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研究生： 張祐錡
Yu-Chi Chang
論文名稱： 常壓電漿氮化處理對AISI 304不鏽鋼抗衝擊磨損和耐蝕性能之研究
Study of Atmospheric Pressure Plasma Nitriding on Impact Wear and Corrosion Resistance of AISI 304 Stainless Steel
指導教授： 郭俞麟
Yu-Lin Kuo
口試委員: 趙振綱
Ching-Kong Chao
李志偉
Jyh-Wei Lee
許正勳
Cheng-Hsun, Hsu
學位類別： 碩士
Master
系所名稱： 工程學院 - 機械工程系
Department of Mechanical Engineering
論文出版年： 2021
畢業學年度： 109
語文別： 中文
論文頁數： 120
中文關鍵詞： 常壓電漿氮化處理 、AISI 304不鏽鋼 、抗衝擊磨損能力 、耐蝕性
外文關鍵詞： atmospheric pressure plasma nitriding (APPN), AISI 304 stainless steel, impact wear resistance, corrosion resistance
相關次數： 點閱：154  下載：0 
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    • 第一章 緒論 1 1.1 前言 1 1.2 研究背景與目的 4 第二章 文獻回顧 5 2.1 不鏽鋼介紹 5 2.1.1 定義 5 2.1.2 合金元素對不鏽鋼的影響 6 2.1.3 實驗所使用之材料 10 2.2 氮化處理 11 2.2.1 介紹 11 2.2.2 氮化原理與技術 11 2.2.3 氮化層組織與性質 16 2.2.4 化合物層厚度的控制 18 2.2.5 氮化物形成元素 18 2.3 擴散介紹 20 2.3.1 定義 20 2.3.2 擴散機制 21 2.3.3 穩態擴散 22 2.3.4 非穩態擴散 24 2.4 電漿介紹 27 2.4.1 定義 27 2.4.2 原理及反應機制 28 2.4.3 崩潰電壓 33 2.4.4 非平衡電漿與平衡電漿 33 2.4.5 常壓電漿 34 2.5 腐蝕介紹 37 2.5.1 定義 37 2.5.2 化學腐蝕與電化學腐蝕 37 2.5.3 微電池 39 2.5.4 腐蝕電位與腐蝕速率 41 2.5.5 腐蝕電流及速度的測量方法 42 2.5.6 腐蝕型態 44 2.5.7 合金元素對不鏽鋼耐蝕性的影響 47 第三章 實驗方法 50 3.1 實驗設計 50 3.2 實驗材料 52 3.3 實驗步驟 53 3.3.1 AISI 304不鏽鋼之氮化前處理 53 3.3.2 常壓電漿噴射束之氮化處理流程 53 3.4 實驗設備 55 3.5 分析儀器 57 3.5.1 光學放射光譜儀 57 3.5.2 熱電偶溫度計 58 3.5.3 光學顯微鏡 59 3.5.4 場發射掃描式電子顯微鏡 60 3.5.5 X光繞射儀 61 3.5.6 維克氏硬度機 61 3.5.7 循環式動態衝擊試驗機 63 3.5.8 白光干涉儀 63 3.5.9 恆電位儀 64 第四章 結果與討論 66 4.1 電漿檢測 66 4.1.1 電漿物種分析 66 4.2 溫度測量 68 4.2.1 溫度分析 68 4.3 微結構觀察 71 4.3.1 光學顯微鏡用於不鏽鋼剖面之腐蝕形貌分析 71 4.3.2 場發射掃描式電子顯微鏡用於表面、剖面形貌分析 74 4.4 元素與晶體結構判定 77 4.4.1 能量散射光譜儀用於氮元素成分分析 77 4.4.2 X光繞射分析 79 4.5 機械性質分析 83 4.5.1 表面硬度分析 83 4.5.2 剖面硬度分析 85 4.5.3 衝擊試驗分析 88 4.6 電化學分析 90 4.6.1 動電位極化曲線分析 90 4.7 氮化機制推導 94 4.7.1 常壓電漿噴射束之氮化機制探討 94 4.7.2 氮化動力學探討 96 第五章 結論 98 第六章 未來展望 99 參考文獻 100

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