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研究生: 賈博淵
BO-YUAN JIA
論文名稱: PMMA, TPU及聚(芴-四苯乙烯)混摻之光學及力學性質與鑑定
Characterization, optical and mechanical properties of blending systems of PMMA, TPU and poly(fluorene-tetraphenylethene)
指導教授: 游進陽
Chin-Yang Yu
口試委員: 王丞浩
Chen-Hao Wang
施劭儒
Shao-Ju Shih
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2019
畢業學年度: 107
語文別: 中文
論文頁數: 79
中文關鍵詞: 聚(芴-四苯乙烯)聚甲基丙烯酸甲酯聚氨酯樹脂鈴木耦合聚集誘導發光
外文關鍵詞: poly(fluorene-tetraphenylethene), Suzuki coupling, PMMA, TPU, aggregation-induced emission
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本論文利用鈴木耦合聚合反應使用鈀金屬催化合成新聚(芴-四苯乙烯)聚合物。此聚合物具有良好的溶解度和熱穩定性,具有潛在許多的應用。四苯乙烯為具有聚集誘導發光之特性。新聚(芴-四苯乙烯)耦合芴及四苯乙烯單元並研究其各項性質。
本實驗選用鈀金屬催化之鈴木耦合反應作為高分子聚合反應,並與PMMA及TPU混摻。分別以高效能高分子核心系統 (APC)、液態超導核磁共振儀 (NMR)、紫外光-可見光/近紅外光分析儀 (UV)、螢光光譜儀 (PL)、熱重量損失分析儀 (TGA)、熱示差分析儀 (DSC)、電腦伺服拉力試驗機來鑑定判斷聚(芴-四苯乙烯)聚合物混摻PMMA及TPU的各項性質鑑定。


In this thesis, the synthesis of fluorene-tetraphenylethene polymers using palladium catalyst by Suzuki coupling polymerization has been reported. The resulting polymers showed good solubility and thermal stability and have many potential applications. Tetraphenylethene has the characteristics of aggregation-induced emission (AIE). In this experiment, the polymers were mixed with PMMA and TPU. Advanced polymer chromatography (APC), liquid phase nuclear magnetic resonance(NMR), ultraviolet-visible /near-infrared spectroscopy (UV-vis-NIR), fluorescence spectrometer (PL), thermogravimetric analyzer (TGA), differential scanning calorimetry (DSC) were used to measure the properties of the polymers. The computer assistant tensile testing machine has been used to identify and characterize the mechanical properties of PMMA and TPU mixed with poly (fluorene-tetraphenylethene).

Abstract i 中文摘要 ii 誌謝 iii 目錄 iv 圖目錄 vi 表目錄 ix 第一章 緒論 1 1.1 簡介 2 1.2 有機半導體 3 1.3 固體帶理論 4 1.4 共軛聚合物中的電荷傳輸 6 1.5 螢光 9 1.6 ASTM-D882規範 13 1.7 研究目標 14 第二章 芴單體的合成與性質鑑定 16 2.1 聚合物合成 17 2.1.1 單體製備 17 2.1.2 鈴木耦合反應 19 2.1.3 聚合物的合成 22 2.1.4 聚合物結構性質 23 2.1.5 熱性質 27 第三章 研究方法 33 3.1 實驗材料 34 3.2 實驗機台 35 3.3聚(芴-四苯乙烯)聚合物合成 44 3.3.1聚(芴-四苯乙烯)聚合物反應路徑 44 3.3.2聚(芴-四苯乙烯)合成 45 3.3.3聚(芴-四苯乙烯)性質鑑定 46 3.3.4聚(芴-四苯乙烯)混摻薄膜製作 52 3.3.5拉伸試驗 57 第四章 結論 62 第五章 參考文獻 63

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