本研究分為兩部分，第一部份利用差示掃描量熱法(DSC)以非恆溫及恆溫模
式探討不同莫爾比的乙內醯脲/雙馬來醯亞胺(BMI/HD)反應特徵峰及動力學，以
對此反應相關的聚合動力學和機制有基本的了解，並利用自由模型法和最適化模
型法進行反應動力學分析並獲得動力學參數，包括反應速率常數（K）、活化能
（E）、頻率因子（A）、積分模型[g(α)]和微分模型[f(α)]描述聚合反應，並藉由
獲得的動力學參數重建實驗數據以知其可信度。添加 HQ 於各樣品中並搭配電子
順磁共振(EPR)可知系統有至少兩種反應機制，分別為自由基加成聚合反應、aza
Michael 和 Michael 加成反應。藉由熱重分析(TGA)可知添加劑中含有較多的 BMI，
其熱穩定性較高。
第二部分則將不同莫爾比的乙內醯脲/雙馬來醯亞胺(BMI/HD)作為正極添加
劑加入鋰離子電池中，透過循環伏安法(CV)、常/高溫充放電測試、電化學交流阻
抗(EIS)以分析其電化學性質，並探討添加劑層對 NCM523 系統的影響。首先，
由 SEM 影像可知含有添加劑的樣品經充放電測試後，其表面形貌與 Blank
NCM523 不同，即可知添加劑會於充放電過程中於電極表面形成物質；其次，分
析其電化學表現，發現 BMI/HD=2/1_0.5 %添加量的樣品於各項電化學性質方面
皆優於1 %添加量的樣品，因此電化學性質的優劣應與添加量及 BMI 和 HD 的
合成莫爾比有著密不可分之關係。

Non-isothermal and isothermal polymerization kinetics of different molar ratio of
BMI/HD are investigated by differential scanning calorimetry (DSC). The easiest way
to establish mathematical relationships between process rate, conversion and
temperature is determining kinetic triplet which are activation energy, preexponential factor, and models for reaction mechanism of each system by the model-free (isoconversional) and model-fitting method. The average activation energy of molar ratio 1/1 and 2/1 of BMI/HD are ca. 48.11 kJ/mol and 61.6 kJ/mol, respectively.
It is shown that mechanism of aza-Michael, Michael addition reaction and free radical
polymerization reaction appear in all systems by adding HQ into each system and
coordinating with electron paramagnetic resonance (EPR). Thermal stability of two
kinds of additives rise with increasing content of BMI which are measured by
thermogravimetric analysis.
To study the performance affected by adding different molar ratio of additives in
lithium-ion battery are investigated by cyclic voltammetry (CV), room/high (55℃)
temperature charge/discharge test and electrochemical impedance spectroscopy (EIS).
The additive of 2/1_0.5% is the optimal one possessing the phenomenon of
depolarization, reduced kinetic resistance and improved discharge capacity compared
to others, so speculate that all properties significantly are influenced by the isolation additive layer on cathode active materials and the level of additive. Furthermore, it can be verified that the formation of additive layer during charge/discharge through comparing the difference between the image of the surface morphology of the sample with additive and the blank sample by scanning electron microscope (SEM).

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