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研究生： 賴姵宇
Pei-Yu Lai
論文名稱： 金屬玻璃鍍層於鋰電池正極鋁集流板之腐蝕特性研究
Investigation of corrosion properties of thin film metallic glasses on cathodic aluminum current collectors in lithium ion batteries
指導教授： 朱瑾
Jinn P. Chu
黃炳照
Bing-Joe Hwang
口試委員: 鄭銘堯
Ming-Yao Cheng
學位類別： 碩士
Master
系所名稱： 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年： 2016
畢業學年度： 104
語文別： 英文
論文頁數： 137
中文關鍵詞： 雙三氟甲烷磺醯亞胺鋰 、鋁集流板 、腐蝕 、金屬玻璃薄膜 、類固液界面膜
外文關鍵詞： Lithium bis(trifluoromethane sulfonyl) imide, corrosion, aluminum current collector, thin film metallic glass, solid-electrolyte-interface-like layer
相關次數： 點閱：271  下載：0 
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    • 雙三氟甲烷磺醯亞胺鋰(LiTFSI)電解鹽之化學穩定性及熱穩定性優於六氟磷酸鋰(LiPF6)鹽，如作為鋰電池電解液鹽類，不僅可降低電池安全性顧慮，亦可提升電池使用壽命。

    Lithium bis(trifluoromethane sulfonyl) imide (LiTFSI) salt is claimed to be a potential alternative to lithium hexafluorophosphate (LiPF6) since it has greater electrochemical properties such as chemical and thermal stability which may provide benefits of higher safety and longer lifetime of lithium ion batteries (LIBs).

    Table of Contents 摘要 I Abstract II Acknowledgements IV Table of Contents V List of Figures VII List of Tables XII Chapter 1 Introduction 1 1.1 Evolution and Developments of Lithium Batteries 1 1.2 Overview of Metallic Glasses (MGs) 2 1.3 Motivation and Objectives of the Work 3 Chapter 2 Background 5 2.1 Lithium Ion Batteries (LIBs) 5 2.1.1 Working Principles of LIBs 5 2.1.2 Materials for LIBs 8 2.1.3 Corrosion of Al current collectors in LIBs 13 2.2 Thin Film Metallic Glasses (TFMGs) 16 2.2.1 Concepts and Characteristics 16 2.2.2 Anti-corrosion Properties 18 2.2.3 Fabrication of TFMGs – Magnetron Sputtering 22 Chapter 3 Experimental Procedures 24 3.1 Instruments 24 3.2 Materials 25 3.3 Study Methodologies 26 3.3.1 Substrate Preparation 28 3.3.2 Electrolyte Preparation 30 3.3.3 Electrode Preparation 31 3.3.4 2-Electrode System Assembly 34 3.3.5 3-Electrode System Assembly 35 3.4 Materials Characterizations 36 3.4.1 Microstructural Analyses 36 3.4.2 Electrical Resistivity 38 3.4.3 Electrochemical Stability 39 3.4.4 Water Content 41 3.4.5 Crystallographic Characterization 42 3.5 Electrochemical Measurements 43 3.5.1 Electrochemical Resistance 43 3.5.2 Corrosion Behavior 43 3.5.3 Ecorr and Jcorr Determination 44 3.5.4 Charge-Discharge Cycling Performance 44 Chapter 4 Results and Discussion 46 4.1 Effects of TFMGs on the Anti-corrosion Property of Al Substrates 46 4.1.1 Characterizations of Al Current Collectors 46 4.1.1.1 Microstructural Analyses 46 4.1.1.2 Ecorr and Jcorr Determination 52 4.1.2 Corrosion Test Trials 58 4.1.3 Corrosion and Impedance Tests 60 4.1.3.1 Corrosion Behavior 60 4.1.3.2 Electrochemical Resistance 66 4.1.4 Microstructural Analyses after Corrosion 72 4.2 Integration of Cathode Materials with TFMG-Coated Current Collectors 92 4.2.1 Cell System Trials 92 4.2.2 Characterizations of Electrodes 95 4.2.2.1 Microstructure Observation 95 4.2.2.2 Crystallographic Characterization 96 4.2.3 Coin Cell Cycling Performance 97 4.2.3.1 Capacity and Retention 97 4.2.3.2 Electrochemical Resistance 102 4.2.4 Supplementary Tests- Sample Microstructural Analyses after the Corrosion Test within the Electrolyte of an addition of LiPF6 105 4.3 Corrosion Types and Proposed Corrosion Mechanisms 108 4.4 Overall Discussion 112 Chapter 5 Conclusions 114 References 116

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