提升能量密度為現今研發鋰電池重要的課題之一，無陽極鋰電池可以將正極提供之鋰離子完全傳遞到負極並循環利用，1,2有效降低電池總重量，顯著提高電池整體能量密度並且降低了成本。然而，鋰離子以非預期之沉積導致低庫倫效率和鋰枝晶生長的挑戰，阻礙當前無陽極鋰電池的發展。因為不均勻的鋰鍍層和原始銅電極上不穩定的SEI層形成，導致電容量快速的下降，所以我們使用 P(AMPS-co-BA)具有特殊官能基的設計進而修飾銅箔集電體以抑制鋰枝晶生成。修飾後的集電體與未修飾集電體在鋰沉積與剝離的實驗中(-0.5~1.0V，0.5mAh/cm2)可以看出，修飾後的集電體在100次的循環內都維持穩定的電壓且維持99.8%的庫倫效率，而未修飾的集電體的有嚴重的過電位現象以及17.7%的低庫倫效率。由庫倫效率結果可以證明具有特殊官能基的P(AMPS-co-BA)塗層具有提升鋰沉脫能力，能有效抑制鋰枝晶生長且提高無陽極鋰電池的壽命。

Recently, electric vehicles(EV) is blooming owing to fuel resource shortage. Improving the energy density plays an important role for EV. High energy density for EV equals longer travel and better energy efficiency. Anode-free batteries have obtained considerable attention for commercial application due to high energy density and low cost. However, uneven lithium plating and unstable SEI layer will lead to low coulombic efficiency, poor capacity retention and dendrite formation, limiting the development of anode-free lithium batteries. In this work, we synthesized co-polymer P (AMPS-co-BA) as the artificial protection layer onto Cu foil. P(AMPS-co-BA) is block co-polymer with two functional groups, BA and AMPS, respectively. In the experiment of lithium deposition and stripping (-0.5~1.0V, 0.5mAh/cm2), it can be seen that the modified current collector and the prsitin current collector. These functional groups supply elasticity and ionic conductivity. Based on our results, after 100 cycles of lithium plating/stripping, it is indicated that the artificial layer can successfully suppress the formation of lithium dendrites, thereby enhancing the coulombic efficiency to 99.8% during lithium plating and stripping. The results of the coulombic efficiency demonstrate that the P(AMPS-co-BA) coating with functional groups can improve the adsorbtion and desorption stability of lithium, effectively inhibiting the growth of lithium dendrites and enhancing the lifespan of anode-free lithium batteries.

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