本研究論文以製備功能性材料為出發點，使用有機合成方式製備聚氨基甲酸酯(PU)，並導入新型含氟鏈延長劑，賦予聚氨基甲酸酯(PU)擁有其特殊性質，合成出新型含氟聚氨基甲酸酯(FPU)，進行一系列鑑定與分析。本研究分為三部分：第一部分使用4,4’-diphenylmethane diisocyanate (MDI)為硬鏈段、 polycaprolactone diol (PCL)為軟鏈段及4-(1,1,1,3,3,3-hexafluoro-2-(4-hydroxyphenyl)propan-2-yl)phenol (HFP)鏈延長劑，合成含氟聚胺基甲酸酯(HFP/PUs)，隨著HFP配方比增加，由體外紅血球沾附試驗結果發現，於HFP/PUs表面上的紅血球沾附量減少。
第二部分使用5H-octafluoropentanoyl (OFP)與2-amino-2-methyl-1,3-propanediol (AMPD)合成新型氟鏈延長劑2,2,3,3,4,4,5,5-octafluoro-N-(1,3-dihydroxy-2-methylpropan-2-yl) pentanamide (ODMP)，並以MDI為硬鏈段、PCL為軟鏈段，合成新型含氟聚胺基甲酸酯 (ODMP/PUs)，當ODMP配方比例增加時，由SEM圖像顯示ODMP/PUs水解降解性質降低，由體外紅血球研究結果發現，ODMP/PUs表面上的紅血球沾附量減少。
第三部分使用2,2,3,3,4,4,4-heptafluorobutanoyl chloride (HFC)與trimethylolpropane (TMP)合成新型氟鏈延長劑 2,2,3,3,4,4,4-Heptafluoro-butynic acid 2,2-bis-hydroxymethyl-butyl ester (HFBA)。並使用MDI為硬鏈段、PCL為軟鏈段，合成新型含氟聚胺基甲酸酯 (HFBA/PUs)，本研究特點在於HFBA/PUs的防水去污性能，隨著HFBA配方比例增加，HFBA/PUs塗層對水滴、茶污、油墨的阻抗能力提升。

The starting point of this research is to prepare the functional material. The organic synthesis way is used to prepare the polyurethane (PU). Furthermore, a new-type fluorine-containing chain extender is introduced to synthesize a new-type fluorine-containing polyurethane (FPU) with special properties. A series of characterizations and analyses are carried out. This research is divided into three parts: The first part uses 4,4’-diphenylmethane diisocyanate (MDI) as a hard segment, polycaprolactone diol (PCL) as a soft segment, and 4-(1,1,1,3,3,3-hexafluoro-2-(4-hydroxyphenyl)propan-2-yl)phenol (HFP) as a chain extender to synthesize the fluorine-containing polyurethane (HFP/PUs). From the result of red blood cell adhesion test in vitro, it is found that the red blood cell adhesion amount on HFP/PUs surface is decreased with the increase of HFP in the formula.
The second part uses 5H-octafluoropentanoyl (OFP) and 2-amino-2-methyl-1,3-propanediol (AMPD) to synthesize a new-type fluorine-containing chain extender 2,2,3,3,4,4,5,5-octafluoro-N- (1,3-dihydroxy-2-methylpropan-2-yl) pentanamide (ODMP). In addition, the MDI is used as a hard segment, and the PCL is used as a soft segment to synthesize a new-type fluorine-containing polyurethane (ODMP/PUs). When the proportion of ODMP is increased, the hydrolyzing degradation property of ODMP/PUs is decreased revealed from the SEM image, and the red blood cell adhesion amount on ODMP/PUs surface is decreased revealed from the red blood cell adhesion test in vitro.
The third part uses 2,2,3,3,4,4,4-heptafluorobutanoyl chloride (HFC) and trimethylolpropane (TMP) to synthesize a new-type fluorine-containing chain extender 2,2,3,3,4,4,4-Heptafluoro-butynic acid 2,2-bis-hydroxymethyl-butyl ester (HFBA). In addition, the MDI is used as a hard segment, and the PCL is used as a soft segment to synthesize a new-type fluorine-containing polyurethane (HFBA/PUs). This research is characterized by the waterproof decontamination performance of HFBA/PUs. When the proportion of HFBA is increased, the resistance of HFBA/PUs coating to water droplet, tea stain and ink is increased.

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