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研究生： 翁啟達
Chi-Da Weng
論文名稱： 自組裝型固態高分子電解質合成及行為研究
Study on the Synthesis and Behavior of Self-assembling Solid Polymer Electrolyte
指導教授： 許應舉
Ying-Gev Hsu
口試委員: 黃茂全
none
王英靖
none
學位類別： 碩士
Master
系所名稱： 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年： 2005
畢業學年度： 93
語文別： 中文
論文頁數： 108
中文關鍵詞： 自組裝 、固態高分子電解質
外文關鍵詞： self assembly, solid polymer electrolytes
相關次數： 點閱：318  下載：0 
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    • 中文摘要
    本研究以4-羥基苯甲醛與11-溴-1-十一烯等起始物合成出具疏水基團之3,5-bis(11-methacryloylundecyl-1-oxybenzyloxy)benzoic acid（MBA），使之與poly(ethylene glycol)（PEG, Mw＝600）進行酯化反應，合成具自組裝基團之poly(ethylene glycol)- 3,5-bis(11-methacryloyl -undecyl-1-oxybenzyloxy)benzoate（PEG-BMBA），其中間產物之結構均經由FT-IR、NMR和Mass等儀器證實。PEG-BMBA可經由兩種不同的方式進行組裝，其一為在不同的溶劑極性下，其在親疏水性差異的驅動下進行自組裝；另一方式為PEG-BMBA於過氯酸鋰溶液中，經由配位鍵的驅動下進行自組裝，其組裝可分別由UV-Vis與FT-IR光譜證實，此外，組裝後的PEG-BMBA加熱硬化後能夠溶合（solvation）過氯酸鋰，證明此固態高分子電解質（Solid Polymer Electrolyte）確實具有離子傳導的功能。

    A poly(ethylene glycol) (PEG, Mw＝600) containing self-assembly compound poly(ethylene glycol)-3,5-bis(11- methacryloylundecyl -1- oxybenzyloxy)benzoate (PEG-BMBA) was synthesized by the reaction of 3,5-bis(11- methacryloylundecyl-1-oxybenzyloxy) benzoic acid (MBA) with PEG. The structures of PEG-MBA and the intermediates were identified by FTIR, NMR and Mass spectroscopy. PEG-BMBA was through supersonic vibration of the compound in CH2Cl2/MeOH solution of different polarity and was examined by UV-Vis or FT-IR spectroscopy. It was found that the assembly of the compound was formed chiefly through hydrophobic interaction and coordinative bonding. After assembling, the supramolecules was cured.The polymer could solvate lithium ion in it to increase the ability of ionic conductivity.

    目錄 中文摘要-I 英文摘要II 目錄---III 附圖索引-IV 附表索引-V 第一章前言--1 第二章文獻回顧--4 2-1高分子電解質之起源---4 2-2高分子電解質之發展---4 第三章基本原理--8 3-1反應機制----8 3-1.1 親核取代反應---8 3-1.2 還原反應10 3-1.3 醇與亞硫醯氯之反應---11 3-1.4 加成與皂化反應-12 3-1.5 醯化反應-15 3-1.6 酯化反應---18 3-2自組裝的原理---20 3-3高分子電解質傳導機制----23 第四章實驗部份---26 4-1實驗藥品--28 4-2實驗儀器與測試方法--30 4-3實驗方法-----32 4-3.1.14－（10－十一烯－1－氧）苯甲醛之合成-32 4-3.1.24－（10－十一烯－1－氧）苄醇之合成--34 4-3.1.3氯化－4－（10－十一烯－1－氧）苄基之合成--36 4-3.1.43, 5－雙【4－（10－十一烯－1－氧）苄氧】苯甲酸甲酯之合成---38 4-3.1.53, 5－雙【4－（11－羥十一－1－氧）苄氧】苯甲酸之合成--40 4-3.1.63, 5－雙【4－【11－（甲基丙烯酸根）十一－1－氧】苄氧】苯甲酸之合成--42 4-3.1.73, 5－雙【4－【11－（甲基丙烯酸根）十一－1－氧】苄氧】苯甲酸聚乙二酯之合成--43 4-3.2自組裝薄膜之製備-44 4-3.3固態高分子電解質之製備---45 第五章結果與討論----46 5-1 聚乙二醇衍生物之結構鑑定與分析----46 5-1.1 4－（10－十一烯－1－氧）苯甲醛之結構鑑定與分析 46 5-1.2 4－（10－十一烯－1－氧）苄醇之結構鑑定與分析 ---47 5-1.3 氯化－4－（10－十一烯－1－氧）苄基之結構鑑定與 分析-----48 5-1.4 3, 5－雙【4－（10－十一烯－1－氧）苄氧】苯甲酸甲酯之結構鑑定與分析----49 5-1.5 3, 5－雙【4－（11－羥十一－1－氧）苄氧】苯甲酸之結構鑑定與分析---50 5-1.6 3, 5－雙【4－【11－（甲基丙烯酸根）十一－1－氧】苄氧】苯甲酸之結構鑑定與分析----51 5-1.7 3, 5－雙【4－【11－（甲基丙烯酸根）十一－1－氧】苄氧】苯甲酸聚乙二酯之結構鑑定與分析-------52 5-2 自組裝行為及離子傳導之研究--76 第六章結論----86 第七章參考文獻--87

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