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研究生: 梁耀龍
Yao- Lung Liang
論文名稱: 碳奈米材料於鈣鈦礦太陽能電池之研究
The Study on Carbon Nanomaterials in Perovskite Solar Cells
指導教授: 陳良益
Liang-Yih Chen
口試委員: 陳良益
Liang-Yih Chen
陳貞夙
Jen-Sue Chen
吳季珍
Jih-Jen Wu
邱智瑋
Chih-Wei Chiu
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2020
畢業學年度: 108
語文別: 中文
論文頁數: 118
中文關鍵詞: 鈣鈦礦太陽能電池奈米碳管碳電極
外文關鍵詞: perovskite, solar cell, carbon nanotube, carbon electrode
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在本研究中主要探討將碳奈米材料應用於鈣鈦礦太陽能電池對其效能的影響。在此,主要將碳奈米管材料添加於鈣鈦礦吸光層,以及使用混合不同奈米碳管比例的導電碳漿製作成碳電極取代原本電洞傳輸層與金電極。當鈣鈦礦層中添加0.06 mg的碳奈米管並同時以金做為電極時,其平均效率為10.2 %,最高效率可達12.4 %。由X-光繞射圖譜分析可知:添加碳奈米管於鈣鈦礦層時,鈣鈦礦的平均晶粒由53 nm下降至43 nm,且由交流阻抗頻譜分析結果中亦發現載子發生再結合阻力變小,導致太陽能電池短路電流密度值下降,以致於整體的轉換效率低於未添加碳奈米管的鈣鈦礦太陽能電池 (平均效率:13.1 %,最高效率:15.8 %)。此外,亦探討將不同比例碳奈米管添加至導電碳漿中,再以網版印刷法製備碳電極。由四點探針分析結果可知:當添加0.5 wt%碳奈米管至導電碳漿後,除了降低碳電極的片電阻值,由交流阻抗頻譜分析結果中得知載子的傳輸阻力變小、再結合阻力上升,使得填充因子增加,平均效率由未添加的5.88 %提升至6.41 %,而最高效率達8.06 %。


In this study, we mainly discuss the effect of applying carbon nanomaterials to perovskite solar cells (PSCs) on their performance. Herein, the carbon nanotubes were added to the perovskite light-harvesting materials. In addition, a conductive carbon paste mixed with different ratio of carbon nanotubes (CNTs) was employed as electrode of PSCs to replace the hole transport materials and gold (Au) electrode. When 0.06 mg carbon nanotubes were added to the perovskite layer and Au was used as the electrode, the average power conversion efficiency (PCE) was 10.2 % and the highest PCE could achieve 12.4 %. According to X-ray diffraction pattern analysis, the average grain size of perovskite reduces from 53 nm to 43 nm when CNTs were added to perovskite layer. In addition, the recombination resistance become small was also found in the results of electrochemical impedance spectroscopy (EIS) analysis to reduce the short current density of PSC. Therefore, the PCE of CNTs added perovskite solar cell was lower than that of the perovskite solar cell without addition of CNTs (average PCE: 13.1%, the highest PCE: 15.8%). We also investigated adding CNTs of different ration to the conductive carbon pate, and then using the blade coating method to prepare carbon electrode. From analysis results of the four-point probe, it could be known that when 0.5 wt% CNTs were added to conductive carbon paste, the sheet resistance of the carbon electrode could be reduced. In addition, according to the result of EIS analysis, improvement of fill factor is attributed to lower transport resistance and higher recombination resistance. The average PCE was improved from 5.88 % to 6.41 % and the highest PCE cloud achieve 8.06 %.

中文摘要 III Abstract IV 致謝 VI 目錄 VII 表目錄 X 圖目錄 XII 第一章、 緒論 1 1-1 前言 1 1-2 研究動機與目的 2 第二章、 理論基礎與文獻回顧 4 2-1 半導體簡介 4 2-1-1 半導體特性 4 2-1-2 p-n 接面(p-n junction) 7 2-2 鈣鈦礦材料 8 2-2-1 鈣鈦礦之能隙性質 11 2-3 鈣鈦礦太陽能電池簡介 12 2-3-1 介孔(mesoporous)結構 15 2-3-2 n-i-p平面結構 17 2-3-3 p-i-n平面結構 19 2-4 碳電極於鈣鈦礦太陽能電池之應用 20 2-4-1 雙界面結構(bi-interfacil structure) 21 2-4-2 三界面結構(tri-interfacil structure) 24 2-5 奈米碳管於鈣鈦礦太陽能電池之應用 28 2-5-1 奈米碳管簡介 28 2-5-2 奈米碳管添加於鈣鈦礦層 31 2-5-3 奈米碳管添加於電洞傳輸層 34 第三章、 實驗方法與步驟 37 3-1 實驗流程 37 3-2 實驗藥品與儀器設備 38 3-2-1 實驗藥品 38 3-2-2 實驗設備 40 3-2-3 分析儀器 43 3-3 實驗步驟 55 3-3-1 清洗FTO導電玻璃及定義工作面積 55 3-3-2 二氧化鈦緻密層及結構層製備 56 3-3-3 鋰處理修飾二氧化鈦電子傳輸層 57 3-3-4 DMF/DMSO混合溶劑預處理、奈米碳管前驅溶液配置與沉積鈣鈦礦層 58 3-3-5 沉積電洞傳輸層 60 3-3-6 蒸鍍金電極 60 3-3-7 網印碳電極 61 第四章、 結果與討論 62 4-1 以金電極進行鈣鈦礦太陽能電池之性能研究 62 4-2 奈米碳管添加對於鈣鈦礦層塗佈製程與性質之探討 67 4-2-1 奈米碳管添加對於鈣鈦礦層形貌與性質分析 68 4-2-2 奈米碳管添加對於鈣鈦礦太陽能電池性能之影響 79 4-3 以碳材作為電極進行鈣鈦礦太陽能電池效能之探討 84 4-3-1 碳電極的製程參數與電性分析 84 4-3-2 以碳電極進行鈣鈦礦太陽能電池製作與效能分析 86 第五章、 結論 91 第六章、 參考文獻 92

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全文公開日期 2025/08/17 (國家圖書館:臺灣博碩士論文系統)
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