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研究生: 劉人豪
Ren-Hao Liu
論文名稱: 電滲透化學灌漿灌入氯化鈣對高嶺土負極改良範圍之研究
A Study of Cemented Zones for Injection of Calcium Chloride Solution during Electroosmotic Chemical Treatment of Kaolinite
指導教授: 歐章煜
Chang-Yu Ou
口試委員: 林宏達
none
簡紹琦
none
謝百鈎
none
學位類別: 碩士
Master
系所名稱: 工程學院 - 營建工程系
Department of Civil and Construction Engineering
論文出版年: 2011
畢業學年度: 99
語文別: 中文
論文頁數: 151
中文關鍵詞: 電滲透化學灌漿
外文關鍵詞: Electroosmotic, Chemical Treatment, Kaolinite
相關次數: 點閱:203下載:16
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電滲透化學灌漿工法於現地試驗的電極佈置方式,目前仍採用電滲透排水工法研究所建議的值進行試驗;對於電滲灌漿試驗的結果,膠結硬化僅發生在靠近電極管周圍的情況,若電極佈置失當,改良的範圍將遠不如預期。本研究以室內模型試體,對高嶺土灌入氯化鈣溶液進行電滲透化學灌漿試驗。試驗設計對於不同電極尺寸、不同輸入電壓及鄰近兩對電極,在電力相互影響下,對不同電極間距進行試驗。電滲試驗結束後量測土樣鈣離子含量、pH值及於負極膠結的改良範圍,來分析負極土壤於電場作用下的膠結改良範圍。最後以試驗的結果配合理論,提出現地適當電極間距佈置的預測方法。研究結果顯示:當負極附近土內pH值達到9以上的區域,均可產生膠結硬化反應。小電極鈑尺寸,在不受儀器邊界影響下,其膠結形狀會受電場強度分佈的影響,於電極鈑向外形成圓柱體。以4種不同電極鈑尺寸,在輸入電壓17.5V的情況下,其膠結範圍的延伸半徑均為40mm。隨著土內電場強度放大N倍,其膠結延伸半徑放大N^0.5倍,並經由此關係,可由一組試驗結果,對其他試驗條件的改良範圍作預測。


Nowadays the electrode arrangement of the electroosmotic chemical grouting in the field still adopts that suggested in the pure electroosmotic method because of deficiency in research. Therefore, the cemented zone of soil often occurs only near the electrode pipe. If the electrode arrangement is inappropriate, the cemented zone will be less than expected. The objective of this study is to investigate the cemented zone when calcium chloride solution is used as an injection material. A series of laboratory electroosmotic chemical treatment tests was carried out for different electrode sizes, input voltages and spacing of steel pipes. After the tests, cemented zones, pH values, cone resistances, water contents, and concentrations of Ca2+ in kaolinite at different locations were measured and discussed. Finally, the experimental results are analyzed with a suitable theory of electricity. Results show that the cemented zone normally occurs when pH values near the cathode is greater than 9. for small size of electric plates, which the boundary of the electroosmotic cell does not restrained from the development of cemented zones, the shape of cemented zones are highly related to the electric field and close to cylinder centering to the electric plate. The extensions of cemented zones for four different sizes of electro-plates are all equal to 40 mm. The extension of cemented zones is enlarged to N^0.5 times when the electric field increases by N times. A simple method is thus developed to estimate the possible range of cemented zone for different sizes of electrodes based on an electroosmotic experimental result.

中文摘要I AbstractII 誌 謝III 目錄IV 表目錄VIII 圖目錄IX 第一章緒論1 1.1研究動機與目的1 1.2研究方法2 1.3論文內容2 第二章文獻回顧4 2.1電力滲透及電滲化學灌漿發展歷史4 2.1.1電力滲透發展歷史5 2.1.2電滲透化學灌漿發展歷史6 2.1.3電力滲透現地試驗發展7 2.1.4國內研究發展8 2.2電力滲透機制11 2.2.1電雙層理論11 2.2.2電力滲透行為14 2.3電滲透化學反應15 2.4灌入漿液電滲膠結機制16 2.4.1氯化鈣溶液電滲膠結機制16 2.4.2水玻璃溶液電滲膠結機制18 2.5電極型式影響19 第三章試驗計劃、儀器設備及試驗方法35 3.1試驗計劃35 3.1.1試驗組35 3.1.2試驗土樣38 3.1.3電極材料38 3.1.4試驗灌入之化學漿液39 3.1.5灌漿時間39 3.1.6圓錐貫入及取樣規劃40 3.2試驗設備40 3.2.1主體設備40 3.2.2加壓設備42 3.2.3灌漿及集水設備42 3.2.4電力供應系統42 3.2.5即時監測計讀系統43 3.2.6室內圓錐貫入設備43 3.2.7感應耦合電漿原子發射光譜儀(ICP-AES)44 3.2.8電子式pH量測儀45 3.3試驗步驟45 3.3.1重模試體製作步驟45 3.3.2電滲透化學灌漿試驗步驟46 3.3.3室內圓錐灌入試驗步驟47 3.3.4取樣含水量試驗步驟48 3.3.5酸鹼值(pH)量測步驟48 3.3.6鈣離子量測試驗步驟49 第四章試驗結果與討論72 4.1試驗代號說明72 4.2單管電極尺寸改變試驗結果73 4.2.1膠結範圍74 4.2.2強度發展75 4.3單管電壓改變試驗結果77 4.3.1膠結範圍77 4.3.2強度發展79 4.4雙管試驗結果81 4.4.1膠結範圍81 4.4.2強度發展83 4.5綜合討論84 第五章結論與建議142 5.1結論142 5.2建議144 參考文獻146 附錄151

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