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研究生: 丁正祥
CHENG - HSIANG TING
論文名稱: 聚丙稀/苯乙烯三嵌段共聚物複合材料多品質加工參數之最佳化
Optimization of Processing Parameters for Multiple Qualities of PP/ERS Composites
指導教授: 黃昌群
Chang-Chiun Huang
口試委員: 郭中豐
Chung-Feng Jeffrey Kuo
邱智瑋
Chih-Wei Chiu
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2016
畢業學年度: 105
語文別: 中文
論文頁數: 95
中文關鍵詞: 聚丙烯苯乙烯三嵌段聚合物田口法層級分析法倒類神經網路粒子群優法。
外文關鍵詞: ERS, BPNN and PSO.
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  • 本論文的研究目的為利用增加軟鏈段長度的苯乙烯三嵌段共聚物(Enhanced rubber segment,ERS)提升聚丙烯(Polypropylene,PP)之物理性質並保有原光學性質,藉此提升市面嬰兒餐具之物理性質或光學性質的不足,並達到降低汰換率與節能環保的概念。經由參考不同的苯乙烯三嵌段共聚物文獻,瞭解材料物理性質與光學性質的變化,並找出適合本研究分析產品品質的混煉比例區間,再配合多項加工參數詳細分析品質間的變化,最後找出所希望的產品品質加工參數組。研究方法首先以田口法結合層級法去分析品質之影響並且獲得區域性最佳化參數,再透過田口實驗數據與倒傳遞類神經網路預測與模擬田口實驗設計法所得到的加工參數與產品品質之間的交互影響關係,之後以產品品質為粒子群優法的適應性函數,並將加工參數範圍作為粒子群優法的邊界條件,透過不斷地更新與迭代找出全域性最佳之加工參數組合。研究結果顯示,田口法結合層級分析法與倒傳遞類神經結合粒子群優法,能有效率地決策最佳加工參數,而倒傳遞類神經結合粒子群優法求得之最佳品質優於田口法與層級分析法所得之品質,且相較於市面產品各品質表現均有效的提升。


    The aim of this study is to upgrade mechanical properties and maintain optical properties of Polypropylene (PP) by Enhanced rubber segment (ERS) to enhance baby tableware qualities also achieve the concept of energy saving and low replacement rate. By reading different literatures will help us to understand the physical and optical properties of material and locate suitable mixing ratios for this study, then we can use some parameters for further analysis to find the optimal qualities of product. In the beginning, we will discuss the influence of the composite’s qualities in different ratios and find local optimal parameters by using Taguchi method with Analytic Hierarchy Process (AHP). After that, we will create a math model on Back-Propagation Neural Network (BPNN) by stimulating the interaction of parameters and qualities from Taguchi experimental design. Once BPNN makes a successful prediction, we will be able to use particle swarm optimization method to analyze the math model and set the parameter’s range as boundary conditions. Particle swarm optimization will constantly update and iterate until locating the global optimal parameters. As a conclusion, using Taguchi method along AHP and BPNN with particle swarm optimization will efficiently pin down the optimal parameters, but the final performance reviews that BPNN with particle swarm optimization is slightly more precise, offering a better outcome than Taguchi method along AHP. The final performance also has much better qualities than the products on the market.

    目錄 摘要 I ABSTRACT II 致謝 III 目錄 IV 圖目錄 VIII 表目錄 X 第一章 緒論 1 1.1. 前言 1 1.2. 研究動機與目的 2 1.3. 文獻回顧 4 1.4 論文研究流程 11 第二章 實驗設備與材料 12 2.1 材料介紹 12 2.1.1聚丙烯(Polypropylene, PP) 12 2.1.2苯乙烯三嵌段聚合物(Styrene Ethylene/Butylene Styrene, SEBS) 13 2.2 加工設備 15 2.2.1射出成型機 15 2.2.2 單螺桿混煉機 17 2.3 材料分析儀器 18 2.3.1 熱重損失分析儀 18 2.3.2 熱示差分析儀 19 2.3.3 萬能拉力試驗機 20 2.3.4霧度計 22 2.3.5 衝擊試驗機 23 第三章 製程最佳化理論 25 3.1田口實驗法 26 3.1.1 訊號雜訊比 27 3.1.2 變異數分析 28 3.1.3 因子反應表 31 3.1.4 信賴區間 31 3.2 層級分析法 32 3.2.1 層級與要素 33 3.2.2 評估尺度 33 3.2.3 AHP的進行步驟與運算方法 34 3.3 倒傳遞類神經網路 36 3.3.1 集成函數 38 3.3.2 轉換函數 38 3.3.3 正規化 39 3.3.4 加權值與偏權值調整 39 3.3.5 倒傳遞類神經之演算法 40 3.4 粒子群優法(PARTICLE SWARM OPTIMIZATION, PSO) 42 3.4.1 數學模式 43 3.4.2 多目標問題數學模式 44 第四章 實驗規劃及結果討論 47 4.1 實驗材料 47 4.2 材料分析 48 4.3實驗規劃 50 4.3.1 田口實驗規劃及實驗結果 50 4.3.2 層級分析結果 57 4.3.3 倒傳遞類神經規劃及實驗結果 61 4.3.4粒子群優演算法及實驗結果 68 第五章 結論 73 參考文獻 75

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