研究生: |
黃鑫傑 Hsin-chieh Huang |
---|---|
論文名稱: |
含C4碳氫化合物與DMF或NMP相平衡性質研究 Phase Equilibrium Properties for Mixtures Containing C4 Hydrocarbons and DMF or NMP |
指導教授: |
李明哲
Ming-Jer Lee |
口試委員: |
陳瑞堂
Jui-Tang Chen 李豪業 Hao-Yeh Lee |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2013 |
畢業學年度: | 101 |
語文別: | 中文 |
論文頁數: | 135 |
中文關鍵詞: | 汽液相平衡 、熱力模式參數 、丁二烯萃取溶劑 、四碳類 |
外文關鍵詞: | vapor-liquid equilibria, thermodynamic models, butadienens extractive solvents, C4 |
相關次數: | 點閱:447 下載:1 |
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本實驗使用一套可變體積-附視窗暨影像處理系統的高壓相平衡分析裝置,以合成法量取由丁二烯萃取溶劑DMF或NMP與1-丁烯、異丁烯、順丁烯-2、反丁烯-2、正丁烷、異丁烷或甲基乙炔等所組合而成十四組雙成分系統的汽液相平衡實驗數據,量測溫度介於298.15 K ~ 348.15 K之間,平衡壓力則介於1 bar ~ 20 bar之間。實驗所量取的雙成份系統之汽液相平衡數據均分別使用 NRTL-HOC及 UNIQUAC-HOC 模式關聯,同時也求取最適化的二元參數值。
In the present study, a visual and volume-variable high-pressure phase equilibrium analyzer (PEA) was used to measure the phase equilibrium data for the binary mixtures containing an extractive solvent, N,N-dimethylformamide (DMF) or N-methylpyrrolidone (NMP) with 1-butene、iso-butene、cis-butene-2、trans-butene-2、n-butane、iso-butane、methyl acetylene at temperatures from 298.15 K to 348.15 K and pressures from 1 bar to 20 bar. All the phase equilibrium data correlated with the NRTL-HOC and the UNIQUAC-HOC models, respectively, and simultaneously determine the optimal values of the binary parameters.
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