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研究生: 曾祐強
Yu-chiang Tseng
論文名稱: 磷酸鋰鐵電池發展趨勢—學術論文之主路徑分析
A Study of The Technology Development trend of Lithium Iron Phosphate Batteries:Main Path of Academic Articles
指導教授: 劉顯仲
John S. Liu
口試委員: 何秀青
none
盧煜煬
none
學位類別: 碩士
Master
系所名稱: 管理學院 - 科技管理研究所
Graduate Institute of Technology Management
論文出版年: 2011
畢業學年度: 99
語文別: 中文
論文頁數: 91
中文關鍵詞: 磷酸鋰鐵成長曲線主路徑分析h-index發展趨勢
外文關鍵詞: LiFePO4, Li ion batteries, S curve, main path analysis, h-index
相關次數: 點閱:321下載:13
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  • 電動車兼具環保與節能省碳概念,獲得世界各國青睞並推廣。在眾多電池技術中,磷酸鋰鐵(LiFePO4)電池具備安全性高、放電穩定與價格相對便宜等優點,可望成為電動車電池主流技術。本研究欲透過學術論文找出磷酸鋰鐵的發展脈絡,協助欲進入該產業的企業或個人掌握研究動向、建立優勢。
    本研究使用Web of Science資料庫檢索磷酸鋰鐵領域的學術論文,並依據論文間的引證關係,透過主路徑分析計算論文間引證連結的強度,發掘對後續研究有很大貢獻的論文,將它們依引用關係繪製成主要發展路徑圖,用以說明研究領域中主要思想的演變歷程,藉此可瞭解時下熱門研究主題與未來可能動向。此外,本研究也使用h-index找出技術領域中最具引響力的學者與期刊,並由論文的成長曲線推測技術所處的成長階段。
    本研究發現,磷酸鋰鐵位於成長曲線的中後期,如何商品化為產業目前面臨的問題;透過主路徑分析瞭解磷酸鋰鐵的合成技術、鋰離子在兩相間的脫嵌與嵌入模式,以及改善磷酸鋰鐵材料克電容量表現的方法等為近十年來主要的研究課題。未來將朝向高性能的磷酸鋰鐵電池發展,維持高電容量、同時提升能量密度,因此合成技術的改善、導電碳結構的設計、磷酸鋰鐵的粒徑大小與形態,為不可或缺的熱門研究題材。本研究亦顯示主路徑分析可有效率找出對目標研究領域有重要影響力的學術論文,透過視覺化的呈現有助於使用者瞭解技術發展全貌。


    In order to reduce CO2 emission and avoid the greenhouse effect, a lot of countries, including U.S., Japan, China, have already carried out development policy to promote green vehicles. For the upcoming era of electric vehicles, this paper would focus on the research trend of LiFePO4, a type of battery technology for EVs, and use visual tool to show the flow of knowledge mainstreams. Through this study, one can obtain basic domain knowledge of LiFePO4 battery, and capture the main development trajectory in the short times.
    Citation network in academic articles have been developed. This paper use main path analysis and h-index to find out the influential articles and authors in the field of LiFePO4. We found three active knowledge mainstreams in recent ten years. They are synthesis of LiFePO4 particles, Lithium extraction/insertion process in LiFePO4, and Improvement of LiFePO4 electrochemical performance, such as enhancing electronic conductivity or Li ion diffusion to reach high electric capacity.
    Through growth curve analysis with academic articles, we found LiFePO4 is on the growing stage, and it’s time to commercialize. In the future, development of high performance battery is expected. Use innovative design of carbon conductive network via proper synthesis process to invent LiFePO4 battery, which with both high electric capacity and high energy density, would be the research trend in academic field. In this paper we show that main path analysis is a proper methodology for finding influence articles and authors in the field of technology research.

    目錄 第壹章 緒論…………………………………………………………………………………1 一、研究背景與動機……………………………………………………………1 二、研究目的…………………………………………………………………………4 第貳章 文獻探討…………………………………………………………………………5 一、知識領域視覺化……………………………………………………………5 二、引文分析…………………………………………………………………………6 三、主路徑分析……………………………………………………………………7 四、g-index與h-index…………………………………………………14 五、成長曲線…………………………………………………………………………14 六、磷酸鋰鐵電池…………………………………………………………………18 (一)鋰離子脫嵌/嵌入機制………………………………………19 (二)提升磷酸鋰鐵的導電性………………………………………20 1.化學取代…………………………………………………………………21 2. 金屬摻雜………………………………………………………………21 3. 塗佈導電材料………………………………………………………21 (三)磷酸鋰鐵的合成方法…………………………………………23 1. 固相法(Solid-State reacion)…………23 2. 溶膠-凝膠法(Sol-Gel)………………………………23 3. 共沉澱法(Coprecipitated)…………………24 4. 水熱法(Hydrothermal synthesis)…24 5. 噴霧裂解法(Spray-pyrolysis)…………24 第参章 研究方法………………………………………………….26 一、研究架構…………………………………………………….26 (一)資料來源……………………………………………….27 (二)資料蒐集與關鍵字檢索……………………………….27 (三)期刊與作者基本統計………………………………….31 (四)成長曲線分析與Loglet Lab…………………………31 (五)主路徑分析與Pajek…………………………………31 第肆章 研究結果………………………………………………….33 一、期刊與作者基本統計……………………………………….33 (一)期刊統計……………………………………………….33 (二)作者統計……………………………………………….33 二、磷酸鋰鐵學術論文成長曲線分析………………………….38 三、磷酸鋰鐵學術論文主路徑分析……………………………39 (一)傳統主路徑…………………………………………….40 (二)整體觀點的主路徑…………………………………….48 (三)發展結構觀點的主路徑………………………………56 (四) 磷酸鋰鐵近年發展…………………………………...59 第伍章 研究結論………………………………………………….66 一、磷酸鋰鐵學術研究論文發展趨勢軌跡總結………………66 二、研究發現…………………………………………………………68 三、研究貢獻……………………………………………………….69 參考文獻………………………...………………………………………………………71

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