研究生: |
楊家麟 CHIA-LIN YANG |
---|---|
論文名稱: |
合成含奈米POSS之聚醯亞胺及其性質研究 Synthesis and Characterization of Polyimides Based on Polyhedral Oligomeric Silsesquioxane |
指導教授: |
陳燿騰
YAW-TERNG CHERN |
口試委員: |
陳原振
none 王健珍 none |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2005 |
畢業學年度: | 93 |
語文別: | 中文 |
論文頁數: | 150 |
中文關鍵詞: | 聚醯亞胺 、多面體矽氧烷 |
外文關鍵詞: | Polyimide, Polyhedral Oligomeric Silsesquioxane |
相關次數: | 點閱:182 下載:0 |
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中文摘要
本論文以具反應性多面體矽氧烷寡聚物(Polyhedral Oligomeric Sil-
sesquioxane,POSS) 與聚醯亞胺以兩種不同的製備方法(醯亞胺奈米寡
聚物掺混法、共聚合法)形成之多面體矽氧烷寡聚物/聚醯亞胺奈米複合材料,並研究POSS含量對其溶解度、熱性質與機械性質的影響。
首先,以POSS-4-aminobenzene之一胺單體與芳香族二酸酐(ODPA)經溶液縮合聚合成聚醯亞胺奈米寡聚物,並將其以不同比例與聚醯亞胺(Ref.)進行掺混,這些掺混物可經由溶液塗佈成具有韌性之薄膜。這些膜的抗張強度範圍於103~127 MPa之間,斷裂伸長率為19~145%。經由DMA 分析可測得知玻璃轉移溫度在242~255℃。此外,在氮氣和空氣下的10%重量損失分別是512~522℃與505~523℃之間。
以1,4-Bis(4-aminophenoxy)-2-(4-POSS-benzyloxy)benzene之含PO-
SS二胺單體、TH/NH2 二胺單體與芳香族二酸酐(ODPA)製備的聚醯亞胺奈米複合材料具有中到高的固有黏度,黏度範圍在0.32~1.2 dL/g,分子量1.4~7.4*104。此系列的聚醯亞胺具有好的溶解度,可溶於大部分的有機溶劑中,且皆可經由溶液塗佈成具有韌性之薄膜。這些膜的抗張強度範圍於37~93 MPa之間,斷裂伸長率為3~197%。經由DMA 分析可測得玻璃轉移溫度在245~258℃。此外,在氮氣和空氣下的10%重量損失分別是495~517℃與475~516℃之間。
Abstract
In this study, nanoporous polyhedral oligomeric silsesquioxane (POSS) molecules, were covalently tethered to the imide oligomer and copolyimide to form POSS/polyimide nanocomposites in two methods. The solubility properties, thermal properties and the dynamic mechanical properties of the POSS/polyimide nanocomposites were investigated by varying the weight ratio of POSS.
First, the imide nanooligomer, were prepared via the solution condensa-
tion of aromatic dianhydrides with POSS-4-aminobenzene, and added it by different ratio into polyimide, and gave flexible and tough films via solvent casting. The films had tensile strength of 103~127 MPa, and elongation to breakage values of 19~145%.The DMA analysis reveals that the glass transition temperatures ranged from 242 to 255℃. In addition, the temperat-
ures of 10% weight loss in nitrogen and the air ranged on 512~522℃ and 505~523℃, respectively.
Second, a series of polyimide nanocomposites were prepared by reaction of different ratio 1,4-Bis(4-aminophenoxy)-2-(4-POSS-benzyloxy)-
benzene, and 1,4-Bis(4-aminophenoxy)-2-tert-butylbenzene with aromatic tetracarboxylic dianhydride. The polymer were prepared with moderate to high inherent viscosities 0.32~1.2 dL/g, and molecular weight 1.4~7.4*104. The obtained copolyimides were readily soluble in common organic solvents and gave flexible and tough films via solvent casting. The films had tensile strength of 37 ~ 93 MPa , and elongation to breakage values of 3 ~ 197 % .
The DMA analysis reveals that the glass transition temperatures ranged from 245 to 258℃. In addition, the temperatures of 10% weight loss in nitrogen and the air ranged on 495~517℃ and 475~516℃, respectively.
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