簡易檢索 / 詳目顯示

研究生: 謝靜箖
Jing-Lin Hsieh
論文名稱: 高效率白光激發錯合體系統之磷光有機發光二極體
Highly efficient and white phosphorescent organic light-emitting diodes with exciplex emitting layer
指導教授: 李志堅
Chih-Chien Lee
口試委員: 李志堅
Chih-Chien Lee
劉舜維
Shun-Wei Liu
范慶麟
Ching-Lin Fan
張志豪
Chih-Hao Chang
學位類別: 碩士
Master
系所名稱: 電資學院 - 電子工程系
Department of Electronic and Computer Engineering
論文出版年: 2020
畢業學年度: 108
語文別: 中文
論文頁數: 65
中文關鍵詞: 有機發光二極體激發複合體高效率高亮度
外文關鍵詞: organic light-emitting diodes, Exciplex, high efficiency, high brightness
相關次數: 點閱:406下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報


摘要 I ABSTRACT II 圖目錄 VII 表目錄 IX Chapter 1緒論 1 1.1 前言 1 1.2 有機電致發光二極體歷史發展 1 Chapter 2 基礎理論 4 2.1 有機發光二極體原理 4 2.2 有機激發錯合體(Exciplex) 7 2.3 電激發光機制 9 2.3.1 Föster energy transfer 9 2.3.2 Dexter energy transfer 10 2.3.3 載子捕捉(Carrier trapping) 12 2.3.4 元件放光路徑及效率 12 Chapter 3 文獻回顧 14 3.1 第一篇文獻回顧 14 3.2 第二篇文獻回顧 15 3.3 第三篇文獻回顧 16 Chapter 4 實驗 18 4.1 實驗流程 18 4.1.1 黃光微影製程(photolithography) 18 4.1.2 熱蒸鍍製程 20 4.1.3 元件封裝 22 4.2 實驗儀器介紹 22 4.2.1 超音波震盪機 22 4.2.2 旋轉塗佈機 23 4.2.3 曝光機 24 4.2.4 濺鍍機 24 4.2.5 雷雕機 25 4.2.6 電漿機 26 4.2.7 熱蒸鍍機 26 4.2.8 手套箱 28 4.2.9 材料純化系統 29 4.3 量測儀器介紹 29 4.3.1 探針式膜厚量測儀 29 4.3.2 橢圓偏振儀 30 4.3.3 積分球 31 4.3.4 分光式輝度計 31 4.3.5 紫外-可見光光譜儀 32 4.3.6 螢光光譜儀 33 4.4 材料介紹 35 4.4.1 電洞注入材料 35 4.4.2 電洞傳輸材料 35 4.4.3 主動層放光材料 37 4.4.4 電子傳輸材料 38 4.4.5 電子注入材料 39 4.4.6 陰極材料 39 Chapter 5 結果與討論 40 5.1 光譜實驗結果 40 5.2 元件實驗結果 41 5.2.1 藍光元件 43 5.2.2 紅光元件一 44 5.2.3 紅光元件二 45 5.2.4 白光元件一 47 5.2.5 白光元件二 48 結論 50 References 51

[1] J. J. Lih, C. F. Sung, M. S. Weaver, M. Hack, and J. J. Brown, "4.3: A Phosphorescent Active-Matrix OLED Display Driven by Amorphous Silicon Backplane," SID Symposium Digest of Technical Papers, 34, 14-17 (2003).
[2]  J.-J. Lih and C.-F. Sung, "Full-color active-matrix OLED based on a-Si TFT technology," Journal of the Society for Information Display, 11, 617-620 (2003).
[3]  T. Sasaoka, M. Sekiya, A. Yumoto, J. Yamada, T. Hirano, Y. Iwase, T. Yamada, T. Ishibashi, T. Mori, M. Asano, S. Tamura, and T. Urabe, "24.4L: Late-News Paper: A 13.0-inch AM-OLED Display with Top Emitting Structure and Adaptive Current Mode Programmed Pixel Circuit (TAC)," SID Symposium Digest of Technical Papers, 32, 384-387 (2001).
[4]  Z. Y. Xie and L. S. Hung, "High-contrast organic light-emitting diodes," Applied Physics Letters, 84, 1207-1209 (2004).
[5]  M. Kashiwabara, K. Hanawa, R. Asaki, I. Kobori, R. Matsuura, H. Yamada, T. Yamamoto, A. Ozawa, Y. Sato, S. Terada, J. Yamada, T. Sasaoka, S. Tamura, and T. Urabe, "29.5L: Late-News Paper: Advanced AM-OLED Display Based on White Emitter with Microcavity Structure," SID Symposium Digest of Technical Papers, 35, 1017-1019 (2004).
[6]  G. He, M. Pfeiffer, K. Leo, M. Hofmann, J. Birnstock, R. Pudzich, and J. Salbeck, "High-efficiency and low-voltage p‐i‐n electrophosphorescent organic light-emitting diodes with double-emission layers," Applied Physics Letters, 85, 3911-3913 (2004).
[7]  H. Sasabe, N. Toyota, H. Nakanishi, T. Ishizaka, Y. J. Pu, and J. Kido, "3,3'-Bicarbazole-based host materials for high-efficiency blue phosphorescent OLEDs with extremely low driving voltage," Advanced Materials, 24, 3212-7 (2012).
[8]  P. E. Burrows, G. Gu, V. Bulovic, Z. Shen, S. R. Forrest, and M. E. Thompson, "Achieving full-color organic light-emitting devices for lightweight, flat-panel displays," Ieee Transactions on Electron Devices, 44, 1188-1203 (1997).
[9] A. B. Chwang, M. A. Rothman, S. Y. Mao, R. H. Hewitt, M. S. Weaver, J. A. Silvernail, K. Rajan, M. Hack, J. J. Brown, X. Chu, L. Moro, T. Krajewski, and N. Rutherford, "Thin film encapsulated flexible organic electroluminescent displays," Applied Physics Letters, 83, 413-415 (2003).
[10] M. Pope, H. P. Kallmann, and P. Magnante, "Electroluminescence in Organic Crystals," The Journal of Chemical Physics, vol. 38, pp. 2042-2043, 1963.
[11] C. W. Tang and S. A. VanSlyke, "Organic electroluminescent diodes," Applied Physics Letters, 51, 913-915 (1987).
[12] D. F. O’Brien, M. A. Baldo, M. E. Thompson, and S. R. Forrest, "Improved energy transfer in electrophosphorescent devices," Applied Physics Letters, vol. 74, pp. 442-444, 1999.
[13] S. Y. Lee, T. Yasuda, H. Komiyama, J. Lee, and C. Adachi, "Thermally Activated Delayed Fluorescence Polymers for Efficient Solution-Processed Organic Light-Emitting Diodes," Advanced Materials, 28, 4019-4024 (2016).
[14] A. Endo, K. Sato, K. Yoshimura, T. Kai, A. Kawada, H. Miyazaki, and C. Adachi, "Efficient up-conversion of triplet excitons into a singlet state and its application for organic light emitting diodes," Applied Physics Letters, 98, 083302 (2011).
[15] S. Youn Lee, T. Yasuda, H. Nomura, and C. Adachi, "High-efficiency organic light-emitting diodes utilizing thermally activated delayed fluorescence from triazine-based donor–acceptor hybrid molecules," Applied Physics Letters, 101, 093306 (2012).
[16] H. Tanaka, K. Shizu, H. Miyazaki, and C. Adachi, "Efficient green thermally activated delayed fluorescence (TADF) from a phenoxazine-triphenyltriazine (PXZ-TRZ) derivative," Chemical Communications, 48, 11392-11394 (2012).
[17] T. Nakagawa, S.-Y. Ku, K.-T. Wong, and C. Adachi, "Electroluminescence based on thermally activated delayed fluorescence generated by a spirobifluorene donor-acceptor structure," Chemical Communications, 48, 9580-9582 (2012).
[18] Q. S. Zhang, J. Li, K. Shizu, S. P. Huang, S. Hirata, H. Miyazaki, and C. Adachi, "Design of Efficient Thermally Activated Delayed Fluorescence Materials for Pure Blue Organic Light Emitting Diodes," Journal of the American Chemical Society, 134, 14706-14709 (2012).
[19] H. Uoyama, K. Goushi, K. Shizu, H. Nomura, and C. Adachi, "Highly efficient organic light-emitting diodes from delayed fluorescence," Nature, 492, 234 (2012).
[20] A. Endo, K. Sato, K. Yoshimura, T. Kai, A. Kawada, H. Miyazaki, and C. Adachi, "Efficient up-conversion of triplet excitons into a singlet state and its application for organic light emitting diodes," Applied Physics Letters, 98, 083302 (2011).
[21] S. Youn Lee, T. Yasuda, H. Nomura, and C. Adachi, "High-efficiency organic light-emitting diodes utilizing thermally activated delayed fluorescence from triazine-based donor–acceptor hybrid molecules," Applied Physics Letters, 101, 093306 (2012).
[22] H. Tanaka, K. Shizu, H. Miyazaki, and C. Adachi, "Efficient green thermally activated delayed fluorescence (TADF) from a phenoxazine-triphenyltriazine (PXZ-TRZ) derivative," Chemical Communications, 48, 11392 (2012).
[23] T. Nakagawa, S.-Y. Ku, K.-T. Wong, and C. Adachi, "Electroluminescence based on thermally activated delayed fluorescence generated by a spirobifluorene donor-acceptor structure," Chemical Communications, 48, 9580-9582 (2012).
[24] Q. S. Zhang, J. Li, K. Shizu, S. P. Huang, S. Hirata, H. Miyazaki, and C. Adachi, "Design of Efficient Thermally Activated Delayed Fluorescence Materials for Pure Blue Organic Light Emitting Diodes," Journal of the American Chemical Society, 134, 14706 (2012).
[25] H. Uoyama, K. Goushi, K. Shizu, H. Nomura, and C. Adachi, "Highly efficient organic light-emitting diodes from delayed fluorescence," Nature, 492, 234 (2012).
[26] X. K. Liu, Z. Chen, J. Qing, W.-J. Zhang, B. Wu, H. L. Tam, F. Zhu, X.-H. Zhang, C.-S. Lee, "Remanagement of Singlet and Triplet Excitons in Single-Emissive-Layer Hybrid White Organic Light-Emitting DevicesUsing Thermally Activated Delayed Fluorescent Blue Exciplex" Advanced Materials, 27, 7079-7085 (2015).
[27] D. Luo, Q. Chen, Y. Gao, M. Zhang, and B. Liu, "Extremely Simplified, High-Performance, and Doping-Free White Organic Light-Emitting Diodes Based on a Single Thermally Activated Delayed Fluorescent Emitter" ACS Energy Letters, 3, 1531−1538 (2018).
[28] X. Tang, X.-Y. Liu, Y. Yuan, Y.-J. Wang, H.-C. Li, Z.-Q. Jiang, L.-S. Liao, "High-Efficiency White Organic Light-Emitting Diodes Integrating Gradient Exciplex Allocation System and Novel D‑Spiro‑A Materials" ACS Applied Materials & Interfaces., 10, 29840-29847 (2018).
[29] W.-Y. Hung, P.-Y. Chiang, S.-W. Lin, W.-C. Tang, Y.-T. Chen, S.-H. Liu, P.-T. Chou, Y.-T. Hung, and K.-T. Wong, "Balance the Carrier Mobility To Achieve High Performance Exciplex OLED Using a Triazine-Based Acceptor" ACS Applied Materials & Interfaces., 8, 4811-4818 (2016).
[30] S. E. Shaheen, G. E. Jabbour, M. M. Morrell, Y. Kawabe, B. Kippelen and N.Peyghambarian, "Bright blue organic light-emitting diode with improved color purity using a LiF/Al cathode, " Journal of Applied Physics, 84, 2324 (1998).

無法下載圖示 全文公開日期 2025/07/31 (校內網路)
全文公開日期 本全文未授權公開 (校外網路)
全文公開日期 本全文未授權公開 (國家圖書館:臺灣博碩士論文系統)
QR CODE