本研究採用一套靜態式液相循環的相平衡裝置，量測2-甲基呋喃 + 糠醇、異丙醇 + 糠醇與呋喃 + 糠醛共三組在353.15 K、373.15 K及408.15 K溫度下的雙成分混合物之汽液相平衡，實驗結果顯示每組雙成分系統皆無共沸物產生，且均是正偏差。本研究也量測了2-甲基呋喃在溫度348.59 K ~ 409.02 K之間的飽和蒸氣壓，並使用extended Antoine方程式關聯，所量取的雙成分汽液相平衡數據的熱力學一致性均分別以逐點法、面積法與無限稀釋法確認。本實驗所測得之汽液平衡數據分別以Wilson-HOC，NRTL-HOC以及UNIQUAC-HOC模式關聯，每一種模式均能獲得令人滿意的結果。

A static-type apparatus with a liquid-phase circulation loop was used to measure isothermal vapor-liquid equilibrium (VLE) data for the binary systems of 2-methylfuran + furfuryl alcohol, isopropanol + furfuryl alcohol, and furan + furfural at 353.15 K, 373.15 K, and 408.15 K. The experimental results showed no azeotrope formation and positive deviations from ideality in each binary system. The vapor pressures of pure 2-methylfuran were also measured from 348.15 K to 409.02 K and fitted to the extended Antoine equation. The thermodynamic consistency of the new binary VLE data has been confirmed by the point, area, and infinite dilution tests. The Wilson-HOC, the NRTL-HOC, and the UNIQUAC-HOC models were used to correlate the VLE data. Satisfactory results have been obtained from each model.

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