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研究生： 陳薇婷
Wei-Ting Chen
論文名稱： 開發雙極異質薄膜實現超高性能蒸騰驅動產電
Bipolar Heterogeneous Membranes for Transpiration-Driven Power Generation with Ultrahigh Performance
指導教授： 葉禮賢
Li-Hsien Yeh
口試委員: 童國倫
Kuo-Lun Tung
劉偉仁
Wei-Ren Liu
邱昱誠
Yu-Cheng Chiu
學位類別： 碩士
Master
系所名稱： 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年： 2022
畢業學年度： 110
語文別： 中文
論文頁數： 87
中文關鍵詞： 離子傳輸 、電動能源轉換 、毛細作用 、蒸騰作用 、水驅動能源產生器 、聚電解質 、二維材料
外文關鍵詞： Ion transport, Electrokinetic energy conversion, Capillary action, Transpiration, Water-enabled power generator, Polyelectrolyte, Two dimensional material
相關次數： 點閱：262  下載：0 
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    • 現今環境汙染與能源危機已成為全球熱議的話題，隨著碳中和目標的提出，發展綠色能源成為迫在眉睫的需求。過去幾年，電動能源轉換的概念被提出，透過外界壓力驅使流體通過表面帶電通道進而產生能源，卻因轉換效率低(< 5%)而受限於實際應用。在這裡，我們設計一種雙極異質薄膜，該薄膜結合二维石墨烯及兩種雙極聚電解質(聚苯乙烯磺酸鈉(PSS)和聚賴氨酸(PLL))，在導電二維石墨烯的幫助下，兩種帶有空間電荷之聚電解質可作為高速離子傳輸層。此外，不對稱的電荷設計不僅可以通過膜誘導電荷分離且具有離子整流的特性，藉此來達到高效的電動能源轉換。當滴上0.3 ml去離子水溶液於薄膜一端時能產生高達0.74 V的開路電壓和32 μA的短路電流且發電時間可長達4小時。最後我們使用上述蒸騰驅動發電裝置來啟動商業用計算機和點亮不同顏色之LED，此種設計概念不僅可以成為下一世代自發性電動能源產生裝置的強大基礎，也可以大幅提高電動能源轉換效率，在未來應用上勢必具有無限的潛力。

    Nowadays environmental pollution and energy crisis have become the talk of the town. With the global “carbon neutrality” goal being proposed, the development of renewable energy has become the trend. Over the past one decade, the concept of the electrokinetic energy conversion (EKEC), where the energy can be generated by the pressure-driven flow of solution through charge channels, has emerged. However, the low EKEC efficiency (< 5%) limits its practical applications. Herein, we develop a layer-by-layer bipolar heterogeneous membrane, composed of a two-dimensional (2D) graphene and two types of bipolar polyelectrolytes (i.e., poly(sodium 4-styrenesulfonic) (PSS) and poly-L-lysine (PLL)), for highly efficient transpiration-driven EKEC. Both the polyelectrolytes with space charges are utilized as the high-speed ion transport layers, with the help of the conductive 2D graphene. Moreover, the design of asymmetric bipolar charges can induce charge separation through the membrane as well as ionic rectification, both of which are capable of enhancing the energy generation efficiency. As a result, a high open-circuit voltage of ~0.74 V, a high short-circuit current of ~32 A, along with a significantly amplified power generation time (> 4 hr) can be achieved by dropping 0.3 mL pure deionized water onto the membrane. The use of the developed transpiration-driven power generator in powering electronics such as LEDs and commercial calculator is also demonstrated. This study is not only of fundamental significance for boosting EKEC efficiency but also paves a new avenue towards water-enabled sustainable energy generator.

    中文摘要 II Abstract V 致謝 VI 目錄 VII 圖目錄 X 表目錄 XIV 第一章 緒論 1 1.1前言 1 1.2文獻回顧 3 1.3研究動機 12 第二章 原理機制 14 2.1 電雙層 14 2.2 離子電流整流效應 15 2.3 電動現象 17 2.4 電動能源轉換 18 第三章 實驗裝置與流程 22 3.1 實驗藥品 22 3.2 實驗製備裝置 23 3.3 實驗製備流程 24 3.4 實驗架設 26 3.5 材料分析儀器 27 第四章 結果與討論 31 4.1石墨烯材料性質分析 31 4.1.1 拉曼光譜分析(Raman spectroscopy) 31 4.1.2 掃描式電子顯微鏡分析 (SEM) 31 4.1.3 原子力顯微鏡分析 (AFM) 31 4.1.4 界面電位分析 (Zeta potential) 32 4.2 雙極異質薄膜材料性質分析 32 4.2.1 掃描式電子顯微鏡分析 (SEM) 32 4.2.2 傅立葉紅外線光譜分析(FTIR) 33 4.2.3 接觸角分析 (Contact angle) 32 4.3 雙極異質薄膜之產電效能實驗結果分析 33 4.3.1 雙極異質薄膜之離子整流 33 4.3.2 導電材料對於雙極異質薄膜影響之實驗驗證 33 4.3.3 聚電解質塗布比例對於雙極異質薄膜影響之實驗驗證 34 4.3.4 溶液滴入方向對於雙極異質薄膜影響之實驗驗證 34 4.3.5 滴水量對於雙極異質薄膜影響之實驗驗證 34 4.3.6 長度對於雙極異質薄膜影響之實驗驗證 35 4.3.7 寬度對於雙極異質薄膜影響之實驗驗證 35 4.3.8 鹽溶液對於雙極異質薄膜影響之實驗驗證 35 4.3.9 彎曲角度對於雙極異質薄膜影響之實驗驗證 36 4.4 雙極異質薄膜於電動能源轉換之結果分析 36 4.4.1 雙極異質薄膜於電動能源轉換之真實功率輸出結果 36 4.4.2 雙極異質薄膜於真實功率輸出之提升 36 4.5 雙極異質薄膜應用之結果分析 37 4.5.1 串聯與並聯對於雙極異質薄膜影響之實驗驗證 37 4.5.2 雙極異質薄膜實際應用 37 第五章 結論 37

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