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| 研究生： |
黃新堯 Hsin-Yao Huang |
|---|---|
| 論文名稱： |
奈米級核殼型橡膠添加劑、無機二氧化矽/有機高分子核殼型顆粒、及蒙特納石黏土對不飽和聚酯、乙烯基酯、及環氧樹脂之聚合固化反應動力、玻璃轉移溫度、体積收縮、機械性質及微觀型態結構之影響研究 Effects of nano-scale core-shell rubber additives, inorganic silica /organic polymer core-shell particle, and montmorillonite clay on the cure kinetics, glass transition temperatures, volume shrinkage, mechanical properties and cured sample morphology for unsaturated polyester, vinyl ester, and epoxy resins |
| 指導教授： |
黃延吉
Yan-Jyi Huang |
| 口試委員: |
陳崇賢
Chorng-Shyan Chern 邱文英 Wen-Yen Chiu |
| 學位類別： |
碩士 Master |
| 系所名稱： |
工程學院 - 化學工程系 Department of Chemical Engineering |
| 論文出版年： | 2012 |
| 畢業學年度： | 100 |
| 語文別： | 中文 |
| 論文頁數： | 327 |
| 中文關鍵詞： | 核殼形橡膠 、蒙特納石黏土 、不飽和聚酯 、乙烯基酯樹脂 、固化動力 、玻璃轉移溫度 、體積收縮 、機械性質 |
| 外文關鍵詞： | Core-Shell Rubber(CSR), Montmorillonite (MMT), unsaturated polyester(UP), vinyl ester resin (VER), curing kinetics, glass transition, volume shrinkage, microstructure, mechanical properties, radius of gyration |
| 相關次數： | 點閱：179 下載：2 |
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本文目的主要為探討三種特用添加劑，分別為：(1)奈米級核殼型橡膠(core-shell rubber) (2)無機矽膠/有機高分子核殼型顆粒及(3)有機化改質蒙特納石黏土(Montmorillonite clay，MMT)，其對苯乙烯/不飽和聚酯(或乙烯基酯)/特用添加劑三成份系統及環氧樹脂/硬化劑/特用添加劑三成份系統之反應前相容性，聚合固化反應動力，玻璃轉移溫度、微觀型態結構、抗體積收縮特性及機械性質等之影響研究。
本研究也利用小角度X-ray散射儀(SAXS)測量不飽和聚酯(UP)及乙烯基酯(VER)之稀薄苯乙烯(St)溶液之散射強度，再根據Guinier Law計算不同UP及乙烯基酯(VER)之環動半徑(Radius of Gyration)，可用於St/UP(或VER)/MMT三成份系統，瞭解UP(或VER)分子擴散至蒙特納石黏土(MMT)層間之難易程度。
吾人也利用微分掃描熱分析儀(DSC)及傅立葉轉換紅外光譜儀(FTIR)測量ST/UP(or VER)/additive 三成份系在聚合固化中之反應動力。最後依據Takayanagi機械模式，ST/UP(or VER)/additive三成份系聚合固化後的樣品，其在各相區之玻璃轉移溫度，吾人亦以動態機械測定儀(DMA)測量之
The effects of four additives, including (1) nano- scale core-shell rubber additive,(2) inorganic silica gel/organic polymer core-shell particle, (3) organic montmorillonite clay, on the cure kinetics, glass transition temperatures, cured sample morphology, volume shrinkage characteristics and mechanical properties of the Styrene(St)/ Unsaturated polyester (or Vinyl ester resin)/ additives ternary systems and Epoxy/curing agent /additive ternary systems after the cure have been investigated.
The experimental results have been explained by integrated measurements combining phase characteristic of the St/VER/additive ternary system and Epoxy/curing agent /additive ternary systems before the cure, final cure conversion, glass transition temperature, SAXS and WAXS analysis, cured sample morphology and Mechanical properties.
Also the scattering intensity of vinyl ester resin (VER) and unsaturated polyester (UP) with different structure in dilute styrene solution was measured by the method of small angle X-ray scattering (SAXS), and the radius of gyration of VER and the UP molecule can then be calculated by using the Guinier law.
The reaction kinetics for the ST/UP(or VER)/additive ternary system during the cure was measured by differential scanning calorimetry(DSC) and Fourier transform infrared spectrometry (FTIR). Finally, based on the Takayanagi mechanical models, the glass transition temperature in each region of the cured samples for ST/UP(or VER)/additive ternary system has been measured by dynamic mechanical analysis (DMA).
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