全固態電池(All-solid-state battery, ASSB)與傳統的鋰離子電池(Lithium-ion battery, LIB)相比更安全，且具有更高的能量密度和更廣的工作溫度範圍，使其成為未來的前景。具有層狀結構的富鎳過渡金屬氧化物(LiNi0.8Mn0.1Co0.1O2, NCM 811)是具有高能量密度和高充電電壓等有前途的正極活性材料。為了製備全固態電池中的複合正極，添加了硫化物顆粒以降低正極和固態電解質之間的介面阻抗。然而，硫化物由於其窄的電化學窗口和活性材料之間會產生介面反應，使得介面阻抗增加而不夠穩定。
本實驗將克服這些挑戰，使用具有不同摩爾比的PEO聚合物與雙(三氟甲基磺醯)氨基鋰(LiTFSI)，分別應用於LiNbO3@NCM811高電壓正極材料與LiFePO4低電位正極材料，PEO-LiTFSI可以在複合正極中形成離子傳遞路徑並作為黏著劑。第一部份應用於LNO@NCM811正極材料上，通過濕式混漿法塗布厚度約為80 μm的複合正極。由PEO-LiTFSI和NCM811組成的複合正極透過交流阻抗與不鏽鋼對稱電池進行導離子與導電子率的量測，90 vol.% NCM811和10 vol.% PEO-LiTFSI 的複合正極膜於60℃時的導離子與導電子率分別為2.84 × 10-4 S/cm和3.76 × 10-3 S/cm。以Li6PS5Cl硫化物電解質和銦金屬作為負極所組成的混合型全固態電池，電位區間為2~3.9 V(Li-In/Li+)，其第三循環的放電電容量和庫侖效率分別為90.09 mAh/g和81.24%，雖然電容維持率並不是很優異，但是在前五圈的放電電容量是高於硫化物全固態電池。
第二部份應用於LiFePO4正極材料上，同樣使用PEO-LiTFSI導離子性高分子黏著劑進行複合正極膜的製備，此時充放電的電位區間比較適合PEO-LiTSFI為2.4~3.1 V(Li-In/Li+)，首圈的放電電容量和庫倫效率為51.79 mAh/g 和61.8%，其電容維持率不是很好，因為來自銦金屬負極的衰退，還有LiFePO4與Li6PS5Cl間的化學反應造成正極介面阻抗增加。兩個部份在電容維持率上都還有很大的進步空間，不過我們建立了電池衰退的分析方法是可以更清楚改進的方向。

All-solid-state batteries (ASSBs) are safer and have higher energy density and a larger operating temperature window than conventional Li-ion batteries, making them a future perspective. Nickel-rich lithium transition metal oxides (LiNi0.8Mn0.1Co0.1O2, NMC811) with the layered structure are promising cathode candidates for high energy density and high charging voltage. To prepare a composite cathode, sulfide-based particles have been added to reduce the interfacial resistance between the cathode and solid-state electrolyte. However, sulfide is not stable enough due to its narrow electrochemical window and interfacial resistance between active materials.
The strategies to overcome these challenges are utilizing PEO-based polymers with different molar ratios of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI). It can also form an ionic conducting pathway in the composite cathode and act as a binder to fabricate a sheet-type electrode. We will divide it into two parts, LNO@NCM811, and LiFePO4 cathode active materials are contained. For the first part, a composite cathode film including NCM811 cathode active materials and PEO-LiTFSI with a thickness of 80 μm is coated by the slurry-coating process. The composite cathodes consisting of PEO-LiTFSI and NCM811 are assessed by AC impedance techniques with symmetric ion-blocking cells. The ionic and electronic conductivities of the composite with 90 vol.% of NMC811and 10 vol.% PEO-LiTFSI were determined as 2.84 × 10-4 S/cm and 3.76 × 10-3 S/cm at 60℃ respectively. With the condition of the potential range from 2 to 3.9 V(vs. Li-In/Li+), the 3rd cycle of discharge capacity and coulombic efficiency of ASSBs with pellet-type LPSC sulfide electrolyte and indium metal as an anode is 90.09 mAh/g and 81.24%, respectively. Although the capacity retention is not quite good, the discharge capacity
The second part is combined LiFePO4 cathode active material and PEO-LiTFSI ion-conducting binder for the preparation of the composite cathode film. With the condition of the potential range from 2.4 to 3.1 V(vs. Li-In/Li+), the discharge capacity and coulombic efficiency of the first cycle are 51.79 mAh/g and 61.8%. Its capacity retention is also not good, because of the decay from the indium as anode, and the chemical reaction between LiFePO4 and Li6PS5Cl causes the interface resistance between cathode and electrolyte increase. There is still a lot of space for improvement in the capacity retention of this two parts. However, the analysis method for the reason of battery aging is established and the direction for improvement can be more clearly identified.

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