本論文主要探討以兩種不同的犧牲層溶液－Poly(acrylic acid)與Polystyrene sulfonates，利用轉印技術轉印具親水性的氧化鋅薄膜於P3HT:PCBM目標基板上。其中氧化鋅薄膜以合成之奈米粒子之氧化鋅溶液利用旋轉塗佈法，和以噴霧裂解法製備成薄膜。
不論以Poly(acrylic acid)或 Polystyrene sulfonates當犧牲層，轉印之氧化鋅奈米粒子薄膜，均需混摻具疏水性的有機小分子，才能轉印成功，發現轉印技術成功要件為薄膜間的親疏水性。而轉印以噴霧裂解法製備之氧化鋅薄膜，與其犧牲層間的鍵結元素型態與強度甚為重要，由SEM與XPS得知，Polystyrene sulfonates之SO3-與Zn2+ 間靜電作用力很弱，而Poly(acrylic acid)之COO-與Zn2+以共價鍵鍵結，無法轉印，使得PSS可以成功轉印氧化鋅薄膜於主動層上。
最後以PSS為犧牲層轉印以噴霧裂解法製備之氧化鋅薄膜於具疏水層之ITO基板上，製備反置型有機太陽能電池，而在溫度300℃、流速320sccm-10mins之氧化鋅薄膜，可得其光電轉換效率為3.17。

In this thesis, we focuses on a facile method of transferring hydrophilic Zinc oxide film to P3HT: PCBM substrate using water soluble materials like Poly(acrylic acid) and Poly(styrene sulfonate) as sacrificial layer. The Zinc oxide thin-films were coated on the sacrificial layer by spin-coating method from solution-based Zinc oxide nanoparticles and spray pyrolysis. When Poly (acrylic acid) or Poly(styrene sulfonate) used as sacrificial layer, Zinc oxide thin-film which prepared by solution-based Zinc oxide nanoparticles, were blended with hydrophobic organic small-molecules in order to transfer the film successfully onto P3HT:PCBM substrate. We have found that the key of transfer requirement is the hydrophilicity relationship between two thin-film layers. On the other hand, to transfer Zinc oxide thin films prepared by spray pyrolysis, we found that the element of bond energy between the sacrificial layer and Zinc oxide is important. From XPS and SEM results, Poly(acrylic acid) of carboxyl (COO-) functional group formed strong covalent bonds with Zn2+ ions compared to Poly(styrene sulfonate) of SO3-, which severely limits the transfer of the film.
Finally, Poly(styrene sulfonate) was used as sacrificial layer to transfer Zinc oxide thin film, which was prepared by spray pyrolysis on the ITO substrate with a hydrophobic layer, and fabricated the inverted organic solar cell devices. A power conversion efficiency of 3.17% was achieved. The result suggests that using a water soluble sacrificial layer is promising method to transfer thin film.

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