研究生: |
周綱彥 Gun-yen Chou |
---|---|
論文名稱: |
交聯劑對材料表面能及熱性質之影響與超疏水至超親水間可控表面之研究 Effect of the curing agent on surface energy and thermal properties of polymeric materials and the study of tunable surface energy from superhydrophobicity to superhydrophilicity |
指導教授: |
陳建光
Jem-Kun Chen |
口試委員: |
邱顯堂
none 許應舉 none |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
論文出版年: | 2008 |
畢業學年度: | 96 |
語文別: | 中文 |
論文頁數: | 104 |
中文關鍵詞: | 無 |
相關次數: | 點閱:202 下載:3 |
分享至: |
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本篇論文有兩個主題,其一為探討交聯劑對各高分子熱性質及表面能的影響,其二為利用新穎奈米草技術製備超疏水表面並使其局部表面轉為超親水。
為了得到高的熱性質以及低表面能的材料,我們於是加入了交聯劑使高分子進行交聯反應,藉由交聯劑含量多寡、交聯反應時間,以及交聯的溫度來探討交聯劑對於熱性質的變化與表面能的影響。
另外我們利用奈米草當做基材,將Polybenzoxazine和奈米粉體SiO2混合鍍在上層製備一個超疏水的表面,並利用UV光照射來達到超疏水的材料上擁有選擇性的超親水區域。
This study has two subjects. One is to find out the thermal properties and surface energy of polymer after adding curing agent, the other is to use nanograss fabricating a superhydrophobic surface, then exposing the prepared film under UV light to make a selective superhydrophilic surface.
In order to get a material which has high thermal properties and low surface energy, we add curing agent into the polymeric system. By changing curing agent contents, changing curing time and curing temperature, we can understand curing agent play an important role in thermal properties and surface energy.
Second, we use nanograss as our substrate. We mix Polybenzoxazine and SiO2 together then coat them on the nanograss substrate to fabricate a rough surface. By illuminating UV light on the superhydrophobic surface, we can get a surface with superhydrophobic and superhydrophilic properties at our desired region.
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