本文探討以傳統乳化聚合法，同時添加乳化劑及共乳化劑，合成奈米級之反應性微膠(RM)顆粒，以及Pickering乳化聚合法合成高分子(Polymer)-氧化石墨烯(GO)核殼形顆粒(CSP)以及高分子(Polymer)-熱還原氧化石墨烯(GO)核殼形顆粒(CSP)作為環氧樹脂(EPR)之抗體積收縮劑(LPA)以及增加其導熱和導電性能。
吾人利用總體聚合法及溶液聚合法，合成三種不同化學結構之傳統UP樹脂，包括：Maleic anhydride (MA)- Phthalic anhydride (PA)-1,2-Propanediol (PG)型、MA-PG型、MA-1,6-Hexanediol (HD)型UP樹脂；及聚合度(n)為0.16、2、5之環氧樹脂(EPR)與VER作為基材。
奈米級RMs顆粒之合成是以苯乙烯(Styrene，St)及上述合成之MA-HD型UP樹脂分別做為共單體，利用傳統乳化聚合法，結合乳化劑(十二烷基硫酸鈉，Sodium dodecyl sulfate，SDS)和共乳化劑(戊醇，1-Pentanol)的添加，並利用氫氧化鈉水溶液(NaOH(aq))控制乳化系統的pH值，以利自乳化聚合的機制同時作用，抑制乳化顆粒的凝聚，進而合成出奈米級(粒徑小於100 nm)之反應性微膠(RM)顆粒。
高分子(Polymer)-氧化石墨烯(GO)核殼形顆粒(CSP)的合成，是以苯乙烯(Styrene，St)及苯乙烯交聯不飽和聚脂樹脂為核心，不飽和聚脂樹脂是Maleic anhydride (MA) -1,6-Hexanediol (HD)型UP樹脂，利用pickering乳化聚合法以氧化石墨烯(GO)和熱還原氧化石墨烯(TRGO)為界面活性劑包覆高分子的表面。
於100 ℃下製備不同CSP添加量(0、0.5、1.0及1.5 wt%)之EPR (n=0.16)/DDM/Polymer-GO和EPR (n=0.16)/DDM/Polymer-TRGO固化試片。吾人並以SEM觀察EPR (n=0.16)/DDM/Polymer-GO和EPR (n=0.16)/DDM/Polymer-TRGO三成份聚合固化後樣品之微觀形態結構，亦測量CSP添加量和樹脂基材之種類等因素，對三成份之體積收縮特性與機械性質和導電導熱之影響。

In this thesis, traditional emulsion polymerization methods with the addition of surfactant and co-surfactant, have been employed to synthesize nano-scale microgel (RM) particles and the synthesis of polymer-graphene oxide(GO) core-shell particles(CSP) and polymer-thermally reduced graphene oxide(TRGO) core-shell particles(CSP) by Pickering emulsion polymerization as low-profile additives (LPA) for epoxy resin, and increase its thermal conductivity and electrical properties has also investigated.
The bulk and solution polymerization were used to synthesize three kinds of traditional UP resins with different chemical structures, including Maleic anhydride (MA) -Phthalic anhydride (PA) -1, 2-Propanediol (PG) type, MA-PG type, MA-1,6-Hexanediol (HD) type UP resin. Epoxy resin (EPR) and VER with a degree of polymerization (n) of 0.16, 2, and 5,respectively,were synthesized by the bulk and solution polymerizations as well.
The nano-scale RM particles were synthesized by traditional emulsion polymerization, combined with surfactant (Sodium Dodecyl sulfate, SDS) and co- surfactant (1-Pentanol). In the synthesis of RM, using styrene (St) and unsaturated polyester (MA-HD types of UP) as comonomers, sodium hydroxide solution (NaOH(aq)) was also employed to control pH value of the emulsion systems and facilitate simultaneous action of the mechanism of the self-emulsification polymerization. As a result, the aggregation of colloid particles in the emulsion polymerizations would be greatly reduced, and the nano-scale reactive microgel particles (RM) with a particle size less than 100 nm could be synthesized.
The synthesis of polymer-graphene oxide (GO) core-shell particles (CSP) and polymer-thermally reduced graphene oxide(TRGO) core-shell particles(CSP) has been based on styrene (Styrene, St) and styrene cross-linked unsaturated polyester resin. The unsaturated polyester resin can be Maleic anhydride (MA) -1,6-Hexanediol (HD) type UP resin, which has been synthesized by pickering emulsification polymerization method and graphene (GO) is a surfactant coating polymer surface.
EPR (n=0.16)/DDM/Polymer-GO and EPR (n=0.16)/DDM/Polymer-TRGO ternary systems with different loading of CSP (0, 0.5, 1.0 and 1.5 wt%) and EPR (n=0.16)/DDM/Polymer-GO and EPR (n=0.16)/DDM/Polymer-TRGO were cured isothermally at 100 °C. The effects of CSP concentration and type of resin matrix on the cured morphology by SEM, for volumetric shrinkage after the cure, and mechanical properties and thermal and electrical conductivities for the EPR (n=0.16)/DDM/Polymer-GO and EPR (n=0.16)/DDM/Polymer-TRGO cured systems has aslo been investigated.

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