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研究生: 努萊拉
Nur - Laila Hamidah
論文名稱: 含氟官能基之馬來醯亞添加劑合成及其新創鈍性膜對鋰離子電池性能影響之研究
Synthesis of fluorine functional group of maleimide based additive and its applications to the solid electrolyte interface (SEI) formation of lithium ion battery
指導教授: 王復民
Fu-Ming Wang
口試委員: 黃炳照
Bing-Joe Hwang
陳崇賢
Chorng-Shyan Chern
許榮木
Jung-Mu Hsu
學位類別: 碩士
Master
系所名稱: 應用科技學院 - 應用科技研究所
Graduate Institute of Applied Science and Technology
論文出版年: 2013
畢業學年度: 101
語文別: 英文
論文頁數: 165
中文關鍵詞: 固態電解質介面膜(SEI)氟官能基順丁烯二酰亞胺鋰離子電池
外文關鍵詞: Fluorine functional group
相關次數: 點閱:185下載:7
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    Table of Contents Abstract 摘要 Acknowledgements Table of Contents List of Figures List of Tables Chapter 1 Introduction 1.1 Background 1.2 Lithium ion Battery components 1.3 The lithium-Ion battery reaction mechanism 1.4 The applications of Lithium ion battery batteries 1.5 Introduction of Solid Electrolyte Interfaces 1.5.1 The Reaction Mechanism of SEI 1.6 Problem Formulation 1.7 Research Purpose Chapter 2 SEI Formation and modification 2.1 SEI Modification on Anode Materials 2.1.1 Silicon Modified Nanowire Surface 2.1.2 Carbon Pretreatment on The SEI Formation 2.2 SEI Modification on Cathode Materials 2.2.1 Layered, Spinel surface modified 2.2.2 Surface Coating 2.3 The modification of SEI on Electrolyte 2.3.1 Lithium Salt 2.3.2 Solvent 2.3.3 Aging Mechanism 2.3.4 Electrolyte Additive Chapter 3 Research Methodology 3.1 Research Design 3.2 Materials 3.3 Equipments 3.4 Experimental procedure 3.4.1 Preliminary Experiment 3.4.2 Electrochemical Measurement Chapter 4 Synthesis of New Additives 4.1 Synthesis Part 4.1.1 Hydrogenetion Part 4.1.2 Dehydration Part 4.2 Characterization Chapter 5 Electrolyte Preparation and Electrochemical Analysis 5.1 Electrolyte Preparation 5.1.1 Blank electrolyte 5.1.2 O-MI additive- based electrolyte 5.1.3 F-MI additive- based electrolyte 5.1.4 2F-MI additive- based electrolyte 5.2 Electrochemical Analysis 5.2.1 Cyclic Voltammetry (CV) 5.2.2 Electrochemical Impedance Spectroscopy (EIS) analysis 5.2.3 Charge and discharge Chapter 6 SEI Evaluation 6.1 SEM and EDX Result 6.2 XPS and NMR Result 6.2.1 XPS analysis 6.2.2 NMR result Chapter 7 Conclusion Reference

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    [10] F.-M. Wang, H.-M. Cheng, H.-C. Wu, S.-Y. Chu, C.-S. Cheng, and C.-R. Yang, “Novel SEI formation of maleimide-based additives and its improvement of capability and cyclicability in lithium ion batteries,” Electrochimica Acta, vol. 54, no. 12, pp. 3344–3351, Apr. 2009.

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