研究生: |
黃景嫻 Jing-Sian Huang |
---|---|
論文名稱: |
含RAFT試劑之馬來醯亞胺/巴比妥酸聚合反應之研究 Study for Polymerization of N,N-Bismaleimide-4,4-Diphenylmethane/Barbituric Acid in the Presence of RAFT Agent |
指導教授: |
陳崇賢
Chorng-Shyan Chern |
口試委員: |
王復民
Fu-Ming Wang 許榮木 Jung-Mu Hau |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2015 |
畢業學年度: | 103 |
語文別: | 中文 |
論文頁數: | 77 |
中文關鍵詞: | 可逆加成斷鏈鏈轉移聚合法 、雙馬來醯亞胺 、巴比妥酸 、雙苯甲基三硫碳酸酯 |
外文關鍵詞: | DBTTC, RAFT, BMI, BTA |
相關次數: | 點閱:377 下載:4 |
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本實驗主要研究固定莫爾比下(固含量10%),使用雙馬來醯亞胺(N,N-bismaleimide-4,4-diphenylmethane, BMI)、巴比妥酸(Barbituric acid, BTA)以及雙苯甲基三硫碳酸酯(Dibenzyltrithiocarbonate, DBTTC),使用可逆加成斷鏈鏈轉移聚合法(RAFT)合成高分子,系統中之固定莫爾比為BMI/BTA ((2/1(mol/mol)),透過聚合反應進行反應動力學。
主要使用微分式掃描熱量分析儀(DSC),在溫度373-403K反應恆溫一小時,將反應放熱數據利用Excell處理以及利用Matlab數學軟體模擬出m跟n值,再透過Arrhenius方程式計算出活化能(Ea)及頻率因子(A)值,探討不同含量的雙苯甲基三硫碳酸酯(DBTTC)在不同溫度下對反應動力學之影響。
This work was studied on the kinetics of polymerization of N,N-bismaleimide-4,4-diphenylmethane/Barbituric acid in fixed molar ratio with Dibenzyltrithiocarbonate which used as reversible addition-fragmentation chain transfer (RAFT) agent. The system of BMI/BTA = 2/1(mol/mol) was chosen in this work.
The differential scanning calorimerter (DSC) was used to measure the heat of reation for one hour at the isothermal temperature in the range of 373-403 K. The exothermic data of the reaction were calculated via Excell process and used the Matlab mathematical software to simulate the value of m with n, and then through the Arrhenius equation calculated the activation energy (Ea) and frequency factor (A). Therefore, those data could investigate the effect of kinetics of polymerization on different contents of Dibenzyltrithiocarbonate (DBTTC) in different temperature.
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