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研究生: 王光明
Kuang-Ming Wang
論文名稱: 丙烯腈基共聚高分子與二氧化鈦/丁二腈之固態複合電解質在固態鋰離子電池之應用
Application of composite solid electrolyte of acrylonitrile-based copolymer and titanium dioxide/succinonitrile in solid-state lithium-ion batteries
指導教授: 陳崇賢
Chorng-Shyan Chern
口試委員: 許榮木
Jung-Mu Shu
范國泰
Quoc-Thai Pham
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 89
中文關鍵詞: 固態複合高分子電解質丁二腈二氧化鈦丙烯腈共聚合體增塑劑
外文關鍵詞: Solid Composite Polymer Electrolyte, Succinonitrile, Titanium Dioxide, Acrylonitrile Copolymer, Plasticizer
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  • 摘要 I Abstract II 致謝 III 目錄 V 圖目錄 VIII 表目錄 XI 第1章 緒論 1 1.1 前言 1 1.2 研究動機與研究方向 5 1.2.1 電池原理 5 1.2.2 聚合物固態電解質 6 第2章 文獻回顧 7 2.1 正極材料 7 2.2 固態電解質的設計 10 2.2.1 有機固態電解質 10 2.2.2 混摻改性 12 2.2.3 共聚交聯 13 2.2.4 增塑劑 15 2.2.5 複合固態電解質 16 2.3 高分子合成機制 19 第3章 實驗方法與步驟 20 3.1 實驗藥品 20 3.2 實驗儀器與器材 21 3.3 高分子合成及固態電解液製備 22 3.3.1 PG5合成 22 3.3.2 固態電解液製備 22 3.4 固態電解質材料製備 23 3.4.1 膠體滲透層析儀(GPC)原理及製備 23 3.4.2 差示掃描量熱分析(DSC)原理及製備 23 3.4.3 熱重分析儀(TGA)原理及製備 23 3.4.4 機械性質測試樣品製備 24 3.4.5 傅立葉轉換紅外光譜分析(FT-IR)原理及樣品製備 24 3.4.6 本質黏度樣品製備 24 3.5 固態電解質電化學量測製備 25 3.5.1 正極製備 25 3.5.2 離子電導率樣品製備 26 3.5.3 線性掃描伏安(LSV)樣品製備 27 3.5.4 鋰離子遷移常數及介面穩定性樣品製備 28 3.5.5 固態電池製備 29 3.6 實驗流程圖 30 3.6.1 高分子合成 30 3.6.2 正極漿料製備 30 3.6.3 正極製備 30 第4章 實驗結果與討論 31 4.1 固態電解質材料分析 31 4.1.1 凝膠滲透層析分析 31 4.1.2 差示掃描量熱分析 33 4.1.3 熱重分析 35 4.1.4 機械性性質測試 36 4.1.5 傅立葉轉換紅外光譜分析 38 4.1.6 本質黏度分析 40 4.2 固態電解質電化學特性分析 42 4.2.1 鋰離子電導率 42 4.2.2 線性掃描伏安法 47 4.2.3 鋰離子遷移常數 48 4.2.4 鋰金屬固態電解質之界面穩定性 50 4.2.5 充放電循環性能之電池測試 52 4.2.6 交流阻抗分析 56 第5章 結論 59 第6章 未來工作與建議 60 參考資料 61 附錄A 67 附錄B 70

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