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研究生: 李威霖
William Anderson Lee Sanchez
論文名稱: The endurance limitation of heat resistance performance for Polycarbonate
The endurance limitation of heat resistance performance for Polycarbonate
指導教授: 邱顯堂
Hsien-Tang Chiu
口試委員: 邱顯堂
Hsien-Tang Chiu
游進陽
Chin-Yang Yu
陳建光
Jem-Kun Chen
江宗穎
John Chiang
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2017
畢業學年度: 105
語文別: 英文
論文頁數: 59
中文關鍵詞: polycarbonateaccelerated agingizod impacttensile strengthTGADSC
外文關鍵詞: polycarbonate, accelerated aging, izod impact, tensile strength, TGA, DSC
相關次數: 點閱:263下載:4
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All the materials are exposed to different kinds of environments and unfavorable climatic conditions along the time; also known as ageing. The ageing is a successive shift of state and property that in general leads to a stage of malfunction. The ambient temperature is constantly changing in a comparatively broad range. These temperatures changes will influence in the diverse material’s properties. Particularly in polymer materials, the mechanical properties have very significant changes due to increased temperature; plastics become softer and flexible. In the same way, by decreasing the temperature the plastic become harder and brittle. The unique properties of the Polycarbonate establish it a polymer of choice in a broad range of applications. However, it is relatively expensive compared with other plastics with similar applications, so it is usually reprocessed. Due to the wide range of applications and recycling process in which may involve high temperature processes, it is important to know the thermal endurance along the time of the material. Different methods and conditions to study this material stage of malfunction have been researched. In this study, it was designed a set of accelerated aging in which environmental conditions are mainly focused on temperature and humidity. First, the samples were put under the different aging tests conditions and then they were used for: izod impact test, tensile strength test, TGA and DSC; in order to know the basic physical and thermal properties of the material. Finally, the results were used to predict the shelf life of the polycarbonate 945 respect to work under normal environmental conditions.


All the materials are exposed to different kinds of environments and unfavorable climatic conditions along the time; also known as ageing. The ageing is a successive shift of state and property that in general leads to a stage of malfunction. The ambient temperature is constantly changing in a comparatively broad range. These temperatures changes will influence in the diverse material’s properties. Particularly in polymer materials, the mechanical properties have very significant changes due to increased temperature; plastics become softer and flexible. In the same way, by decreasing the temperature the plastic become harder and brittle. The unique properties of the Polycarbonate establish it a polymer of choice in a broad range of applications. However, it is relatively expensive compared with other plastics with similar applications, so it is usually reprocessed. Due to the wide range of applications and recycling process in which may involve high temperature processes, it is important to know the thermal endurance along the time of the material. Different methods and conditions to study this material stage of malfunction have been researched. In this study, it was designed a set of accelerated aging in which environmental conditions are mainly focused on temperature and humidity. First, the samples were put under the different aging tests conditions and then they were used for: izod impact test, tensile strength test, TGA and DSC; in order to know the basic physical and thermal properties of the material. Finally, the results were used to predict the shelf life of the polycarbonate 945 respect to work under normal environmental conditions.

Table of Contents CHAPTER 1 Introduction……………………………………………………………1 CHAPTER 2 Experimental procedure………………………………………………3 2.1 Accelerated aging test ………………………………………………………3 2.1.1 Real environment aging test …………………………………………7 2.1.2 High temperature aging test …………………………………………8 2.1.3 High temperature and humidity aging test ………………………9 2.2 Izod impact test ………………………………………………………………10 2.3 Tensile strength test ………………………………………………………11 2.4 Thermogravimetric analysis test …………………………………………13 2.5 Differential scanning calorimetry test ………………………………14 CHAPTER 3 Results and discussion………………………………………………16 3.1 Temperature variation versus material physical properties ……16 3.1.1 Room temperature aging test …………………………………………16 3.1.1.1 Influence of room temperature aging on impact strength ……………………………………………………………………………………………16 3.1.1.2 Influence of room temperature aging on tensile strength…………………………………………………………………………………17 3.1.1.3 Influence of room temperature aging on thermal cracking ……………………………………………………………………………………………18 3.1.1.4 Influence of room temperature aging on molecular chain structure ………………………………………………………………………………20 3.1.2 Low temperature aging test ……………………………………………22 3.1.2.1 Influence of low temperature aging on impact strength ……………………………………………………………………………………………22 3.1.2.2 Influence of low temperature aging on tensile strength ……………………………………………………………………………………………22 3.1.2.3 Influence of low temperature aging on thermal cracking…………………………………………………………………………………24 3.1.2.4 Influence of low temperature aging on molecular chain structure………………………………………………………………………………25 3.1.3 High temperature aging test …………………………………………27 3.1.3.1 Influence of high temperature aging on impact strength…………………………………………………………………………………27 3.1.3.2 Influence of high temperature aging on tensile strength ……………………………………………………………………………………………28 3.1.3.3 Influence of high temperature aging on thermal cracking ……………………………………………………………………………………………30 3.1.3.4 Influence of high temperature aging on molecular chain structure ………………………………………………………………………………31 3.2 High temperature and high humidity versus material physical properties ……………………………………………………………………………33 3.2.1 Influence of high temperature and high humidity aging on impact strength…………………………………………………………………………………33 3.2.2 Influence of high temperature and high humidity aging on tensile strength………………………………………………………………………35 3.2.3 Influence of high temperature and high humidity aging on thermal cracking………………………………………………………………………37 3.2.4 Influence of high temperature and high humidity aging on molecular chain structure…………………………………………………………40 3.3 Material lifespan assessment ………………………………………………43 3.3.1 Lifespan assessment of different environmental temperatures tests………………………………………………………………………………………43 3.3.2 Lifespan assessment of high temperature and high humidity test………………………………………………………………………………………44 CHAPTER 4 Conclusions………………………………………………………………46 References………………………………………………………………………………48

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