研究生: |
Edo Indra Permana Edo Indra Permana |
---|---|
論文名稱: |
Carbon Microcoil-Embedded Cellulose Nanofiber Film Toward Flexible Supercapacitor Electrode Carbon Microcoil-Embedded Cellulose Nanofiber Film Toward Flexible Supercapacitor Electrode |
指導教授: |
今榮東洋子
Toyoko Imae |
口試委員: |
林麗瓊
Li-Chyong Chen 邱昱誠 Yu-Cheng Chiu |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2020 |
畢業學年度: | 108 |
語文別: | 英文 |
論文頁數: | 64 |
中文關鍵詞: | Cellulose nanofiber 、Carbon microcoil 、Supercapacitor 、Flexible |
外文關鍵詞: | Cellulose nanofiber, Carbon microcoil, Supercapacitor, Flexible |
相關次數: | 點閱:270 下載:0 |
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製備了由纖維素奈米纖維、酸處理的碳微線圈(CMC)、聚吡咯和碳量子點組成的複合膜。 通過掃描電子顯微鏡氮吸附-解吸等溫線、紅外吸收光譜和拉曼光譜驗證組分材料的累積/沉積和膜的表面性質。
在1M NaCl水溶液中,該膜作為電解質在三電極系統中用作工作電極。 循環伏安法(CV)顯示,CMC / TOCNF比電容約為85 F / g,隨聚吡咯和碳點的添加而增加,在5mV / s的掃描速率下最大達到854 F / g。 另外,該複合膜電極在3000次循環後的電容保持率為91.1%,該膜在彎曲50次後的穩定性為82.1%。 這些結果表明所製備的柔性超級電容器電極品質是能受到彎曲後能有好的電容率。
The composite films consisting of cellulose nanofiber, acid-treated carbon microcoil (CMC), polypyrrole and carbon dots were prepared. The accumulation/deposition of component materials and the surface property of the films were confirmed with scanning electron microscopy, nitrogen adsorption-desorption isotherm, infrared adsorption spectroscopy, and Raman spectroscopy.
The films were used as a working electrode in a three-electrodes system in an aqueous 1M NaCl solution as an electrolyte. The cyclic voltammetry (CV) showed that the specific capacitance of CMC/TOCNF about 85 F/g, increased with the addition of polypyrrole, and carbon dots and reached maximum of 854 F/g at the scan rate of 5mV/s. Moreover, the capacitance retention of the relevant composite film electrode was 91.1% after 3000 cycles, and the stability for this film after 50 times bending was 82.1%. These results indicate the enough quality of the prepared flexible supercapacitor electrode
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