研究生: |
林旻嫻 Min-Hsien Lin |
---|---|
論文名稱: |
碳氮化硼與超奈米鑽石於矽奈米線複合結構之超級電容特性研究 Hybrid Nanostructures of Boron Carbon Nitrides with Ultra-nanocrystalline Diamond on Silicon Nanowires for Supercapacitor Properties |
指導教授: |
黃柏仁
Bohr-Ran Huang |
口試委員: |
張立
周賢鎧 |
學位類別: |
碩士 Master |
系所名稱: |
電資學院 - 電子工程系 Department of Electronic and Computer Engineering |
論文出版年: | 2023 |
畢業學年度: | 112 |
語文別: | 中文 |
論文頁數: | 339 |
中文關鍵詞: | 矽奈米線 、磷 、超奈米鑽石 、碳氮化硼 、超級電容器 |
外文關鍵詞: | Silicon nanowires, Phosphorus, Ultra-nanocrystalline diamond, Boron Carbon Nitride, Supercapacitor |
相關次數: | 點閱:452 下載:0 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本研究探討碳氮化硼複合超奈米鑽石於不同結構之矽奈米線上作為超級電容器之應用,並探討退火後處理對於此結構之影響。內文將分為三個部分。第一部分分別探討超奈米鑽石、碳氮化硼及碳氮化硼複合超奈米鑽石於矽基板上之電化學感測,並探討以溫度800℃之退火後處理對此三種結構之影響,本部分較佳之參數為(BCN(1:2)-NUNCD_(10 min)/Si)N8其比電容值為10.007(F/g)。
第二部分將第一部分之矽基板改成矽奈米線,探討3D結構對電化學感測之影響,並探討以溫度800℃之退火後處理對此三種結構之影響: Type I: NUNCD/SiNWs、Type II: BCN/SiNWs、Type III: BCN-NUNCD/SiNWs;接著為了提升其電化學感測特性,將矽奈米線先與超奈米鑽石做結合,再跟碳氮化硼複合超奈米鑽石做結合形成BCN-NUNCD/NUNCD/SiNWs,並探討以溫度800℃之退火後處理對此結構之影響。在此部分發現利用矽奈米線結構,皆可以提升超奈米鑽石、碳氮化硼及碳氮化硼複合超奈米鑽石作為超級電容器之重量比電容值,而使用矽奈米線複合奈米鑽石結構可以更加有效的提升重量比電容值,並利用氮氣退火後處理,可發現電容值從18.93提升至123.91(F/g),其充放電循環穩定性可增加473.91%。表明此種BCN-NUNCD/NUNCD/SiNWs新型複合結構具有優異之循環穩定性。
第三部分則在探討矽奈米線做磷摻雜後之分析,並將第二部分較好之結果套用於矽奈米線做磷摻雜之基板上探討其超級電容器之特性。在此部分發現通過磷摻雜後皆會使其循環穩定性增加,本部分較佳之參數為(BCN(1:1)-NUNCD_(7.5 min)/NUNCD_(12.5 min)/PSG_(975℃ 30 min )-SiNWs_(20 min))N8其比電容值為33.193(F/g),其充放電循環穩定性可增加450%。
關鍵字:矽奈米線、磷、超奈米鑽石、碳氮化硼、超級電容器
This study is divided into three main parts. In the first part, we combined two materials: nanocrystalline diamond (NUNCD) and Boron Carbon Nitride (BCN) on silicon-Based, the optimal parameter in this section is (BCN(1:2)-NUNCD_(10 min)/Si)N8, which exhibits a specific capacitance of 10.007 (F/g).
The second part , we combined two materials: nanocrystalline diamond (NUNCD) and Boron Carbon Nitride (BCN) on silicon nanowires ,forming four types of novel composite structures: (i) NUNCD/SiNWs, (ii) BCN/SiNWs, (iii)BCN-NUNCD/SiNWs and(iv)BCN-NUNCD/NUNCD/SiNWs for supercapacitors. This study found that the silicon nanowires and ultra-nanodiamonds combined silicon nanowire can effectively improve the capacitance value of ultra-nanodiamonds, boron Carbon Nitride and ultra-nanodiamonds combined boron Carbon Nitride. After annealing the ultra-nanodiamonds combined boron Carbon Nitride on the ultra-nanodiamonds combined silicon nanowire substrate with nitrogen for 800 C, it can be found that the capacitance value is increased from 18.93 to 123.91 (F/g), and the charge-discharge cycle stability is improved 473.91%.
The third part, we found that the phosphorus doping can enhances cycle stability across all cases. The optimal parameter in this section is (BCN(1:1)-NUNCD_(7.5 min)/NUNCD_(12.5 min)/PSG_(975℃ 30 min )-SiNWs_(20 min))N8, which exhibits a specific capacitance of 33.193(F/g), and the charge-discharge cycle stability is improved 450%.
Keywords: Silicon nanowires, Phosphorus, Ultra-nanocrystalline diamond, Boron Carbon Nitride, Supercapacitor
[1].S.H.Wang, T.Wang, Corrosion-Resistant Functional Diamond Coatings for Reliable Interfacing of Liquid Metals with Solid Metals, ACS Applied Materials & Interfaces, 36 (2020), 40891-40900.
https://pubs.acs.org/doi/abs/10.1021/acsami.0c09428
[2].S.T. Lee, Z. Lin, CVD diamond films: nucleation and growth, Materials Science and Engineering: R: Reports, 25 (1999), 123-154.
https://www.sciencedirect.com/science/article/pii/S0927796X99000030
[3].Kui-Qing Peng, Xin Wanga, Silicon nanowires for advanced energy conversion and storage, nanotoday, 8 (2013), 75-97.
https://www.sciencedirect.com/science/article/pii/S1748013212001466
[4].Huang Ruia, Fan Xing, Carbon-coated silicon nanowire array films for high-performance lithium-ion battery anodes, Applied Physics Letters, 95 (2013), 133119.
https://www.scopus.com/record/display.uri?eid=2-s2.0-70349662178&origin=inward&txGid=62a87fc5bf6a68066be7622bfb4a957c
[5].Kelzenberg Michael D, Boettcher Shannon W, Enhanced absorption and carrier collection in Si wire arrays for photovoltaic applications, Nature Materials, 9 (2010), 239 – 244.
https://www.scopus.com/record/display.uri?eid=2-s2.0-77249164255&origin=inward&txGid=6a88c1526b81bc00e595cb038b75430a
[6].R. B. Weisman, New Frontiers in Nanocarbons, Electrochem. Soc. Interface, 22 (2013), 49.
https://doi.org/10.1149/2.F02133if
[7].H. W. Kroto, J. R. Heath, S. C. O'Brien, R. F. Curl and R. E. Smalley, C60: Buckminsterfullerene, Nature, 318 (1985), 162-163.
https://doi.org/10.1038/318162a0
[8].Patrick T.Moseleya, David A.J.Rand, Understanding the functions of carbon in the negative active-mass of the lead–acid battery: A review of progress, Journal of Energy Storage, 19 (2018), 272-290.
https://www.sciencedirect.com/science/article/pii/S2352152X18303955
[9].S.J. Kim, B.K Jul, Y.H. Lee, B.S. Park, Emission characteristic of diamond-tip FEA fabricated by transfer mold technique, IEEE, 526 (1996), 526-529.
https://doi.org/10.1109/IVMC.1996.601879
[10].Seiichiro Matsumoto, Yoichiro Sato, Mutsukazu Kamo and Nobuo Setaka, Vapor deposition of diamond particles from methane, Japanese Journal of Applied Physics, 21 (1982), L183.
https://doi.org/10.1143/JJAP.21.L183
[11].Arora, S. and V. Vankar, Field emission characteristics of microcrystalline diamond films: Effect of surface coverage and thickness, Thin Solid Films, 515(4) (2006), 1963-1969.
https://doi.org/10.1016/j.tsf.2006.08.002
[12].Ichiro Watanabe, Takashi Matsushita Takashi Matsushita and Koujyu Sasahara Koujyu Sasahara, Low-Temperature Synthesis of Diamond Films in Thermoassisted RF Plasma Chemical Vapor Deposition, Japanese Journal of Applied Physics, 31 (1992), 1428.
https://doi.org/10.1143/JJAP.31.1428
[13].O.A. Williams, M. Nesladek, M. Daenen, S. Michaelson, A. Hoffman, E. Osawa, K. Haenen, R.B. Jackman, Growth, electronic properties and applications of nanodiamond, Diamond and Related Materials, 17(7–10) (2008), 1080-1088.
https://doi.org/10.1016/j.diamond.2008.01.103
[14].Butler, J.E. and Sumant, A.V., The CVD of Nanodiamond Materials, Chemical Vapor Deposition, 14 (2008), 145-160.
https://doi.org/10.1002/cvde.200700037
[15].Shraddha Dhanraj Nehate, Sreeram Sundaresh, Hydrogenation of Boron Carbon Nitride Thin Films for Low-k Dielectric Applications, ECS Journal of Solid State Science and Technology, 10 (2021), 093001.
https://iopscience.iop.org/article/10.1149/2162-8777/ac210d
[16].Rongting Wu, Adrian Gozar, Large-area borophene sheets on sacrificial Cu(111) films promoted by recrystallization from subsurface boron, npj Quantum Materials volume , 4 (2019), 40.
https://www.nature.com/articles/s41535-019-0181-0
[17].Siby Thomas, Sang Uck Lee, Atomistic insights into the anisotropic mechanical properties and role of ripples on the thermal expansion of h-BCN monolayers, RSC Advances, 9 (2019), 1238-1246.
https://pubs.rsc.org/en/content/articlehtml/2019/ra/c8ra08076c
[18].Shayan Angizi, Md Ali Akbar, Review—Two-Dimensional Boron Carbon Nitride: A Comprehensive Review, ECS Journal of Solid State Science and Technology, 9 (2020), 083004.
https://iopscience.iop.org/article/10.1149/2162-8777/abb8ef
[19].Evgeni S. Penev, Somnath Bhowmick, Polymorphism of Two-Dimensional Boron, American Chemical Society, 5 (2012), 2441-2445. https://pubs.acs.org/doi/full/10.1021/nl3004754
[20].Walter R. L. Lambrecht, Benjamin Segall, Anomalous band-gap behavior and phase stability of c-BN–diamond alloys, PHYSICAL REVIEW B, 47 (1993), 9289.
https://journals.aps.org/prb/abstract/10.1103/PhysRevB.47.9289
[21].Md. Abdul Mannan, Yuji Baba, Hexagonal Nano-Crystalline BCN Films Grown on Si (100) Substrate Studied by X-Ray Absorption Spectroscopy, Materials Sciences and Applications, 4 (2013), 9
https://www.scirp.org/html/3-7700988_31618.htm.
[22].D.Y. Guo, P.G. Li, Z.W. Chen, Z.P. Wu, W.H. Tang, Ultra-wide bandgap semiconductor of β-Ga2O3 and its research progress of deep ultraviolet transparent electrode and solar-blind photodetector, Acta Phys. Sin., 68(7) (2019), 078501.
https://doi.org/10.7498/aps.68.20181845
[23].S. Abolhosseini, A. Heshmati, J. Altmann, A review of renewable energy supply and energy efficiency technologies, Cog. Eng. 8145 (2014).
https://dx.doi.org/10.2139/ssrn.2432429.
[24].Wang S, Wei T, Qi Z., Supercapacitor energy storage technology and its application in renewable energy power generation system. In: Goswami D.Y., Zhao Y. (eds) Proceedings of ISES World Congress 2007 (Vol. I–Vol. V). Springer, Berlin, Heidelberg.
https://doi.org/10.1007/978-3-540-75997-3_566
[25].W. Raza, F. Ali, N. Raza, Y. Luo, K.H. Kim, J. Yang, et al., Recent advancements in supercapacitor technology, Nano Energy, 52 (2018), 441-473.
https://doi.org/10.1016/j.nanoen.2018.08.013
[26].J. Xie, P. Yang, Y. Wang, T. Qi, Y. Lei, C.M. Li, Puzzles and confusions in supercapacitor and battery: theory and solutions, J Power Sources, 401 (2018), 213-223.
https://doi.org/10.1016/j.jpowsour.2018.08.090
[27].Binoy K. Saikia, Santhi Maria Benoy, Mousumi Bora, Joyshil Tamuly, Mayank Pandey, Dhurbajyoti Bhattacharya, A brief review on supercapacitor energy storage devices and utilization of natural carbon resources as their electrode materials, Fuel, 282 (2020), 118796.
https://doi.org/10.1016/j.fuel.2020.118796.
[28].N. Nitta, F. Wu, J.T. Lee, G. Yushin, Li-ion battery materials: present and future, Mater Today, 18 (5) (2015), 252-264.
https://doi.org/10.1016/j.mattod.2014.10.040
[29].Yanfang Xu, Weibang Lu, Guangbiao Xu, Tsu-Wei Chou, Structural supercapacitor composites: A review, Composites Science and Technology, 204 (2021), 108636.
https://doi.org/10.1016/j.compscitech.2020.108636
[30].N.P. Shetti, S. Dias, K.R. Reddy, Nanostructured organic and inorganic materials for Li-ion batteries: a review, Mater Sci Semicond Process, 104 (2019), 104684.
https://doi.org/10.1016/j.mssp.2019.104684
[31].R.E. Ruther, C.N. Sun, A. Holliday, S. Cheng, F.M. Delnick, T.A. Zawodzinski Jr., et al., Stable electrolyte for high voltage electrochemical double-layer capacitors, J Electrochem Soc (2017), A277-A283.
https://doi.org/10.1149/2.0951702jes
[32].Y. Luo, Q. Zhang, W. Hong, Z. Xiao, H. Bai, A High-performance electrochemical supercapacitor based on polyaniline/reduced graphene oxide electrode and copper (ii) ion active electrolyte, Phys. Chem. Chem. Phys., 20 (1) (2017), 131-136.
https://doi.org/10.1039/c7cp07156f
[33].G. Wang, L. Zhang, J. Zhang, A review of electrode materials for electrochemical supercapacitors, Chem. Soc. Rev., 41 (2012), 797-828.
https://doi.org/10.1039/C1CS15060J
[34].A. González, E. Goikolea, J.A. Barrena, R. Mysyk, Review on supercapacitors: technologies and materials, Renew. Sustain. Energy Rev., 58 (2016), 1189-1206.
https://doi.org/10.1016/j.rser.2015.12.249
[35].K. Poonam, A. Sharma, S.K. Arora, Tripathi, review of supercapacitors: materials and devices, J. Energy Stor., 21 (2019), 801-825.
https://doi.org/10.1016/j.est.2019.01.01
[36].R.L. Spyker, R.M. Nelms, Classical equivalent circuit parameters for a double-layer capacitor, IEEE Trans Aerosp Electron Syst, 36 (3) (2000), 829-836.
https://doi.org/10.1109/7.869502
[37].Y. Show, Research article on electric double-layer capacitor fabricated with addition of carbon nanotube to polarizable electrode, J Nanomater (2012), 1-8.
https://doi.org/10.1155/2012/929343
[38].M. Yassine, D. Fabris, Performance of commercially available supercapacitors, Energies, 10 (9) (2017), 1340-1352.
https://doi.org/10.3390/en10091340
[39].Yong S, Fabrication and characterisation of fabric supercapacitor [Doctoral Thesis], University of Southampton (2016) p.160.
https://eprints.soton.ac.uk/417382/
[40].Kim BK, Sy S, Yu A, Zhang J., Electrochemical supercapacitors for energy storage and conversion, Handbook of Clean Energy Systems, Wiley Publications (2015), 1-25.
https://doi.org/10.1002/9781118991978.hces112.
[41].B.E. Conway, Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, Kluwer Academic/Plenum Publishers, New York (1999).
https://link.springer.com/book/10.1007/978-1-4757-3058-6
[42].V. Augustyn, P. Simon, B. Dunn, Pseudocapacitive oxide materials for high-rate electrochemical energy storage, Energy Environ. Sci., 7 (2014), 1597-1664.
https://doi.org/10.1039/C3EE44164D
[43].C. Zhao, W. Zheng, A review for aqueous electrochemical supercapacitors, J. Front. Energy Res., 3(23) (2015), 1-8.
https://doi.org/10.3389/fenrg.2015.00023
[44].A. C. Ferrari and J. Robertson, Origin of the 1150-cmÀ1 Raman mode in nanocrystalline diamond, PHYSICAL REVIEW B, 63, (2001),121405
https://doi.org/10.1103/PhysRevB.63.121405
[45].W. C. Ke, C. Y. Chiang, T. G. Kim, Y. C. Lin, C. Y. Liao, K. J. Chang, J. C. Lin, Nitrogen doped ultrananocrystalline diamond conductive layer grown on InGaN-based light-emitting diodes using nanopattern enhanced nucleation, Applied Surface Science, 2021, 546, 149052.
https://doi.org/10.1016/j.apsusc.2021.149052
[46].W. Zhang, L. Guan, B. Wang, H. Liu, J. Wang, X. Hong, J. Long, S. Wei, X. Xiong, Y. Xiong, Directly tuning the surface morphologies and electron pathway of graphite/diamond composite films for enhanced electron field emission, Journal of Alloys and Compounds, 2022, 928, 167243.
https://doi.org/10.1016/j.jallcom.2022.167243
[47].Y. F. Tzeng, Y. C. Lee, C. Y. Lee, H. T. Chiu, I. N. Lin, Electron field emission properties on UNCD coated Si-nanowires, Diamond & Related Materials, 2008, 17, 753-757.
https://doi.org/10.1016/j.diamond.2007.10.014
[48].Q. Xia, H. Yang, M. Wang, M. Yang, Q. Guo, L. Wan, H. Xia, Y. Yu, High Energy and High Power Lithium-Ion Capacitors Based on Boron and Nitrogen Dual-Doped 3D Carbon Nanofibers as Both Cathode and Anode, Adv. Energy Mater., 2017, 7, 1701336.
https://doi.org/10.1002/aenm.201701336
[49].A. Bashir, M. Maqbool, R. Lv, A. Usman, W. Aftab, H. Niu, L. Kang, S. L. Bai, Engineering of Interfacial Interactions Among BN And CNT Hybrid Towards Higher Heat Conduction Within TPU Composites, Composites: Part A, 2023, 167, 107428.
https://doi.org/10.1016/j.compositesa.2023.107428
[50].X. Yuan, Y. Zhang, Y. Yan, B. Wei, K. Qiao, B. Zhu, X. Cai, T.-W. Chou, Tunable synthesis of biomass-based hierarchical porous carbon scaffold@ MnO2 nanohybrids for asymmetric supercapacitor, Chem. Eng. J., 393 (2020), 121214.
https://doi.org/10.1016/j.cej.2019.03.090
[51].Dongping Chen, Facile fabrication of nanoporous BCN with excellent charge/discharge cycle stability for high-performance supercapacitors, Materials Letters, 246 (2019),28-31.
https://www.sciencedirect.com/science/article/pii/S0167577X19304008
[52].Shuilin Wu, Yatu Chen, Tianpeng Jiao, Jun Zhou, Junye Cheng, Bin Liu, Shaoran Yang, Kaili Zhang,Wenjun Zhang, An Aqueous Zn-Ion Hybrid Supercapacitor with High Energy Density and Ultrastability up to 80,000 Cycles, Advanced Energy Materials, 9(47) (2019), 1902915.
https://doi.org/10.1002/aenm.201902915
[53].S. Veeresh, H. Ganesha, Y.S. Nagaraju, H. Vijeth, H. Devendrappa, Activated carbon incorporated graphene oxide with SnO2 and TiO2-Zn nanocomposite for supercapacitor application, Journal of Alloys and Compounds, 2023, 952, 169907.
https://doi.org/10.1016/j.jallcom.2023.169907
[54].Panchatcharam, P (Panchatcharam, Praveena) ; Vengidusamy, N (Vengidusamy, Narayanan) ; Arumainathan, S (Arumainathan, Stephen), Facile in situ synthesis of flexible porous polycarbazole/BCN nanocomposite as a novel electrode material for high-performance supercapacitor, Journal of Materials Science: Materials in Electronics , 33, 2022, 23580-23598.
https://doi.org/10.1007/s10854-022-09117-5
[55].Chen, DP; Huang, YZ ; Hu, XL; Li, RK; Qian, YJ ; Li, DX, Green Synthesis of Boron Carbonitride with High Capacitance, Materials, 11(3), 2018, 387.
https://doi.org/10.3390/ma11030387
[56].Li, HP; Zhu, SW; Zhang, M; Wu, PW; Pang, JY ; Zhu, WS ; Jiang, W; Li, HM , Tuning the Chemical Hardness of Boron Nitride Nanosheets by Doping Carbon for Enhanced Adsorption Capacity, Acs Omega, 2(9), 2017, 5385-5394.
https://doi.org/10.1021/acsomega.7b00795
[57].Wang, HHTian, L; Huang, Z; Liang, F; Guan, KK; Jia, QL ; Zhang, HJ; Zhang, SW,Molten salt synthesis of carbon-doped boron nitride nanosheets with enhanced adsorption performance, Nanotechnology, 31(50), 2020, 505606
https://doi.org/10.1088/1361-6528/abb6a4
[58].Indrajit M.Patil, 2D/3D heterostructure of h-BN/reduced graphite oxide as a remarkable electrode Material for supercapacitor, Journal of Power Sources, 479 (2020), 229092.
https://www.sciencedirect.com/science/article/pii/S0378775320313872
[59].Matsoso, BJ ; Ranganathan, K ; Mutuma, BK; Lerotholi, T; Jones, G ; Coville, NJ, Synthesis and characterization of boron carbon oxynitride films with tunable composition using methane, boric acid and ammonia, New Journal of Chemistry, 41(17), 2017, 9497-9504.
https://doi.org/10.1039/C7NJ01886J
[60].Lu, Q; An, J ; Duan, YD ; Luo, QZ; Shang, YY ; Liu, QN ; Tang, YF ; Huang, JY; Tang, CC; Yin, R ; Wang, DS, Highly Efficient and Selective Carbon-Doped BN Photocatalyst Derived from a Homogeneous Precursor Reconfiguration, Catalysts, 12(5), 2022, 555.
https://doi.org/10.3390/catal12050555
[61].Giusto, P ; Cruz, D ; Heil, T ; Tarakina, N ; Patrini, M ; Antonietti, M, Chemical Vapor Deposition of Highly Conjugated, Transparent Boron Carbon Nitride Thin Films, Advanced Science, 8(17), 2021, 2101602.
https://doi.org/10.1002/advs.202101602
[62].Huang, BR; Yang, YK; Lin, TC ; Yang, WL, A simple and low-cost technique for silicon nanowire arrays based solar cells, Solar Energy Materials and Solar Cells, 98, 2012, 357-362.
https://doi.org/10.1016/j.solmat.2011.11.031
[63].M. Hassan, M.A. Gondal, E. Cevik, T.F. Qahtan, A. Bozkurt, M.A. Dastageer, High performance pliable supercapacitor fabricated using activated carbon nanospheres intercalated into boron nitride nanoplates by pulsed laser ablation technique, Arabian Journal of Chemistry, 2020, 13, 6696-6707.
https://doi.org/10.1016/j.arabjc.2020.06.024
[64].J. Devarajan, P. Arumugam, G. Govindasamy, Synthesis of B-C-N nanotubes by CVD method and their electrochemical performance towards supercapacitors, Materials Today: Proceedings, 2023, Available online 20 January.
https://doi.org/10.1016/j.matpr.2023.01.039
[65].Huang, BR; Lin, YC, The Studies of Boron Carbon Nitrides with Ultra-nanocrystalline Diamonds on Silicon-Based Hybrid Nanostructures for Supercapacitor Properties. 2022
https://hdl.handle.net/11296/mm7qg4
[66].F. Gao, M.T. Wolfer, C.E. Nebel, Highly porous diamond foam as a thin-film micro supercapacitor material, Carbon, 80 (2014), 833-840.
https://doi.org/10.1016/j.carbon.2014.09.007
[67].X. Peng, W. Yuan, J. Zou, B. Wang, W. Hu, Y. Xiong, Nitrogen-incorporated ultrananocrystalline diamond/multilayer graphene composite carbon films: Synthesis and electrochemical performances, Electrochimica Acta, 2017, 257, 504-509.
https://doi.org/10.1038/srep04531
[68].ayi, A., Shveyd, A., Sue, AH. et al., Room-temperature ferroelectricity in supramolecular networks of charge-transfer complexes, Nature, 488 (2012), 485-489.
https://doi.org/10.1038/nature11395