本研究以鋰金屬為陽極、PUAT-FS為電解質、LFP-PUAT為陰極。PUAT-FS由70wt%丙烯酸硫代碳酸聚氨酯(PUAT)寡聚物，與支撐材料聚偏氟乙烯-六氟丙烯(PVdF-HFP)以重量比1:1，添加30 wt%的雙氟磺酼亞胺鋰(LiFSI)和20wt%鋰鑭鋯鉭氧(LLZTO)所組成，其電化學窗口為4.6V。
PUAT寡聚物分子量在6000-7000 gmol-1，結構上具備許多帶負電的官能基，因此陰極LFP摻混PUAT後有助於內部鋰離子的傳遞，也可裝載額外的循環鋰，使電池的電容量值增加。充放電測試中，第一圈(也稱做長成圈)進行較低電流充放電，可提高整體電池比電容量值，有助於生成優異的SEI，可提高庫倫效率，令電池更快達到穩態。
PUAT-FS在室溫下離子導電率為0.44 mS cm-1，LFP-PUAT電池於室溫下第一圈充放電以0.1C電流進行，在0.1C、0.2C、0.3C和0.5C電池結果中，0.1C電流下的電池具有最佳電池表現，其最大電容值為181 mAh g-1，在190圈循環後電容衰退率為每圈0.078%。LFP-PUAT電池在室溫下無法承受高電流的充放電循環，因此提高環境溫度到50℃，此時離子導電率達0.7 mS cm-1，可承受超過1C電流的充放電循環。
50℃下，以0.5C電流進行第一圈(長成圈)充放電，在1C、2C和3C結果中，在1C電流下最為優秀，其循環圈數可超過500圈，圈數壽命(電容衰退率達80%時)在第384圈，最大電容值為171 mAh g-1，在500圈時電容衰退率為每圈0.074%。3C電池充放電速度快，所需時間短，循環過程中庫倫效率可穩定達99%，高電流容易造成鋰枝晶生長快速，使電池短路，導致3C電池循環壽命僅190圈。顯然，與商用的鋰電池相比，LFP-PUAT電池在循環壽命與電容量衰退率上仍需加強。

In this thesis research, our batteries have been assembled with lithium metal anode, composite solid-state electrolyte PUAT-FS, and cathode LFP-PUAT. The PUAT-FS electrolyte is made of 70 wt% PUAT oligomer and PVdF-HFP macromolecule at weight ratio 1:1 (w/w), plus 30 wt% LiFSI. Additional 20 wt% LLZTO is added to the electrolyte. The potential window of PUAT-FS is 4.6 V.
The as-prepared PUAT is featured with low molecular weight, 6000-7000 g mol-1. Many functional groups of negative polarity are designed on the PUAT molecular structure, such that the cathode doped with PUAT may improve the lithium ion transport, and enhance the cathode capacity. When the cell is cycled galvanostatically, the first cycle of charge/discharge is executed at low current to facilitate a superior SEI formation, which is also known as the formation cycle. Formation at low current establishes the cycle stability in high-current subsequent charge/discharge, also increases the specific capacity and coulombic efficiency.
In cycling at room temperature, we set the first charge/discharge process at 0.1C. Among the cycle results at 0.1C, 0.2C, 0.3C, 0.5C, the LFP-PUAT battery displays the best charge/discharge behavior at 0.1C, since electrolyte conductivity is merely 0.44 mS cm-1. The maximum capacity reaches 181 mAh g-1. Its capacity fading rate is 0.078% per cycle after 190 cycles. At room temperature, the LFP-PUAT cell cannot be cycled properly at high currents. Raising the cycling temperature to 50 ℃, with electrolyte conductivity 0.7 mS cm-1, the LFP-PUAT cell is allowed to operate at current exceeding 1C.
In cycling at 50 ℃, we set the current of formation cycle, 0.5C. Cycling results at 1C, 2C, and 3C indicate that 1C cycling exhibits the ideal energy storage behavior. Its total cycle number exceeds 500 cycles, with a maximum capacity 171 mAh g-1. The cycle life, defined as capacity retention less than 80%, reaches 384 cycles. The capacity fading rate is 0.074% per cycle. At high current cycling, 3C, the charging/discharging time is shorter than those of 1C and 2C, and the coulombic efficiency still reaches 99%. Nonetheless, high current encourages dendrite growth, leading to short cycle life, 190 cycles only. Evidently, our solid state battery, LFP-PUAT cell, the cycle life and capacity fade performance still require substantial improvements, in comparison with those commercially available lithium ion batteries.

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