簡易檢索 / 詳目顯示

研究生: 陳義軒
Yi-Hsuan Chen
論文名稱: 製程參數及封孔處理對6061鋁合金微弧氧化磨潤性能之影響
Effect of Process Parameters and Sealing Treatment on 6061 Aluminum Alloy Micro-arc Oxidation of Tribological Performance
指導教授: 林原慶
Yuan-Ching Lin
口試委員: 向四海
Su-Hai Hsiang
周振嘉
Chen-Chia Chou
呂道揆
Daw-Kwei Leu
林原慶
Yuan-Ching Lin
學位類別: 碩士
Master
系所名稱: 工程學院 - 機械工程系
Department of Mechanical Engineering
論文出版年: 2019
畢業學年度: 107
語文別: 中文
論文頁數: 124
中文關鍵詞: 6061鋁合金表面處理微弧氧化磨潤性能封孔處理潤滑材料
外文關鍵詞: 6061 aluminum alloy, Surface treatment, Micro-arc Oxidation, Tribological performance, Sealing treatment, lubricant material
相關次數: 點閱:184下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報

在鋁酸鈉電解液中藉由微弧氧化在6061鋁合金表面上形成具有高硬度的陶瓷氧化層,以改善6061鋁合金的耐磨性。但多孔隙且非常粗糙的陶瓷層表面,並不利於實際應用。本研究改變不同的電流密度來評估微弧氧化層的冶金性質、機械性質及磨潤性能,以求得最佳的電流密度。並在磨耗試驗中使用不同潤滑劑與封孔處理,用以降低對磨件之損傷,藉由不同材料及形式的對磨件進行磨耗試驗,分析不同製程參數對微弧氧化層磨潤性能的影響。
試驗結果顯示,電流密度15A/dm2條件下形成的微弧氧化陶瓷層硬度最高、耐磨耗性能最好,並以此電流密度,製作封孔處理試驗用試片。而封孔處理試片的磨耗結果顯示,三種封孔試片的膜層磨痕深度及對磨件磨耗量皆有下降,其中混合封孔比石蠟封孔與二硫化鎢封孔之效果更佳,明顯的降低微弧氧化層的磨痕深度和對磨件磨耗量,其摩擦係數甚至可降至約0.2。在線接觸狀態下(較低最大接觸應力),無論採用軸承鋼柱或氧化鋯柱對磨件,混合封孔試片皆表現出最佳的磨潤性能。在點接觸狀態下(較高最大接觸應力),採用軸承鋼球對磨件時,混合封孔試片表現出最佳的磨潤性能;然而採用氧化鋯球對磨件時,則是石蠟封孔試片表現出最佳的磨潤性能,這與對磨件之材料性質有關。


A ceramic coating with high hardness was made on 6061 aluminum alloy by micro-arc oxidation(MAO) in aluminate electrolyte, which improved the wear resistance of aluminum alloy. However, the surface of coating was porous and rough, which was disadvantageous for practical applications. In this work, different current densities were used to study the formation mechanism of the MAO and obtain the best ceramic coating. Different lubricants and sealing process were used in wear test to reduce the damage of the counterparts. The wear tests were carried out by using different materials and shapes of counterparts to analyze the influence of different parameters on the tribological performance of the ceramic layer.
The results showed that the MAO coating formed at 15A/dm2 shows the highest hardness and the best tribological performance, and use this current density to produce the specimen for sealing treatment. The wear test showed that the wear volume and depth of the three sealing specimens are reduced, and the mixed sealing is the best, which greatly reduces the wear volume, depth and friction coefficient that can be reduced to about 0.2. In line contact, mixed sealing coating showed excellent tribological performance by using 52100 alloy steel or zirconia counterparts. However, in point contact, the effect of the lubricant-sealing coating is gradually decreased due to high contact stress.

摘要 I Abstract II 誌謝 III 目錄 IV 表目錄 VI 圖目錄 VII 第一章 前言 1 1-1 研究動機 1 1-2 研究目的 2 第二章 文獻回顧 3 2-1 鋁合金簡介 3 2-2 表面改質處理技術 3 2-3 微弧氧化簡介 3 2-4 微弧氧化發展歷史 4 2-5 微弧氧化機理 5 2-6 微弧氧化製程的研究範疇[14] 9 2-7 微弧氧化製程參數之研究 12 2-8 磨潤理論 14 2-9表面接觸型態 19 第三章 實驗方法與步驟 22 3-1 試片規格 22 3-2 微弧氧化設備 23 3-3 磨耗試驗設備 24 3-4 分析儀器 27 3-5 實驗步驟 35 3-5-1 微弧氧化步驟及參數 35 3-5-2 封孔處理 36 3-5-3 磨耗試驗 37 第四章 結果與討論 40 4-1製程參數對微弧氧化層表面特徵與冶金性質的影響 40 4-1-1 定電壓製程時間對微弧氧化層表面特徵及厚度的影響 40 4-1-2 不同定電流密度與製程時間對微弧氧化層表面特徵及厚度的影響 43 4-1-3 不同定電流密度對微弧氧化層微結構的影響 48 4-1-4不同定電流密度對微弧氧化層孔隙率的影響 50 4-2 製程參數對微弧氧化層機械性質的影響 54 4-2-1 不同定電流密度對微弧氧化層微觀性質的影響 54 4-2-2 不同定電流密度對微弧氧化層硬度分布的影響 56 4-3 不同製程參數微弧氧化層之磨潤性能評估 58 4-3-1 定電壓微弧氧化層之磨潤性能評估 58 4-3-2 不同定電流密度微弧氧化層之磨潤性能評估 59 4-4 封孔處理之微弧氧化層的磨潤性能評估 68 4-4-1 封孔處理對微弧氧化層表面特徵的影響 68 4-4-2 軸承鋼作為對磨件之微弧氧化層封孔處理的磨潤性能評估 70 4-4-3 氧化鋯作為對磨件之微弧氧化層封孔處理的磨潤性能評估 86 4-5 微弧氧化層之磨潤性能綜合評估 102 第五章 結論 104 參考文獻 106

[1] 徐栢榮, "利用雙極脈衝電源微弧氧化法探討占空比和頻率對7075-T6鋁合金表面氧化膜層之影響," 碩士, 材料工程學系(所), 大同大學, 台北市, 2009.
[2] G. Sabatini, L. Ceschini, C. Martini, J. Williams, and I. Hutchings, "Improving sliding and abrasive wear behaviour of cast A356 and wrought AA7075 aluminium alloys by plasma electrolytic oxidation," Materials & Design, vol. 31, no. 2, pp. 816-828, 2010.
[3] M. Khorasanian, A. Dehghan, M. Shariat, M. Bahrololoom, and S. Javadpour, "Microstructure and wear resistance of oxide coatings on Ti–6Al–4V produced by plasma electrolytic oxidation in an inexpensive electrolyte," Surface and coatings Technology, vol. 206, no. 6, pp. 1495-1502, 2011.
[4] C. Ma, M. Zhang, Y. Yuan, X. Jing, and X. Bai, "Tribological behavior of plasma electrolytic oxidation coatings on the surface of Mg–8Li–1Al alloy," Tribology International, vol. 47, pp. 62-68, 2012.
[5] M. Treviño, N. Garza-Montes-de-Oca, A. Pérez, M. Hernández-Rodríguez, A. Juárez, and R. Colás, "Wear of an aluminium alloy coated by plasma electrolytic oxidation," Surface and Coatings Technology, vol. 206, no. 8-9, pp. 2213-2219, 2012.
[6] Yingliang Cheng, Jinhui Cao, Zhaomei Peng, Qun Wang, E. Matykina, P. Skeldon,G.E. Thompson, "Wear-resistant coatings formed on Zircaloy-2 by plasma electrolytic oxidation in sodium aluminate electrolytes," Electrochimica Acta, vol. 116, pp. 453-466, 2014.
[7] Q. Li, J. Liang, B. Liu, Z. Peng, and Q. Wang, "Effects of cathodic voltages on structure and wear resistance of plasma electrolytic oxidation coatings formed on aluminium alloy," Applied Surface Science, vol. 297, pp. 176-181, 2014.
[8] 陳麒元, "利用微弧氧化法在6061鋁合金上鍍製ZrO2/Al2O3氧化膜之研究," 碩士, 機械工程系, 國立臺灣科技大學, 台北市, 2014.
[9] A. Yerokhin, X. Nie, A. Leyland, A. Matthews, and S. Dowey, "Plasma electrolysis for surface engineering," Surface and coatings technology, vol. 122, no. 2-3, pp. 73-93, 1999.
[10] P. Kurze, W. Krysmann, J. Schreckenbach, T. Schwarz, and K. Rabending, "Coloured ANOF layers on aluminium," Crystal Research and Technology, vol. 22, no. 1, pp. 53-58, 1987.
[11] A. Rakoch and I. Bardin, "Microarc oxidation of light alloys," Metallurgist, vol. 54, no. 5, pp. 378-383, 2010.
[12] 莊祐懿, "探討純鈦在不同電解液微弧氧化對生成氧化膜層的影響," 碩士, 材料及資源工程系研究所, 國立臺北科技大學, 台北市, 2014.
[13] T. W. Clyne and S. C. Troughton, "A review of recent work on discharge characteristics during plasma electrolytic oxidation of various metals," International Materials Reviews, vol. 64, no. 3, pp. 127-162, 2019.
[14] C. Xuejun and P. Jing, "Research Progress of Microarc Oxidation for Corrosion Prevention of Mg-alloys," Journal of Chinese Society for Corrosion and protection, vol. 38, no. 2, pp. 87-104, 2018.
[15] T. Mi, B. Jiang, Z. Liu, and L. Fan, "Plasma formation mechanism of microarc oxidation," Electrochimica Acta, vol. 123, pp. 369-377, 2014.
[16] A. Rakoch, V. Khokhlov, V. Bautin, N. Lebedeva, Y. V. Magurova, and I. Bardin, "Model concepts on the mechanism of microarc oxidation of metal materials and the control over this process," Protection of metals, vol. 42, no. 2, pp. 158-169, 2006.
[17] K. Tillous, T. Toll-Duchanoy, E. Bauer-Grosse, L. Hericher, and G. Geandier, "Microstructure and phase composition of microarc oxidation surface layers formed on aluminium and its alloys 2214-T6 and 7050-T74," Surface and Coatings Technology, vol. 203, no. 19, pp. 2969-2973, 2009.
[18] L. Zhu, Z. Guo, Y. Zhang, Z. Li, and M. Sui, "A mechanism for the growth of a plasma electrolytic oxide coating on Al," Electrochimica Acta, vol. 208, pp. 296-303, 2016.
[19] H. Yu, Q. Dong, Y. Chen, and C. Chen, "Influence of silicon on growth mechanism of micro-arc oxidation coating on cast Al–Si alloy," Royal Society open science, vol. 5, no. 7, p. 172428, 2018.
[20] A. Hakimizad, K. Raeissi, M. A. Golozar, X. Lu, C. Blawert, and M. L. Zheludkevich, "The effect of pulse waveforms on surface morphology, composition and corrosion behavior of Al2O3 and Al2O3/TiO2 nano-composite PEO coatings on 7075 aluminum alloy," Surface and Coatings Technology, vol. 324, pp. 208-221, 2017.
[21] F. Jin, P. K. Chu, G. Xu, J. Zhao, D. Tang, and H. Tong, "Structure and mechanical properties of magnesium alloy treated by micro-arc discharge oxidation using direct current and high-frequency bipolar pulsing modes," Materials Science and Engineering: A, vol. 435, pp. 123-126, 2006.
[22] Q.-P. Tran, Y.-C. Kuo, J.-K. Sun, J.-L. He, and T.-S. Chin, "High quality oxide-layers on Al-alloy by micro-arc oxidation using hybrid voltages," Surface and Coatings Technology, vol. 303, pp. 61-67, 2016.
[23] S. Wang, Y. Xia, L. Liu, and N. Si, "Preparation and performance of MAO coatings obtained on AZ91D Mg alloy under unipolar and bipolar modes in a novel dual electrolyte," Ceramics International, vol. 40, no. 1, pp. 93-99, 2014.
[24] S. Xin, L. Song, R. Zhao, and X. Hu, "Influence of cathodic current on composition, structure and properties of Al2O3 coatings on aluminum alloy prepared by micro-arc oxidation process," Thin Solid Films, vol. 515, no. 1, pp. 326-332, 2006.
[25] J.-H. Wang, M.-H. Du, F.-Z. Han, and J. Yang, "Effects of the ratio of anodic and cathodic currents on the characteristics of micro-arc oxidation ceramic coatings on Al alloys," Applied Surface Science, vol. 292, pp. 658-664, 2014.
[26] Z. Yao, D. Wang, Q. Xia, Y. Zhang, Z. Jiang, and F. Wang, "Effect of PEO power modes on structure and corrosion resistance of ceramic coatings on AZ91D Mg alloy," Surface Engineering, vol. 28, no. 2, pp. 96-101, 2012.
[27] V. Dehnavi, B. L. Luan, D. W. Shoesmith, X. Y. Liu, and S. Rohani, "Effect of duty cycle and applied current frequency on plasma electrolytic oxidation (PEO) coating growth behavior," Surface and Coatings Technology, vol. 226, pp. 100-107, 2013.
[28] N. Xiang, R.-g. Song, J.-j. Zhuang, R.-x. Song, X.-y. Lu, and X.-p. Su, "Effects of current density on microstructure and properties of plasma electrolytic oxidation ceramic coatings formed on 6063 aluminum alloy," Transactions of Nonferrous Metals Society of China, vol. 26, no. 3, pp. 806-813, 2016.
[29] J. Martin, A. Melhem, I. Shchedrina, T. Duchanoy, A. Nominé, G. Henrion,T. Czerwiec, T. Belmonte, "Effects of electrical parameters on plasma electrolytic oxidation of aluminium," Surface and Coatings Technology, vol. 221, pp. 70-76, 2013.
[30] J. Zhang, Y. Fan, X. Zhao, R. Ma, A. Du, and X. Cao, "Influence of duty cycle on the growth behavior and wear resistance of micro-arc oxidation coatings on hot dip aluminized cast iron," Surface and Coatings Technology, vol. 337, pp. 141-149, 2018.
[31] V. Dehnavi, X. Y. Liu, B. L. Luan, D. W. Shoesmith, and S. Rohani, "Phase transformation in plasma electrolytic oxidation coatings on 6061 aluminum alloy," Surface and Coatings Technology, vol. 251, pp. 106-114, 2014.
[32] F. Simchen, M. Sieber, and T. Lampke, "Electrolyte influence on ignition of plasma electrolytic oxidation processes on light metals," Surface and Coatings Technology, vol. 315, pp. 205-213, 2017.
[33] Venkateswarlu K, Rameshbabu N, Sreekanth D, Sandhyarani M, Bose AC,Muthupandi V, Subramanian S, "Role of electrolyte chemistry on electronic and in vitro electrochemical properties of micro-arc oxidized titania films on Cp Ti," Electrochimica Acta, vol. 105, pp. 468-480, 2013.
[34] S. Fatimah, M. Kamil, J. Kwon, M. Kaseem, and Y. Ko, "Dual incorporation of SiO2 and ZrO2 nanoparticles into the oxide layer on 6061 Al alloy via plasma electrolytic oxidation: Coating structure and corrosion properties," Journal of Alloys and Compounds, vol. 707, pp. 358-364, 2017.
[35] K.-J. Ma, M. M. Al Bosta, and W.-T. Wu, "Preparation of self-lubricating composite coatings through a micro-arc plasma oxidation with graphite in electrolyte solution," Surface and Coatings Technology, vol. 259, pp. 318-324, 2014.
[36] E. Matykina, R. Arrabal, P. Skeldon, and G. Thompson, "Incorporation of zirconia nanoparticles into coatings formed on aluminium by AC plasma electrolytic oxidation," Journal of Applied Electrochemistry, vol. 38, no. 10, pp. 1375-1383, 2008.
[37] Quang-Phu Tran, Tsung-Shune Chin, Yu-Cheng Kuo, Chong-Xun Jin, Tran Trung,Chu Van Tuan, Dong Quang Dang, "Diamond powder incorporated oxide layers formed on 6061 Al alloy by plasma electrolytic oxidation," Journal of Alloys and Compounds, vol. 751, pp. 289-298, 2018.
[38] X. Wu, W. Qin, Y. Guo, and Z. Xie, "Self-lubricative coating grown by micro-plasma oxidation on aluminum alloys in the solution of aluminate–graphite," Applied Surface Science, vol. 254, no. 20, pp. 6395-6399, 2008.
[39] K. Rokosz and T. Hryniewicz, "Comparative SEM and EDX analysis of surface coatings created on niobium and titanium alloys after Plasma Electrolytic Oxidation (PEO)," Teh. Vjesn. Tech. Gaz, vol. 24, pp. 465-472, 2017.
[40] F. Wei, W. Zhang, T. Zhang, and F. Wang, "Effect of variations of Al content on microstructure and corrosion resistance of PEO coatings on MgAl alloys," Journal of Alloys and Compounds, vol. 690, pp. 195-205, 2017.
[41] Y.-J. Oh, J.-I. Mun, and J.-H. Kim, "Effects of alloying elements on microstructure and protective properties of Al2O3 coatings formed on aluminum alloy substrates by plasma electrolysis," Surface and Coatings Technology, vol. 204, no. 1-2, pp. 141-148, 2009.
[42] A. Rafieerad, M. Ashra, R. Mahmoodian, and A. Bushroa, "Surface characterization and corrosion behavior of calcium phosphate-base composite layer on titanium and its alloys via plasma electrolytic oxidation: A review paper," Materials Science and Engineering: C, vol. 57, pp. 397-413, 2015.
[43] A. Alabbasi, A. Mehjabeen, M. B. Kannan, Q. Ye, and C. Blawert, "Biodegradable polymer for sealing porous PEO layer on pure magnesium: An in vitro degradation study," Applied Surface Science, vol. 301, pp. 463-467, 2014.
[44] X.-j. Cui, X.-z. Lin, C.-h. Liu, R.-s. Yang, X.-w. Zheng, and M. Gong, "Fabrication and corrosion resistance of a hydrophobic micro-arc oxidation coating on AZ31 Mg alloy," Corrosion Science, vol. 90, pp. 402-412, 2015.
[45] D. Jiang, H. Zhou, S. Wan, G.-Y. Cai, and Z.-H. Dong, "Fabrication of superhydrophobic coating on magnesium alloy with improved corrosion resistance by combining micro-arc oxidation and cyclic assembly," Surface and Coatings Technology, vol. 339, pp. 155-166, 2018.
[46] M. Laleh, F. Kargar, and A. S. Rouhaghdam, "Investigation of rare earth sealing of porous micro-arc oxidation coating formed on AZ91D magnesium alloy," Journal of rare earths, vol. 30, no. 12, pp. 1293-1297, 2012.
[47] M. Mohedano, C. Blawert, and M. Zheludkevich, "Cerium-based sealing of PEO coated AM50 magnesium alloy," Surface and Coatings Technology, vol. 269, pp. 145-154, 2015.
[48] N. Van Phuong, B. R. Fazal, and S. Moon, "Cerium-and phosphate-based sealing treatments of PEO coated AZ31 Mg alloy," Surface and Coatings Technology, vol. 309, pp. 86-95, 2017.
[49] C. Zhang, F. Zhang, L. Song, R. Zeng, S. Li, and E. Han, "Corrosion resistance of a superhydrophobic surface on micro-arc oxidation coated Mg-Li-Ca alloy," Journal of Alloys and Compounds, vol. 728, pp. 815-826, 2017.
[50] Hanhua Wu, Jianbo Wang, Beiyu Long, Beihong Long, Zengsun Jin, Wang Naidan, Fengrong Yu, Dongmei Bi, "Ultra-hard ceramic coatings fabricated through microarc oxidation on aluminium alloy," Applied surface science, vol. 252, no. 5, pp. 1545-1552, 2005.
[51] Guohua Lv, Weichao Gu, Huan Chen, Wenran Feng, M. Latif Khosa, Li Li, Erwu Niu, Guling Zhang, Si-Ze Yang, "Characteristic of ceramic coatings on aluminum by plasma electrolytic oxidation in silicate and phosphate electrolyte," Applied Surface Science, vol. 253, no. 5, pp. 2947-2952, 2006.
[52] W. Kai, K. Bon-Heun, L. Chan-Gyu, K. Young-Joo, L. Sung-Hun, and B. Eungsun, "Effects of electrolytes variation on formation of oxide layers of 6061 Al alloys by plasma electrolytic oxidation," Transactions of Nonferrous Metals Society of China, vol. 19, no. 4, pp. 866-870, 2009.
[53] B. Jiang and Y. Wang, "Plasma electrolytic oxidation treatment of aluminium and titanium alloys," Surface engineering of light alloys, pp. 110-154, 2010.
[54] Wear; Terms, Systematic Analysis Of Wear Processes Classification Of Wear Phenomena, 1979.
[55] K.-H. Zum Gahr, Microstructure and wear of materials. Elsevier, 1987.
[56] E. Rabinowicz, "An adhesive wear model based on variations in strength values," Wear, vol. 63, no. 1, pp. 175-181, 1980.
[57] G. Stachowiak and A. W. Batchelor, Engineering tribology. Butterworth-Heinemann, 2013.
[58] H. Czichos, Tribology: a systems approach to the science and technology of friction, lubrication, and wear. Elsevier, 2009.
[59] N. P. Suh, "The delamination theory of wear," Wear, vol. 25, no. 1, pp. 111-124, 1973.
[60] 宏盛鋼珠軸承有限公司. Available: http://ths-brg.com/index.html
[61] 騰騏國際股份有限公司. Available: http://www.tensky.com.tw/
[62] 許淳景, "新一代生質柴油的磨潤性能評估," 碩士, 機械工程系, 國立臺灣科技大學, 台北市, 2017.
[63] W. C. Oliver and G. M. Pharr, "An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments," Journal of materials research, vol. 7, no. 6, pp. 1564-1583, 1992.
[64] A. C. Fischer-Cripps, Nanoindentation. Springer Science & Business Media, 2011.
[65] J. Boér and P. Blaga, "Reducing production costs by monitoring the roughness of raw product surfaces," Procedia Manufacturing, vol. 22, pp. 202-208, 2018.
[66] G. Mikoleizig, "Surface roughness measurements of cylindrical gears and bevel gears on gear inspection machines," Gear Technology, pp. 48-55, 2015.
[67] H. Thoma, L. Peri, and E. Lato, "Evaluation of wood surface roughness depending on species characteristics," Maderas. Ciencia y tecnología, vol. 17, no. 2, pp. 285-292, 2015.

無法下載圖示 全文公開日期 2021/07/31 (校內網路)
全文公開日期 2024/07/31 (校外網路)
全文公開日期 2024/07/31 (國家圖書館:臺灣博碩士論文系統)
QR CODE