研究生: |
林子立 Tzu-li Lin |
---|---|
論文名稱: |
脫酸大豆油脫色步驟中花生殼灰吸附成效之探討 A study on the performance of peanut hull ashes in bleaching water-degummed and alkali-refined soy oil |
指導教授: |
林俊一
Chun-I Lin |
口試委員: |
李振綱
Cheng-Kang Lee 林坤成 none |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2007 |
畢業學年度: | 95 |
語文別: | 中文 |
論文頁數: | 146 |
中文關鍵詞: | 大豆油 、花生殼灰 、過氧化物 、磷脂 、色素 、β-胡蘿蔔素 、游離脂肪酸 、脫除效率 、吸附劑 |
外文關鍵詞: | peanut hull ashes, soy oil, peroxides, phospholipids, pigments, β-carotene, free fatty acids, removal efficiency, adsorbents |
相關次數: | 點閱:219 下載:4 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本研究評估煅燒後花生殼灰成為脫酸大豆油吸附劑的可行性。花生殼的煅燒條件為300-1000 ℃及45-225分鐘。研究中將花生殼灰吸附大豆油中過氧化物、磷脂、色素、β-胡蘿蔔素和游離脂肪酸的脫除效率拿來與花生殼、稻殼灰、活性白土和再生白土者做一比較。實驗結果顯示灰化時間對脫除效率影響不明顯。500 ℃或700 ℃,是製備有效吸附劑的最佳溫度。以吸附大豆油中過氧化物、磷脂、色素、β-胡蘿蔔素和游離脂肪酸的觀點來看,活性白土和再生白土是非常好的吸附劑(游離脂肪酸除外);花生殼灰是有效的吸附劑;花生殼和稻殼灰則是無效的吸附劑。若是要花生殼灰有更高的脫除效率,必須將之進一步活化。
Peanut hull ashes prepared by calcinating ground peanut hull were evaluated as adsorbent for bleaching the water-degummed and alkali-refined soy oil. The calcination conditions were in the range of 300 -1000 ℃ and 45-225 min. Their performances in adsorbing peroxides, phospholipids, pigments, β-carotene and free fatty acids in soy oil were compared with those of peanut hull, rice hull ash, activated clay and regenerated clay. Experimental results indicated that the influence of ashing time on the removal efficiency was not clear. 500 ℃ or 700 ℃ showed potential as a best ashing temperature for preparing effective adsorbent. On the basis of adsorbing peroxides, phospholipids, pigments, β-carotene and free fatty acids, activated clay and regenerated clay were found to be superior adsorbents, except in adsorbing free fatty acids; peanut hull ashes, effective adsorbents;while peanut hull and rice hull ash non-effective ones. Further activation on peanut hull ashes is suggested to obtain a better performance of it. Regenerated clay was found to be a good substituent for activated clay.
Brown, P., I. A. Jefcoat, D. Parrish, S. Gill and E. Graham, “Evaluation of
the Adsorption Capacity of Peanut Hull Pellets for Heavy Metals in
Solution”, Advances in Environmental Research, 4, 19-29 (2000).
Chang, Y. Y., C. I. Lin and H. K. Chen, “Rice Hull Ash Structure and
Bleaching Performance Produced by ashing Various Times and
Temperatures”, JAOCS, 78(6), 657-660 (2001).
Erickson, D. R., Practical Handbook of Soybean Processing and Utilization,
AOCS Press and United Soybean Board, Champaign, Illinois (1995).
Firestone, D., “Official Method and Recommended Practices of the American
Oil Chemists’ Society”, 4th Ed. AOCS Press, Champaign, Illinois
(1989), Method Ca 5a-40.
Firestone, D., “Official Method and Recommended Practices of the American
Oil Chemists’ Society”, 5th Ed. AOCS Press, Champaign, Illinois
(1998), Method Ca 12-55.
Firestone, D., “Official Method and Recommended Practices of the American Oil Chemists’ Society”, 5th Ed. AOCS Press, Champaign, Illinois (1998), Method Cc 13b-45.
Firestone, D., “Official Method and Recommended Practices of the American Oil Chemists’ Society”, 5th Ed. AOCS Press, Champaign, Illinois (2001), Method Cd 8b-90.
Girgis, B. S., S. S. Yunis and A. M. Soliman, “Characteristics of a Activatd
Carbon from Peanut Hulls in Relation to Conditions of Preparation”,
Materials Letters, 57, 164-172 (2002).
Gnanasambandam R., M. Mathias, and A. Proctor, “Structure and Performancn
of Soy Hull Carbon Adsorbents as Affected by
Pyrolysis Temperature” JAOCS, 75(9), 615-621 (1998).
Gong, R., Y. Sun, J. Chen, H. Liu and C. Yang, “Effect of
Chemical Modification on Dye Adsorption Capacity of Peanut Hull”, Dyes
and Pigment, 67, 175-181 (2005).
Gong, R., M. Li, C. Yang, Y. Sun and J. Chen, “Removal of Cationic Dyes from
Aqueous Solution by Adsorption on Peanut Hull”,Journal of Hazardous
Materials, B121, 247-250 (2005).
Hong, Y., A. Proctor., and J. Shultz, “Acid-Treated Soy Hull Carbon
Structure and Adsorption Performance”,JAOCS, 77(7), 785-790 (2000).
Hymore, F. K., “Effects of Some Additives on the Performance of Acid-
activated Clays in the Bleaching of Palm Oil”,Applied Clay Science ,
10, 379-385 (1996).
Johnson, P. D., M. A. Watson, J. Brown and I.A. Jefcoat, “Peanut Hull
Pellets as a Single Use Sorbent for the Capture of Cu(Ⅱ) from
Wastewater”, Waste Management, 22, 471-480 (2002).
Low, K. S., C. K. Lee and L. Y. Kong, “Decolorisation of Crude Palm Oil by
Acid-activated Spent Bleaching Earth”, J. Chem. Technol. Biotechnol.,
72 (1), 67-73 (1998).
Ma, M. H. and C. I. Lin, “Adsorption Kinetics of β-carotene from Soy Oil
Using Regenerated Clay”, Separation Purification Technology,39, 201-209
(2004).
Namasivayam, C. and K. Periasamy, “Bicarbonate-Treated Peanut Hull Carbon
for Mercury(Ⅱ) Removal from Aqueous Solution”, Wat. Res. , 27(11),
1663-1668 (1993).
Periasamy, K. and C. Namasivayam, “Process Development firi Removal and
Recovery of Cadmium from Wastewater by a Low-Cost Adsorbent: Adsorption
Rate and Equilibrium Studies”, Ind. Eng. Chem. Res. , 33, 317-320 (1994).
Periasamy, K. and C. Namasivayam, “ Removal of Nickel(Ⅱ) from
Aqueous Solution and Nickel Plating Industry Wastewater Using
an Agricultural Waste: Peanut Hulls”, Waste Management, 15(1),
63-68 (1995).
Proctor, A. and S. Palaniappan, “Soy Oil Lutein Adsorption by Rice Hull
Ash”,JAOCS, 66(11), 1618-1621 (1989).
Proctor, A. and R. Gnanasambandam, “Soy Hull as an Adsorbent Source in
Processing Soy Oil”, JAOCS, 74(6), 685-692 (1997a).
Proctor, A. and R. Gnanasambandam, “Soy Hull Carbon as Adsorbents of Crude
Soy Oil Components: Effect of Carbonization Time”, JAOCS, 74(12), 1549-
1552 (1997b).
Proctor, A. and C. D. Harris, “Soy Hull Carbon as an Adsorbent of Minor Crude
Soy Oil Components”, JAOCS, 73(4), 527-529 (1996).
Proctor, A., P. K. Clark and C. A. Parker, “Rice Hull Ash Adsorbent
Performance Under Commercial Soy Oil Bleaching Conditions”, JAOCS, 72
(4), 459-462 (1995).
王韻凱 “脫酸大豆油脫色過程中過氧化物值變化之研究”, 國立台灣科技大學,化學工程系碩士論文 (2005)。
王麗華 “油脂工業廢白土的熱再生研究”, 國立台灣科技大學,化學工程系碩士論文 (1998)。
林士平, “以稻殼灰為吸附劑之芝麻油脫色研究”, 國立台灣科技大學,化學工程系碩士論文 (2000)。
林鴻儒 “以再生白土吸附脫酸大豆油中自由脂肪酸之吸附動力學研究”, 國立台灣科技大學,化學工程系碩士論文 (2004)。
李俊賢 “以再生白土吸附脫酸大豆油中磷脂之吸附動力學研究”, 國立台灣科技大學,化學工程系碩士論文 (2003)。
侯淑珍, “油脂工業脫色處理後廢白土的再生研究”, 國立台灣工業技術學院,化學工程系碩士論文 (1997)。
馬明宏 “以再生白土吸附大豆油中β-胡蘿蔔素之速率研究”, 國立台灣科技大學,化學工程系碩士論文 (2002)。
陳註源 “大豆油脫色動力學研究”, 國立台灣科技大學,化學工程系碩士論文 (2001)。
張悠揚 “稻殼灰對芝麻油脫色之研究”, 國立台灣科技大學,化學工程系碩士論文 (1999)。
黃龍泰 “以稻殼和花生殼製備高表面積之活性碳與其應用”, 國立台灣科技大學,化學工程系碩士論文 (2001)。
戴英漢 “脫酸大豆油真空脫色過程中過氧化物值變化之研究”, 國立
台灣科技大學,化學工程系碩士論文 (2006)。