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研究生: 龔紀維
Ji-Wei GONG
論文名稱: 超深冷處理程序對於不同高碳鋼材顯微組織與耐磨耗性能的影響
Effect of Deep Cryogenic Process on the Microstructure and Wear Performance of the Different High Carbon Steel
指導教授: 林原慶
Yuan-Ching Lin
口試委員: 向四海
Su - Hai Hsiang
郭俊良
Chun-liang Kuo
學位類別: 碩士
Master
系所名稱: 工程學院 - 機械工程系
Department of Mechanical Engineering
論文出版年: 2018
畢業學年度: 106
語文別: 中文
論文頁數: 152
中文關鍵詞: 超深冷處理殘留沃斯田鐵麻田散鐵耐磨耗磨耗表面溫度
外文關鍵詞: deep cryogenic treatment, retained austenite, martensite, wear resistence, wear surface temperature
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本文主要探討不同熱處理程序對高碳工具鋼(high carbon tool steel)及軸承鋼(bearing steel)其顯微組織的影響,並且檢測其硬度,使用迴轉式磨耗試驗機以銷對盤(pin on disc)的方式評估其耐磨耗能力的優劣。
實驗結果顯示兩種鋼料淬火過後立即進行超深冷處理能夠有效的消除殘留沃斯田鐵,但超深冷時間的增長,殘留沃斯田鐵的量並無明顯下降。此外,含鉻元素能夠讓M_s及M_f點提升,使得軸承鋼殘留沃斯田鐵明顯比高碳工具鋼少。兩種鋼料經過超深冷處理,均能夠析出細小的超深冷碳化物,並隨著超深冷處理時間增加,獲得更多細小的超深冷碳化物。X-ray繞射分析結果顯示,高碳工具鋼內含有Fe3C及Fe7C3型碳化物,軸承鋼內含有M3C、M7C3型碳化物,並且鉻元素能夠促使更多碳化物析出,使軸承鋼含碳化物的面積百分比比高碳工具鋼高。此外,熱處理過後均能提升試片的耐磨耗能力,其中,軸承鋼耐磨耗能力優於高碳工具鋼,主要原因在於有效消除殘留沃斯田鐵且能獲得更多細小的碳化物。軸承鋼淬火後,回火一小時,進行超深冷處理二十四小時,再回火一小時,此種試片經二次回火程序讓基材更富有韌性並且其碳化物為所有試片最多者,因此其耐磨耗能力優於其它試片。


In this study discusses the effect of different heat treatment conditions
on the microstructure of high carbon tool steel (SK2) and bearing steel (SUJ2) , measured the hardness and using rotating tribometer in pin on disc mode to evaluate the wear resistence
Experimental result shows that there are amounts of retained austenite on both materials after quenching, immediately the deep cryogenic treatment following quenching process can effectively reduce retained austenite. When the time of the deep cryogenic was prolonged, the retained austenite can not reduce obviously. Adding Chromium atoms makes it elevate the〖 M〗_s and M_f points so that the retained austenite of the bearing steel is significantly less than the high carbon tool steel. The amount of deep cryogenic carbides were precipitated , when holding the deep cryogenic process on the both materials .With the time of the deep cryogenic process increased, it can precipitate more deep cryogenic carbides. The result of X-ray diffraction showed that carbides in the matrix include Fe3C、Fe7C3 in the high carbon tool steel and M3C、M7C3 in the bearing steel. Adding Chromium atoms can precipitate more carbides make the area fraction of the carbides of the bearing steel were higher than high carbon tool steel. After the heat treatment , the wear resistence of the specimens can be improved. Bearing steel has the best wear resistance compared to high carbon tool steels. It is because effectively elimination the amount of retained austenite and precipitation of more fine carbides. Among all the specimen underwent the heat treatment of the condition Q-T1hr-C24hr-T1hr of bearing steel has the best wear performance which may caused twice tempering can improve matrix’s toughness and its carbides are the most of all the test pieces, so its wear resistance is superior to other test pieces.

摘要 I ABSTRACT II 致謝 IV 表目錄 VII 圖目錄 VIII 第一章 前言 1 第二章 文獻回顧 2 2-1 熱處理的意義 2 2-1-1淬火處理(Quenching process) 2 2-1-2回火處理(Tempering process) 3 2-2超深冷處理特性及目的 5 2-2-1超深冷之相關研究 6 2-3麻田散鐵相變化 7 2-4 鋼之合金元素 9 2-5強化機構 11 2-5-1固溶強化(Solid solution strengthening) 11 2-5-2細晶粒強化(Fine grain size strengthening) 11 2-5-3析出強化(Precipitation strengthening ) 12 2-5-4散佈強化(Disperison strengthening ) 12 2-5-5麻田散鐵強化(Martensite strengthening) 12 2-6磨耗概論 13 2-6-1磨潤系統 13 2-6-2磨耗機構 14 第三章 實驗方法與步驟 20 3-1實驗步驟 20 3-2 試片材料 22 3-3 熱處理製程 22 3-3-1 淬火處理 22 3-3-2 回火處理 23 3-3-3 超深冷處理 23 3-4 試片規格 24 3-4-1 顯微組織分析試片 25 3-4-2 X光繞射儀試片 25 3-4-3 場發射穿透式電子顯微鏡試片 25 3-4-4 硬度試片 26 3-4-5 磨耗上試片製作 26 3-4-6 磨耗下試片製作 26 3-5實驗設備與分析儀器 28 3-5-1磨耗試驗機介紹 28 3-5-2分析儀器介紹 29 3-6磨耗試驗 31 3-6-1磨耗試驗機校正 31 3-6-2 磨耗試驗參數設定 31 3-6-3 最大接觸應力計算 32 3-6-4磨耗量量測及計算 34 3-6-5 磨耗試驗溫度量測與最高表面接觸溫度計算 36 3-6-6 磨耗表面形態觀察 42 3-7 殘留沃斯田鐵計算 42 第四章 結果與討論 45 4-1不同熱處理程序顯微組織觀察與分析 45 4-1-1高碳工具鋼(SK2)經過不同熱處理程序下顯微組織觀察與分析 45 4-1-2 軸承鋼(SUJ2)經過不同熱處理程序下顯微組織觀察與分析 66 4-1-3兩種鋼料顯微組織綜合分析與比較 83 4-2不同熱處理程序硬度分析 89 4-2-1 高碳工具鋼(SK2)進行不同熱處理程序下之洛氏硬度及維克氏硬度分析 89 4-2-2 軸承鋼(SUJ2)進行不同熱處理程序下之洛氏硬度及維克氏硬度分析 92 4-2-3 兩種鋼料硬度綜合分析與比較 94 4-3不同熱處理程序試片的磨潤行為 96 4-3-1不同試片之耐磨耗評估 97 4-3-2不同試片之穩態最高表面接觸溫度與摩擦係數 100 4-3-3 未經熱處理之高碳工具鋼磨屑X-ray繞射儀分析 101 4-3-4未經熱處理之高碳工具鋼磨耗表面形貌與摩擦行為 102 4-3-5不同熱處理程序之高碳工具鋼磨耗表面形貌與摩擦行為 105 4-3-6未經熱處理之軸承鋼磨耗表面形貌與摩擦行為 118 4-3-7不同熱處理程序之軸承鋼磨耗表面形貌與摩擦行為 120 4-3-8綜合分析之磨潤評估 131 第五章 結論與建議 133 5-1結論 133 5-2未來研究方向與建議 134 文獻探討 135 附錄 138

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