sure the ingredient of ZnO material by X-ray Diffraction (XRD).

    致謝 摘要 Abstract 目錄 圖目錄 表目錄 第1章 序論 1.1 前言 1.2 研究背景 1.3 研究動機 第2章 文獻回顧 2.1 玻璃研究 2.2 沉積薄膜研究 2.2.1 物理氣相沉積(Physical Vapor Deposition,PVD) 蒸鍍(Evaporation) 濺射(Sputter) 真空濺射種類 2.3 陽極氧化鋁(Anodic Aluminum Oxide, AAO) 2.3.1 陽極氧化應用 2.4 氧化鋅特性 2.5 文獻回顧總結 第3章 實驗方法與步驟 3.1 實驗流程圖 3.2 實驗設備 3.3 實驗步驟 3.4 實驗參數 3.5 實驗分析與儀器原理 3.5.1 場發射掃描式電子顯微鏡(FE-SEM) 3.5.2 X光繞射儀(X-ray Diffraction) 3.5.3 可見光譜量測儀(UV-visible) 第4章 結果與討論 4.1 濺鍍鋁膜表面與橫截面觀察 4.1.1 橫截面微觀結構 4.2 陽極處理分析 4.2.1 外觀形貌 4.2.2 橫截面微觀結構 4.2.3 光學特性分析 4.2.4 陽極處理時間 4.3 氧化鋅分析 4.3.1 外觀形貌 4.3.2 橫截面微觀結構 4.3.1 光學特性分析 4.3.2 鋅氧化處理 第5章 結論與未來展望 第6章 參考文獻

    [1] S. Walheim, "Nanophase-Separated Polymer Films as High-Performance Antireflection Coatings", Science Vol 283,1999.
    [2] 馬遠榮, "低維奈米材料", 科技大觀園, 2004.
    [3] O. Jessensky, "Self-organized formation of hexagonal pore arrays in anodic alumina", Phys. Lett. 72, 1173 (1998)
    [4] R. Hong, "Influence of buffer layer thickness on the structure and optical properties of ZnO thin films", Science 252 (2006)
    [5] N. Padmavathy, "Enhanced bioactivity of ZnO nanoparticles—an antimicrobial study", Science and Technology of Advanced Materials, 2008.
    [6] P. Petkova, A. Francesko, I. Perelshtein, A. Gedanken, and T. Tzanov, "Simultaneous sonochemical-enzymatic coating of medical textiles with antibacterial ZnO nanoparticles", Ultrason Sonochem, vol. 29, pp. 244-50, Mar 2016.
    [7] F. Porter, "Zinc Handbook: Properties, Processing, and Use in Design. CRC Press", 1991.
    [8] W. J. Lin, "Fabrication of highly c-axis oriented ZnO thin films for UV photodetector applications by PECVD", 2014.
    [9] K. Hoshino, "Fundamentals of Nano/Microfabrication and Effect of Scaling", 2014.
    [10] Kenneth Chang, The Nature of Glass Remains Anything but Clear, The New York Times, 2008-07-29
    [11] W. F. Wu, "Properties of radio frequency magnetron sputtered silicon dioxide film", Applied Surface Science, Volume 99, Issue 3, 1996,
    [12] B. Y. Fang, "Optical properties of vanadium dioxide thin film in nanoparticle structure", Optical Materials, vol. 47, 2015.
    [13] J. Vossen, "Thin Film Process,Academic Process ", 1999.
    [14] I. Thomson, "VLSI製造技術", 2006.
    [15] H. B. Z. T.M. Rodgers, H.N.G. Wadley, J. Vac, "Vapor deposition on doublet airfoil substrates: coating thickness control" 2015.
    [16] 楊雲凱, "物理氣相沉積(PVD)介紹", 奈米通訊
    [17] B. Wang, "vacuum" vol.48, NO.5, 1997
    [18] H. C. Arslan, I. Yusufoglu, "Structural and optical characterizations of porous anodic alumina–aluminum nanocomposite films on borofloat substrates" Optical Engineering, vol. 53, no. 7, p. 071822, 2014.
    [19] L. Zaraska, G. Sulka, "Anodic Porous Alumina as a Template for Nanofabrication.", 2011
    [20] P. Boryło, "The influence of atomic layer deposition process temperature on ZnO thin film structure", Applied Surface Science, vol. 474, pp. 177-186, 2019.
    [21] S. Yadav, M. Pashchanka, "Porous alumina-metallic Pt_Pd Cr or Al layered nanocoatings with fully controlled variable interference colors. Science ", 1897–1899.
    [22] D. Cullity, "Elements of X-ray diffraction, Addison-Wesley", 1967.
    [23] 黃淑綺, "以反應式濺鍍製備氧化鋅薄膜及其摻雜之研究", 2006.
    [24] V. Galstyann "Nanostructured ZnO chemical gas sensors”, Ceramics Internationa", 2015.
    [25] P. CHOWDHURY, "Effect of process parameters on growth rate and diameter of nano-porous alumina templates", 2010

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