固態聚合物電解質（SPE）由於其與鋰金屬的良好相容性、高柔韌性和安全性，是下一代固態電池中最有希望的固態電解質之一。為了在能量密度上與當前使用的常規鋰離子電池競爭，SPE必須與LiNixMnyCozO2（x+y+z = 1, 0.5 < x < 1）（NMC）的高能量密度陰極集成在一起。在研究工作中，已生研發出AAM950 / CEAM950和雙（氟磺酰基）酰亞胺鋰（LiFSI）作為固體聚合物電解質（SPE）。通過熱重分析和差示掃描量熱法（TGA-DSC）、核磁共振（NMR）、傅立葉轉移紅外光譜（FT-IR）和充電/放電測試研究了固態聚合物電解質的形態、化學和結構特徵。
CEAM950在25°C時具有2.04×10-4 S cm-1的高離子電導率，在90℃時具有2.41×10-3 S cm-1的高離子電導率。AAM950/CEAM950具有良好的機械性能、高離子電導率、高電化學和熱穩定性。此外，包含性能最佳的SPE的Li / LiNi0.6Mn0.2Co0.2O2電池具有高放電容量和出色的循環性能。
當用作為鋰存儲材料時，矽以高電容量但體積變化大的特性而聞名，而聚合物黏著劑基本上有助於改善循環壽命和增加矽陽極的面積容量。本研究提出了一種藉由氫化矽烷化反應而形成穩固的網狀黏著劑，以達到具有穩定循環性能的高面積電容量的矽陽極。再加入的丙烯酸/丙烯酸2-羧乙酯（AA / CEA）進一步增強了聚合物鏈的局部連接，AA / CEA含有豐富的羥基和羧基，這些羥基和羧基通常可確保它們與矽之間的牢固結合親和力。因此所合成的AAM950 / CEAM950具有持久的界面黏著力，可穩定矽陽極的結構完整性。

The solid polymer electrolyte (SPE) is one type of the most promising solid-state electrolytes for next-generation solid-state batteries, due to its good compatibility with Li-metal, high flexibility, and safety. To compete with currently used conventional Li-ion batteries in energy density, SPEs must be integrated with high energy density cathode of LiNixMnyCozO2（x+y+z = 1, 0.5 < x < 1）（NMC）. In this work, AAM950/CEAM950 and lithium bis(fluorosulfonyl)imide (LiFSI) have been produced as solid polymer electrolytes (SPEs). Morphological, chemical and structural characterizations of the solid-state composite electrolytes are studied by thermogravimetric analysis and differential scanning calorimetry (TGA-DSC), Nuclear Magnetic Resonance (NMR), Fourier transfer-infrared spectrometry (FT-IR) and charge/discharge tests.
CEAM950 shows high ionic conductivities of 2.04 ×10-4 S cm-1 at 25 °C and above2.41×10-3 S cm-1 at 90 ℃. The AAM950/CEAM950 provide good mechanical property, high ionic conductivity, high electrochemical and thermal stability. Moreover, Li/ LiNi0.6Mn0.2Co0.2O2 cells containing the best-performing SPE exhibit high discharge capacity and excellent cycling performance.
Silicon is known for high capacity and large volume change properties when used as lithium storage material. Polymeric binders substantially contribute to improving the cycling life and increasing areal capacity of silicon anode. Herein, a robust network binder via linking by Hydrosilylation is proposed to achieve stable cycling performance of silicon anode with high areal capacity. The Acrylic acid/ 2-Carboxyethyl acrylate (AA/CEA) introduced further enhances the localized linking for the polymer chains. Because AA/CEA is rich in abundant hydroxyl and carboxyl groups that conventionally ensure a strong binding affinity between the AA/CEA and Si. The resultant AAM950/CEAM950 owns durable interfacial adhesion and outstanding mechanical properties to stabilize the structural integrity of Si anode.

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