為了解決一氧化矽體積膨脹變化所形成的SEI層與不可逆相所消耗過多鋰離子的問題，本研究提出將丙烯酸鋰（LiAA)預鋰化於一氧化矽（SiO#a)表面上，丙烯酸鋰（LiAA)含有豐富羧酸基團與鋰離子，這些羧基可確保與氧化矽之間有牢固的結合力，達到穩定的結構特性以及提供額外的鋰離子能夠補足再循環過程中所消耗的鋰離子，能夠提升一氧化矽循環性能。在100圈的電容保持率，SiO#a電容保持率為17%、SiO#a LA電容保持率提升到30.4%及SiO#a LH電容保持率達到56%，提高LiAA比例進行預鋰化於表面，可有效提升的電容量保持率。
除了探討一氧化矽表面預鋰化的效果，也針對兩種不同比例氧化矽分別為SiO#9和SiO#11皆含有碳成分存在，進行LiAA預鋰化於氧化矽表面，在100圈循環後的電容保持率:SiO#a電容保持率提升16.2%；SiO#9電容保持率提升30%以及SiO#11電容保持率提升14%，透過預鋰化於氧化矽表面的LiAA含量來計算所提供額外的鋰離子數量:SiO#a為5.76×10^20個鋰離子；SiO#9為1×10^21個鋰離子；SiO#11為2.07×10^20個鋰離子，在探討預鋰化於三種氧化矽表面的表現為SiO#9> SiO#a> SiO#11，由於SiO#11裡碳含量較高，使LiAA可能預鋰化於SiO#11的碳表面上，LiAA更益於預鋰化在氧化矽表面上，能夠讓電容保持率的提升來自於LiAA預鋰化於氧化矽表面所提供越多額外的鋰離子來補足所消耗的部分，而倍率性能方面1C電流速率下，預鋰化後的氧化矽電容量皆增加75-150mAh/g，額外的鋰離子可促進高電流速率下的快速電化學反應，因此透過預鋰化於氧化矽表面，能夠讓氧化矽能有效提高倍率性能以及改善循環穩定性。

In order to resolve problems from the formation of SEI layer due to volume expansion of silicon monoxide and along with depletion of lithium ions from irreversible phase reactions, this research propose a casual way of synthesis to handle the issue. By using synthesizing lithium acrylate (LiAA) on the surface of silicon monoxide (SiO#a), forming a layer of lithiated polymer which acts as a preliathiation reaction. Lithium acrylate (LiAA) is chosen for the preliathiation process due to the abundant amount of carboxyl groups and lithium ions carried. These carboxyl groups enhance bonding force within silicon monoxide (SiO#a), stabilizing structure characteristics and providing extra lithium ions from depletion during cycling, which enhances cycling ability. In this research, 2 different amounts of addition, which are 15% and 30% of LiAA into SiO#a along with 100 cycles of charge-discharge procedure are conducted. SiO#a BK has a capacity retention of 17%, 15% of LiAA had increase the capacity retention to 30.4% and 30% of LiAA had reach a 56% of capacity retention. This confirms a further insight of by increasing LiAA’s amount into synthesis efficiently increases capacity retention.
Besides of just investigating surface preliathiation effects on silicon monoxide, we further picked on 2 different ratio silicon monoxide containing carbon which are named as SiO#9 and Si#11. As using the method above, surface preliathiation LiAA on the subjected silicon monoxide, at the point of after 100 cycles, capacity retention is: SiO#a increased 16.2%; SiO#9 increased 30% and SiO#11 increased 14%. Calculations of the numbers of lithium-ions provided by LiAA preliathiation on the surface of silicon monoxide: SiO#a has 5.76×10^20 of lithium ions, SiO#9 has 1×10^21 of lithium ions；SiO#11has 2.07×10^20 of lithium ions. In this investigation, the 3 subject ‘s performance are as SiO#9> SiO#a> SiO#11, since sio#11 carbon contain is higher, it is to be suggested LiAA perhaps preliathiated on top of the carbon, as LiAA is more effective preliathiated on silicon monoxide. Increment of capacity retention comes from the LiAA surface preliathiation providing extra lithium-ions from depletion. For rate performance, under 1C current rate, preliathiation of silicon monoxide’s has an increment of 75~150 mAh/g. Extra lithium-ions could promote high current rate electrochemical performance, and due to this, by preliathiation on the surface of silicon monoxide could increase rate performance and enhance cycle stability.

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