研究生: |
戴劭樺 Shao-Hua Dai |
---|---|
論文名稱: |
奈米級及次微米級核殼型橡膠添加劑、矽烷接枝二氧化矽顆粒、官能基化之氧化石墨烯、官能基化之脫層石墨烯奈米層板、高分子接枝之氧化石墨烯及高分子接枝之脫層石墨烯奈米層板對乙烯基酯樹脂之聚合固化反應動力、玻璃轉移溫度及X光散射特性之影響研究 Effects of nano-scale and submicron-scale core-shell rubber additives, silane-grafted silica particle, functionalized graphene oxide, functionalized exfoliated graphene nanoplatelet, polymer-grafted graphene oxide, and polymer-grafted exfoliated graphene nanoplatelet on the cure kinetics, glass transition temperatures, and X-ray scattering characteristics for vinyl ester resins. |
指導教授: |
黃延吉
Yan-Jyi Huang |
口試委員: |
陳崇賢
Chorng-Shyan Chern 邱文英 Wen-Yen Chiu |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2015 |
畢業學年度: | 103 |
語文別: | 中文 |
論文頁數: | 169 |
中文關鍵詞: | 核殼型橡膠 、二氧化矽奈米顆粒 、乙烯基酯樹脂 、聚合固化反應動力 、微分掃描熱分析儀 、傅立葉紅外光分析儀 、動態機械分析儀 、玻璃轉移溫度 、氧化石墨烯 、熱脫層氧化石墨烯 、小角度X光散射儀 、廣角度X光散射儀 、環動半徑 |
外文關鍵詞: | Core-Shell Rubber(CSR), Silica nanoparticle(SNP), Vinyl ester resin(VER), Curing kinetics, DSC, FTIR, DMA, Glass transition(Tg), Graphene oxide(GO), Thermally reduced graphene oxide(TRGO), Radius of gyration(Rg), SAXS, WAXS |
相關次數: | 點閱:803 下載:10 |
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本文目的為探討四種特用添加劑,分別為(1)奈米級及次微米級核殼型橡膠(Core-Shell Rubber, CSR) (2)矽烷接枝之二氧化矽奈米顆粒(Silane-grafted silica nanoparticle, SNP) (3)官能基化氧化石墨烯(Functionalized graphene oxide, GO) (4)脫層氧化石墨烯(functionalized thermally reduced graphene oxide, TRGO),其對苯乙烯(St)/乙烯基酯樹脂(VER)/特用添加劑三成份系統之聚合固化反應動力、玻璃轉移溫度及X光散射特性之影響。
本研究亦利用小角度X光散射儀(Small-angle X-ray Scattering, SAXS),測定VER於稀薄苯乙烯溶液之散射強度,進而根據Guinier law計算不同濃度下之環動半徑(Radius of gyration, Rg),利用廣角度X光散射儀測量苯乙烯/乙烯基酯樹脂/氧化石墨烯(GO)(或熱脫層氧化石墨烯(TRGO))三成份之聚合固化系統其X光散射強度曲線,可以探討GO或TRGO的規則層間距離(d-spacing)的變化及其在樹脂基材中的分散程度。該三成份聚合固化系統是原為插層式脫層的奈米複合材料之特性,因此而得以鑑定之。同時,吾人亦利用拉曼光譜儀(Raman Spectroscope, RS)鑑定官能基化氧化石墨烯與官能基化之脫層石墨烯奈米層板之化學結構。
此外,吾人亦使用差式掃描卡計(DSC)及傅立葉轉化紅外線光譜儀(FTIR)測量St/VER雙成份系統與St/VER/特用添加劑之三成分系統在聚合固化過程中的反應動力。最後根據Takayanagi機械模式,苯乙烯/乙烯基酯樹脂/特用添加劑三成份聚合固化系統其在每一相區的玻璃轉移溫度,吾人亦使用動態機械分析儀(DMA)測定之。
The effects of four special additives, including (1) nano-scale and submicron-scale core-shell rubber additive (CSR), (2) silane-grafted silica noanoparticle (SNP), (3) functionalized graphene oxide (GO), and (4) functionalized thermally reduced graphene oxide (TRGO), on the cure kinetics, glass transition temperature and X-ray scattering characteristics for the Styrene(St)/Vinyl ester resin(VER)/special additives ternary systems after the cure have been investigated.
The scattering intensity of vinyl ester resin (VER) with different structure in dilute styrene solution was measured by the method of small angle X-ray scattering (SAXS), and the radius of gyration of VER can then be calculated by using the Guinier law. Measuring the X-ray scattered intensity profile of the cured specimens for St/VER/GO (or TRGO) ternary system by using wide angle X-ray scattering (WAXS) allows one to investigate the change of d-spacing and the degree of dispersion of the substrate of functionalized graphene oxide (GO) or functionalized thermally reduced graphene oxide (TRGO) nanoplatelet. The structure of intercalated or exfoliated nanocomposites for the cured St/VER/GO (or TRGO) ternary system can then be identified. In the meanwhile, the chemical structures of functionalized graphene oxide (GO) and functionalized thermally reduced graphene (TRGO) were also characterized with Raman Spectroscope (RS)
Moreover, the reaction kinetics for the St/VER/special additive ternary system during the cure was measured by differential scanning calorimetry (DSC) and fourier transform infrared spectroscopy (FTIR). Finally, based on the Takayanagi mechanical models, the glass transition temperature in each region of the cured samples for St/VER/special additive ternary system has been measured by dynamic mechanical analysis (DMA).
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