本研究首先探討製備塑膠光纖芯層材料(包括聚碳酸酯(PC)、聚甲基丙烯酸甲酯(PMMA)、聚苯乙烯(PS)及金屬觸媒環烯烴(MCOC)塑膠系列中的ARTON、TOPAS及ZEONEX)及含氟共聚合物(THV) 皮層材料之流變性質。 再將經流變儀所測得的數值搭配經理論公式計算推導數值，修正得到適用於複合紡絲機之修正值。進而探討不同芯層材料所製備之塑膠光纖在最適化加工條件下，光纖傳輸損耗值與芯皮層剪切黏度比的關係。結果發現經各芯層材料所製備之塑膠光纖大致均會在最適化芯皮層剪切黏度比值下出現光纖傳輸損耗之極小值。 為瞭解上述這些有趣之塑膠光纖光損耗性質，各芯層材料之紅外線、紫外線及可見光吸收光譜和塑膠光纖樣品之霧度及斷面型態均在本文中進一步探討。

In this study, we discussed the rheologic properties of poly carbonate(PC)、poly methyl methacrylate(PMMA)、poly styrene(PS) and ARTON、TOPAS and ZEONEX of metallocene cyclic olefin copolymer(MCOC) series as core material and fluoro copolymer(THV) as cladding material making plastic optical fiber at first. Then according to the data measured by rheometer, we got the correlation suitable for complex fiber-spinning machine after calculation from formula. Furthermore, we investigated the relationship of transmission loss and core/cladding shear viscosity under the optimization of processing. The result shows the minimum of transmission loss corresponding different core/cladding shear viscosity with different core material. In order to understand the behavior of plastic optical fiber, their ultra-red, ultraviolet and visible light absorption spectrum, haze and the cross-section morphology were also discussed further.

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