本研究以常壓輝光放電電漿電解技術(APGDE)，建立綠色製程回收技術，收先評估常壓輝光放電電漿電解技術之不同電極配置系統(Plasma Anode、Plasma Cathode)產生電漿物種，並光學發射光譜儀確認電漿物種，後續進行反應槽溶液進行分析評估，包含了：酸鹼值、臨場過氧化氫濃度、硝酸根離子濃度，最後實際應用於低濃度(20 ppm)四氯金酸三水合物於分別於不同電極配置電漿電解處理，經由ICP-OES降解濃度分析，由操作時間五分鐘結果可以獲得Plasma Anode系統降解效率(99.4%)高於Plasma Cathode系統降解效率(27.0%)，並經由UV-VIS、TEM、XRD，進行電解回收金屬之材料微觀分析確認，奠定綠色製程回收機制，後續以APGDE系統操作於反應槽內進行金屬離子溶液之製程參數最佳化，分別探討高濃度(600 ppm)含金離子溶液於不同電流參數下，金屬離子溶液濃度、氯離子濃度變化、pH值變化，奠定不同電流參數下金屬回收產率之電流參數優化評估，藉由感應耦合電漿放射光譜儀(ICP-OES)分析，16mA電流參數效率最佳，操作時間1小時回收率可達95.8%，然而通過電解過發現溶液酸化導致回收效率下降，故後續將APGDE系統實際應用於產業，對於前驅物 "(" 產業剝金液與含金離子溶液)溶液進行酸鹼調值，各別以pH4、pH7、pH11反應槽前驅物濃度為(600ppm)進行常壓輝光放電電漿電解系統處理並進行溶液與材料分析，由ICP-OES結果顯示經過前驅物調質處理，時間為15分鐘回收率為99%接近完全回收之狀態，後續利用反應速率常數運算結果，驗證在鹼性前驅物條件之下，回收效率最佳，呼應ICP-OES分析之結果，同時APGDE系統也超越法拉第定律所預估之回收產量。在材料微觀分析方面，通過SEM顯現出在鹼性前驅物件之下，形成金之金顆粒之粒徑較小，顯示通過前驅物之改質可調控金屬顆粒回收形式，除了能提供於回收產業製程之應用之外，更可以開發功能性奈米材料。綜合前面實驗結果，顯示出常壓輝光放電電漿電解系統之高效率、低汙染、商用潛力等優勢。
最後經多次與產業商討後，最終期望能達到完全乾濕分離，完全無二次廢液之問題以常壓電漿噴射束(Atmospheric Pressure Plasma Jet) 嘗試進行含金離子溶液(產業剝金液之回收處理，並驗證常壓電漿束確實具回收金金屬顆粒能力，並利用掃描式電子顯微鏡(SEM)分析經製程所回收之金屬組成結晶結構與表面形貌與XRD結果可接近純金屬結果且無任何雜訊生成，達到完全乾濕分離之回收方式，完全無二次廢液產生，未來更朝向應用於中低溫固態氧化物燃料電池之電極材料開發。

關鍵字：常壓輝光放電電漿電解、綠色製程技術、產業剝金溶液、含金離子溶液、常壓電漿噴射束

The study uses atmospheric pressure glow discharge plasma electrolysis technology (APGDE) to establish a green process recovery technology. First, the different electrode configuration systems of atmospheric pressure glow discharge plasma electrolysis technology were evaluated to generate plasma species. Using an Optical emission spectrometer, the plasma species were confirmed, and then analyzed & evaluated the reaction tank solution, including pH value, on-site hydrogen peroxide concentration, nitrate ion concentration. Finally, low concentration (20 ppm) Gold(III) chloride hydrate is treated with plasma electrolysis on different electrodes. The five-minute operation time degradation concentration analysis of ICP-OES shown that the degradation efficiency of the Plasma Anode system (99.4%) was higher than the degradation efficiency of the Plasma Cathode system (27.0%). Through UV-VIS, TEM, XRD, materials analysis, and confirmation of the electrolytic metal recovery material was carried out, and established a green process recovery mechanism, using the APGDE system to operate in the reaction tank and to optimize the process parameters of the metal ion solution. To discuss the high concentration. (600 ppm) Gold ion solution under different current parameters, such as metal ion solution concentration, chloride ion concentration change, pH value change, the current parameter optimization evaluation of metal recovery yield under different current parameters was established. The inductively coupled plasma emission spectrometer (ICP-OES) analysis showed that the 16mA current parameter efficiency was the best, and the recovery rate could reach 95.8% after 1 hour of operation. However, the acidification of the solution through electrolysis has led to a decrease in recovery efficiency. Therefore, the APGDE system will be applied to the industry in the future to avoid such a problem. The "Precursor" ("Industrial gold stripping solution and gold ion-containing solution) solution was adjusted for the acid-base value of pH4, pH7, and pH11 reaction tank (600ppm) for atmospheric pressure glow discharge plasma electrolysis system treatment. From the analysis of solution and materials, the results of ICP-OES shown that after the precursor conditioning treatment, a 99% recovery rate (which was close to the state of complete recovery) was achieved in 15 minute recovery time. The subsequent calculation results of the reaction rate constant were combined to verify the condition of the alkaline precursor. The recovery efficiency which corresponds to the results of ICP-OES analysis was found the best. At the same time, the APGDE system also exceeded the recovery output estimated by Faraday’s law. In terms of material microanalysis, The SEM results show that the size of the gold particles forming the gold was small in the solution under the alkaline precursor objects, ascribing the modification of the precursor can control the metal particle recovery form. In addition to the application of recycling industry processes, functional nanomaterials can also be developed. Based on the experimental results found, the advantages of high efficiency, low pollution, and commercial potential of the atmospheric pressure glow discharge plasma electrolysis system is apparent. Atmospheric Pressure Plasma Jet is used to spray high-concentration normal-pressure plasma beam and to recover gold ion-containing solution (recycling process of industrial gold stripping solution). It also discusses and verifies that the high-concentration constant pressure plasma beam could have the ability to recover gold metal particles. A scanning electron microscope (SEM) used to analyze the metal composition and surface morphology recovered by the manufacturing process. The XRD results were expected to achieve pure metal results without any impurity generation, and it was possible to achieve a completely dry and wet separation recovery method, and no secondary waste liquid was generated. Moreover, this method could be used in the development of electrode materials for medium and low-temperature solid oxide fuel cells.

Keyword：Atmospheric pressure glow discharge plasma, green processing, Gold-containing Solution, industrial gold solution, Atmospheric pressure Plasma Jet.

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