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研究生: 林子立
Tzu-li Lin
論文名稱: 脫酸大豆油脫色步驟中花生殼灰吸附成效之探討
A study on the performance of peanut hull ashes in bleaching water-degummed and alkali-refined soy oil
指導教授: 林俊一
Chun-I Lin
口試委員: 李振綱
Cheng-Kang Lee
林坤成
none
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2007
畢業學年度: 95
語文別: 中文
論文頁數: 146
中文關鍵詞: 大豆油花生殼灰過氧化物磷脂色素β-胡蘿蔔素游離脂肪酸脫除效率吸附劑
外文關鍵詞: peanut hull ashes, soy oil, peroxides, phospholipids, pigments, β-carotene, free fatty acids, removal efficiency, adsorbents
相關次數: 點閱:219下載:4
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  • 本研究評估煅燒後花生殼灰成為脫酸大豆油吸附劑的可行性。花生殼的煅燒條件為300-1000 ℃及45-225分鐘。研究中將花生殼灰吸附大豆油中過氧化物、磷脂、色素、β-胡蘿蔔素和游離脂肪酸的脫除效率拿來與花生殼、稻殼灰、活性白土和再生白土者做一比較。實驗結果顯示灰化時間對脫除效率影響不明顯。500 ℃或700 ℃,是製備有效吸附劑的最佳溫度。以吸附大豆油中過氧化物、磷脂、色素、β-胡蘿蔔素和游離脂肪酸的觀點來看,活性白土和再生白土是非常好的吸附劑(游離脂肪酸除外);花生殼灰是有效的吸附劑;花生殼和稻殼灰則是無效的吸附劑。若是要花生殼灰有更高的脫除效率,必須將之進一步活化。


    Peanut hull ashes prepared by calcinating ground peanut hull were evaluated as adsorbent for bleaching the water-degummed and alkali-refined soy oil. The calcination conditions were in the range of 300 -1000 ℃ and 45-225 min. Their performances in adsorbing peroxides, phospholipids, pigments, β-carotene and free fatty acids in soy oil were compared with those of peanut hull, rice hull ash, activated clay and regenerated clay. Experimental results indicated that the influence of ashing time on the removal efficiency was not clear. 500 ℃ or 700 ℃ showed potential as a best ashing temperature for preparing effective adsorbent. On the basis of adsorbing peroxides, phospholipids, pigments, β-carotene and free fatty acids, activated clay and regenerated clay were found to be superior adsorbents, except in adsorbing free fatty acids; peanut hull ashes, effective adsorbents;while peanut hull and rice hull ash non-effective ones. Further activation on peanut hull ashes is suggested to obtain a better performance of it. Regenerated clay was found to be a good substituent for activated clay.

    目 錄 中文摘要 Ι 英文摘要 II 誌謝 III 目錄 IV 圖表索引 X 第一章緒論 1 第二章文獻回顧 3 2-1花生殼的性質與應用 3 2-2過氧化物值、磷脂、紅色值、β-胡蘿蔔素、游離脂肪酸的測量方法 6 2-2-1 過氧化物值的測量方法 6 2-2-2 磷脂的測量方法 8 2-2-3 紅色值的測量方法 9 2-2-4 β-胡蘿蔔素的測量方法 9 2-2-5 游離脂肪酸的測量方法 10 2-3 吸附劑種類及其吸附能力 11 2-4 製備吸附劑時灰化條件對脫除效率的影響 13 第三章實驗部份 16 3-1 藥品、氣體及吸附劑 16 3-1-1 藥品 16 3-1-1-1過氧化物值之測定 16 3-1-1-2磷脂之測定 17 3-1-1-3 β-胡蘿蔔素之測定 18 3-1-1-4游離脂肪酸之測定 18 3-1-2 氣體 19 3-1-3 吸附劑 19 3-2 實驗儀器及設備 20 3-2-1花生殼灰的製備裝置 20 3-2-2花生殼灰組成及物性測定儀器 22 3-2-3吸附實驗裝置 25 3-2-4油中成份或指數之測定儀器 29 3-2-4-1過氧化物值測定儀器 29 3-2-4-2磷脂值測定儀器 31 3-2-4-3紅色值測定儀器 33 3-2-4-4β-胡蘿蔔素濃度測定儀器 34 3-2-4-5游離脂肪酸濃度測定儀器 34 3-2-5其他儀器與設備 34 3-3 實驗原理或步驟 36 3-3-1花生殼的製備 36 3-3-2花生殼灰的製備 36 3-3-3稻殼灰的製備 38 3-3-4花生殼及花生殼灰的碳、氫和氮之分析 39 3-3-5花生殼、花生殼灰及稻殼灰的成份分析 39 3-3-6花生殼、花生殼灰及稻殼灰大小及形狀觀察 40 3-3-7花生殼、花生殼灰及稻殼灰比表面積、比孔隙體積及平均孔徑測量 41 3-3-8花生殼、花生殼灰及稻殼灰密度之測量 42 3-3-9花生殼、花生殼灰及稻殼灰粒徑測量 43 3-3-10花生殼、花生殼灰及稻殼灰水份測量 44 3-3-11吸附實驗 45 3-3-12 油中成份濃度或指數之測定 46 3-3-12-1過氧化物值之分析 46 3-3-12-1-1滴定液的配製及標定 46 3-3-11-1-2電位差自動滴定儀之分析 48 3-3-12-2 磷脂濃度之分析 50 3-3-12-2-1油樣試液的配製 51 3-3-12-2-2紫外線可見光光譜儀之分析 52 3-3-12-2-3檢量線的製作 53 3-3-11-3紅色值測定 56 3-3-12-4β-胡蘿蔔素之分析 57 3-3-12-4-1紫外線可見光光譜儀之分析 57 3-3-12-4-2檢量線的製作 58 3-3-12-5游離脂肪酸之分析 60 3-3-12-5-1滴定液的配製及標定 60 3-3-12-5-2電位差自動滴定儀之分析 62 3-4實驗工作項目 64 3-4-1 未脫色前大豆油中過氧化物值、磷脂值、Lovibond紅色值、β-胡蘿蔔素濃度及游離脂肪酸濃度隨時間的變化 64 3-4-2 以花生殼為吸附劑的吸附實驗 64 3-4-3 以花生殼灰為吸附劑的吸附實驗 65 3-4-3-1花生殼灰灰化時灰化溫度對脫除效率的影響 65 3-4-3-2花生殼灰灰化時灰化時間對脫除效率的影響 66 3-4-4 以稻殼灰、活性白土及再生白土為吸附劑的吸附實驗 66 第四章結果與討論 67 4-1各種吸附劑的組成和物性量測 67 4-1-1..花生殼灰的碳、氫和氮組成 69 4-1-2..各種吸附劑的成份 70 4-1-3 各種吸附劑的大小及形狀 71 4-1-4 各種吸附劑的比表面積、比孔隙體積及平均孔徑 71 4-1-5 各種吸附劑的密度 79 4-1-6 花生殼、花生殼灰及稻殼灰之粒徑 79 4-1-7各種吸附劑的水份 80 4-2 未脫色大豆油中過氧化物濃度、磷脂濃度、Lovibond 紅色值、β-胡蘿蔔素濃度和游離脂肪酸濃度隨時間變化的情形 82 4-3 各種吸附劑的脫除效率 91 4-3-1-1 由過氧化物值變化算出的脫色效率 93 4-3-1-2 由磷脂濃度變化算出的脫除效率 95 4-3-1-3由Lovibond紅色值變化算出的脫色效率 97 4-3-1-4由β-胡蘿蔔素濃度變化算出的脫色效率 100 4-3-1-5由游離脂肪酸濃度變化算出的脫色效率 102 4-3-2 由吸附劑的觀點來看脫除效率 105 第五章 結論 110 參考文獻 112 附錄:實驗數據 117 作者簡介 133

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